(a) Interpretation: The stronger nucleophile from the given pair is to be identified. Concept introduction: In nucleophilic substitution reaction, nucleophile takes the position of leaving group by attacking on the electron deficient carbon atom. The electron rich chemical species that contains negative charge or lone pair of electrons are known as nucleophile. The strong nucleophile is strong base whose conjugate acid has high p K a value.

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Answer 1

Question

Chapter 7, Problem 7.13P

Interpretation Introduction

(a)

Interpretation: The stronger nucleophile from the given pair is to be identified.

Concept introduction: In nucleophilic substitution reaction, nucleophile takes the position of leaving group by attacking on the electron deficient carbon atom. The electron rich chemical species that contains negative charge or lone pair of electrons are known as nucleophile. The strong nucleophile is strong base whose conjugate acid has high pKa value.

Interpretation Introduction

(b)

Interpretation: The stronger nucleophile from the given pair is to be identified.

Concept introduction: In nucleophilic substitution reaction, nucleophile takes the position of leaving group by attacking on the electron deficient carbon atom. The electron rich chemical species that contains negative charge or lone pair of electrons are known as nucleophile. The strong nucleophile is strong base whose conjugate acid has high pKa value.

Interpretation Introduction

(c)

Interpretation: The stronger nucleophile from the given pair is to be identified.

Concept introduction: In nucleophilic substitution reaction, nucleophile takes the position of leaving group by attacking on the electron deficient carbon atom. The electron rich chemical species that contains negative charge or lone pair of electrons are known as nucleophile. The strong nucleophile is strong base whose conjugate acid has high pKa value.

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Identify the stronger nucleophile in each pair. a.NH3, −NH2 b.CH3NH2, CH3OH c.CH3CO2−, CH3CH2O−

A 3. Rank the following compounds in terms of reactivity with a good nucleophile. Br B NH₂ F D OH E CI

1. Attack the alkyl chloride with the stronger nucleophile. 2. Deprotonated to form the product

Answer 2

Question

Chapter 7, Problem 7.13P

Interpretation Introduction

(a)

Interpretation: The stronger nucleophile from the given pair is to be identified.

Concept introduction: In nucleophilic substitution reaction, nucleophile takes the position of leaving group by attacking on the electron deficient carbon atom. The electron rich chemical species that contains negative charge or lone pair of electrons are known as nucleophile. The strong nucleophile is strong base whose conjugate acid has high pKa value.

Interpretation Introduction

(b)

Interpretation: The stronger nucleophile from the given pair is to be identified.

Concept introduction: In nucleophilic substitution reaction, nucleophile takes the position of leaving group by attacking on the electron deficient carbon atom. The electron rich chemical species that contains negative charge or lone pair of electrons are known as nucleophile. The strong nucleophile is strong base whose conjugate acid has high pKa value.

Interpretation Introduction

(c)

Interpretation: The stronger nucleophile from the given pair is to be identified.

Concept introduction: In nucleophilic substitution reaction, nucleophile takes the position of leaving group by attacking on the electron deficient carbon atom. The electron rich chemical species that contains negative charge or lone pair of electrons are known as nucleophile. The strong nucleophile is strong base whose conjugate acid has high pKa value.

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Answer 3

Question

Chapter 7, Problem 7.13P

Interpretation Introduction

(a)

Interpretation: The stronger nucleophile from the given pair is to be identified.

Concept introduction: In nucleophilic substitution reaction, nucleophile takes the position of leaving group by attacking on the electron deficient carbon atom. The electron rich chemical species that contains negative charge or lone pair of electrons are known as nucleophile. The strong nucleophile is strong base whose conjugate acid has high pKa value.

Interpretation Introduction

(b)

Interpretation: The stronger nucleophile from the given pair is to be identified.

Concept introduction: In nucleophilic substitution reaction, nucleophile takes the position of leaving group by attacking on the electron deficient carbon atom. The electron rich chemical species that contains negative charge or lone pair of electrons are known as nucleophile. The strong nucleophile is strong base whose conjugate acid has high pKa value.

Interpretation Introduction

(c)

Interpretation: The stronger nucleophile from the given pair is to be identified.

Concept introduction: In nucleophilic substitution reaction, nucleophile takes the position of leaving group by attacking on the electron deficient carbon atom. The electron rich chemical species that contains negative charge or lone pair of electrons are known as nucleophile. The strong nucleophile is strong base whose conjugate acid has high pKa value.

Expert Solution & Answer

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Answer 4

Question

Chapter 7, Problem 7.13P

Interpretation Introduction

(a)

Interpretation: The stronger nucleophile from the given pair is to be identified.

Concept introduction: In nucleophilic substitution reaction, nucleophile takes the position of leaving group by attacking on the electron deficient carbon atom. The electron rich chemical species that contains negative charge or lone pair of electrons are known as nucleophile. The strong nucleophile is strong base whose conjugate acid has high pKa value.

Interpretation Introduction

(b)

Interpretation: The stronger nucleophile from the given pair is to be identified.

Concept introduction: In nucleophilic substitution reaction, nucleophile takes the position of leaving group by attacking on the electron deficient carbon atom. The electron rich chemical species that contains negative charge or lone pair of electrons are known as nucleophile. The strong nucleophile is strong base whose conjugate acid has high pKa value.

Interpretation Introduction

(c)

Interpretation: The stronger nucleophile from the given pair is to be identified.

Concept introduction: In nucleophilic substitution reaction, nucleophile takes the position of leaving group by attacking on the electron deficient carbon atom. The electron rich chemical species that contains negative charge or lone pair of electrons are known as nucleophile. The strong nucleophile is strong base whose conjugate acid has high pKa value.

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Answer 5

Chapter 7, Problem 7.13P

Interpretation Introduction

(a)

Interpretation: The stronger nucleophile from the given pair is to be identified.

Concept introduction: In nucleophilic substitution reaction, nucleophile takes the position of leaving group by attacking on the electron deficient carbon atom. The electron rich chemical species that contains negative charge or lone pair of electrons are known as nucleophile. The strong nucleophile is strong base whose conjugate acid has high pKa value.

Interpretation Introduction

(b)

Interpretation: The stronger nucleophile from the given pair is to be identified.

Concept introduction: In nucleophilic substitution reaction, nucleophile takes the position of leaving group by attacking on the electron deficient carbon atom. The electron rich chemical species that contains negative charge or lone pair of electrons are known as nucleophile. The strong nucleophile is strong base whose conjugate acid has high pKa value.

Interpretation Introduction

(c)

Interpretation: The stronger nucleophile from the given pair is to be identified.

Concept introduction: In nucleophilic substitution reaction, nucleophile takes the position of leaving group by attacking on the electron deficient carbon atom. The electron rich chemical species that contains negative charge or lone pair of electrons are known as nucleophile. The strong nucleophile is strong base whose conjugate acid has high pKa value.

Answer 6

Chapter 7, Problem 7.13P

Interpretation Introduction

(a)

Interpretation: The stronger nucleophile from the given pair is to be identified.

Concept introduction: In nucleophilic substitution reaction, nucleophile takes the position of leaving group by attacking on the electron deficient carbon atom. The electron rich chemical species that contains negative charge or lone pair of electrons are known as nucleophile. The strong nucleophile is strong base whose conjugate acid has high pKa value.

Answer 7

Chapter 7, Problem 7.13P

Interpretation Introduction

(a)

Interpretation: The stronger nucleophile from the given pair is to be identified.

Concept introduction: In nucleophilic substitution reaction, nucleophile takes the position of leaving group by attacking on the electron deficient carbon atom. The electron rich chemical species that contains negative charge or lone pair of electrons are known as nucleophile. The strong nucleophile is strong base whose conjugate acid has high pKa value.

Answer 8

Interpretation Introduction

(b)

Interpretation: The stronger nucleophile from the given pair is to be identified.

Concept introduction: In nucleophilic substitution reaction, nucleophile takes the position of leaving group by attacking on the electron deficient carbon atom. The electron rich chemical species that contains negative charge or lone pair of electrons are known as nucleophile. The strong nucleophile is strong base whose conjugate acid has high pKa value.

Answer 9

Interpretation Introduction

(b)

Interpretation: The stronger nucleophile from the given pair is to be identified.

Concept introduction: In nucleophilic substitution reaction, nucleophile takes the position of leaving group by attacking on the electron deficient carbon atom. The electron rich chemical species that contains negative charge or lone pair of electrons are known as nucleophile. The strong nucleophile is strong base whose conjugate acid has high pKa value.

Answer 10

Interpretation Introduction

(c)

Interpretation: The stronger nucleophile from the given pair is to be identified.

Concept introduction: In nucleophilic substitution reaction, nucleophile takes the position of leaving group by attacking on the electron deficient carbon atom. The electron rich chemical species that contains negative charge or lone pair of electrons are known as nucleophile. The strong nucleophile is strong base whose conjugate acid has high pKa value.

Answer 11

Interpretation Introduction

(c)

Interpretation: The stronger nucleophile from the given pair is to be identified.

Concept introduction: In nucleophilic substitution reaction, nucleophile takes the position of leaving group by attacking on the electron deficient carbon atom. The electron rich chemical species that contains negative charge or lone pair of electrons are known as nucleophile. The strong nucleophile is strong base whose conjugate acid has high pKa value.

Answer 12

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Answer 13

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Answer 14

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Answer 15

Ch. 7 - Problem 7.1 Telfairine, a naturally occurring...Ch. 7 - Give the IUPAC name for each compound. a. b. c. d.Ch. 7 - Prob. 7.3P Ch. 7 - An sp3 hybridized CCl bond is more polar than an...Ch. 7 - Prob. 7.5P Ch. 7 - Problem 7.6 Identify the nucleophile and leaving...Ch. 7 - Prob. 7.7P Ch. 7 - Prob. 7.8P Ch. 7 - What neutral nucleophile is needed to convert...Ch. 7 - Prob. 7.10P

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