(a) Interpretation: The better leaving group from the given pair is to be identified. Concept introduction: The replacement or substitution of one functional group with another different functional group in any chemical reaction is termed as substitution reaction. In nucleophilic substitution reaction, nucleophile takes the position of leaving group by attacking on the electron deficient carbon atom. The good leaving groups are weak base whose conjugate acids have low p K a value.

Question

Construct a molecular orbital energy-level diagram for BeH2. Sketch the MO pictures (schematic representation) for the HOMO and LUMO of BeH2 [Orbital Potential Energies, H (1s): -13.6 eV; Be (2s): -9.3 eV, Be (2p): -6.0 eV]

Answer 1

Question

Chapter 7, Problem 7.10P

Interpretation Introduction

(a)

Interpretation: The better leaving group from the given pair is to be identified.

Concept introduction: The replacement or substitution of one functional group with another different functional group in any chemical reaction is termed as substitution reaction. In nucleophilic substitution reaction, nucleophile takes the position of leaving group by attacking on the electron deficient carbon atom. The good leaving groups are weak base whose conjugate acids have low pKa value.

Interpretation Introduction

(b)

Interpretation: The better leaving group from the given pair is to be identified.

Concept introduction: The replacement or substitution of one functional group with another different functional group in any chemical reaction is termed as substitution reaction. In nucleophilic substitution reaction, nucleophile takes the position of leaving group by attacking on the electron deficient carbon atom. The good leaving groups are weak base whose conjugate acids have low pKa value.

Interpretation Introduction

(c)

Interpretation: The better leaving group from the given pair is to be identified.

Concept introduction: The replacement or substitution of one functional group with another different functional group in any chemical reaction is termed as substitution reaction. In nucleophilic substitution reaction, nucleophile takes the position of leaving group by attacking on the electron deficient carbon atom. The good leaving groups are weak base whose conjugate acids have low pKa value.

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Construct a molecular orbital energy-level diagram for BeH2. Sketch the MO pictures (schematic representation) for the HOMO and LUMO of BeH2 [Orbital Potential Energies, H (1s): -13.6 eV; Be (2s): -9.3 eV, Be (2p): -6.0 eV]

Indicate the isomers of the A(H2O)6Cl3 complex. State the type of isomerism they exhibit and explain it briefly.

State the formula of the compound potassium μ-dihydroxydicobaltate (III) tetraoxalate.

Answer 2

Question

Chapter 7, Problem 7.10P

Interpretation Introduction

(a)

Interpretation: The better leaving group from the given pair is to be identified.

Concept introduction: The replacement or substitution of one functional group with another different functional group in any chemical reaction is termed as substitution reaction. In nucleophilic substitution reaction, nucleophile takes the position of leaving group by attacking on the electron deficient carbon atom. The good leaving groups are weak base whose conjugate acids have low pKa value.

Interpretation Introduction

(b)

Interpretation: The better leaving group from the given pair is to be identified.

Concept introduction: The replacement or substitution of one functional group with another different functional group in any chemical reaction is termed as substitution reaction. In nucleophilic substitution reaction, nucleophile takes the position of leaving group by attacking on the electron deficient carbon atom. The good leaving groups are weak base whose conjugate acids have low pKa value.

Interpretation Introduction

(c)

Interpretation: The better leaving group from the given pair is to be identified.

Concept introduction: The replacement or substitution of one functional group with another different functional group in any chemical reaction is termed as substitution reaction. In nucleophilic substitution reaction, nucleophile takes the position of leaving group by attacking on the electron deficient carbon atom. The good leaving groups are weak base whose conjugate acids have low pKa value.

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Answer 3

Question

Chapter 7, Problem 7.10P

Interpretation Introduction

(a)

Interpretation: The better leaving group from the given pair is to be identified.

Concept introduction: The replacement or substitution of one functional group with another different functional group in any chemical reaction is termed as substitution reaction. In nucleophilic substitution reaction, nucleophile takes the position of leaving group by attacking on the electron deficient carbon atom. The good leaving groups are weak base whose conjugate acids have low pKa value.

Interpretation Introduction

(b)

Interpretation: The better leaving group from the given pair is to be identified.

Concept introduction: The replacement or substitution of one functional group with another different functional group in any chemical reaction is termed as substitution reaction. In nucleophilic substitution reaction, nucleophile takes the position of leaving group by attacking on the electron deficient carbon atom. The good leaving groups are weak base whose conjugate acids have low pKa value.

Interpretation Introduction

(c)

Interpretation: The better leaving group from the given pair is to be identified.

Concept introduction: The replacement or substitution of one functional group with another different functional group in any chemical reaction is termed as substitution reaction. In nucleophilic substitution reaction, nucleophile takes the position of leaving group by attacking on the electron deficient carbon atom. The good leaving groups are weak base whose conjugate acids have low pKa value.

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Answer 4

Question

Chapter 7, Problem 7.10P

Interpretation Introduction

(a)

Interpretation: The better leaving group from the given pair is to be identified.

Concept introduction: The replacement or substitution of one functional group with another different functional group in any chemical reaction is termed as substitution reaction. In nucleophilic substitution reaction, nucleophile takes the position of leaving group by attacking on the electron deficient carbon atom. The good leaving groups are weak base whose conjugate acids have low pKa value.

Interpretation Introduction

(b)

Interpretation: The better leaving group from the given pair is to be identified.

Concept introduction: The replacement or substitution of one functional group with another different functional group in any chemical reaction is termed as substitution reaction. In nucleophilic substitution reaction, nucleophile takes the position of leaving group by attacking on the electron deficient carbon atom. The good leaving groups are weak base whose conjugate acids have low pKa value.

Interpretation Introduction

(c)

Interpretation: The better leaving group from the given pair is to be identified.

Concept introduction: The replacement or substitution of one functional group with another different functional group in any chemical reaction is termed as substitution reaction. In nucleophilic substitution reaction, nucleophile takes the position of leaving group by attacking on the electron deficient carbon atom. The good leaving groups are weak base whose conjugate acids have low pKa value.

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Answer 5

Chapter 7, Problem 7.10P

Interpretation Introduction

(a)

Interpretation: The better leaving group from the given pair is to be identified.

Concept introduction: The replacement or substitution of one functional group with another different functional group in any chemical reaction is termed as substitution reaction. In nucleophilic substitution reaction, nucleophile takes the position of leaving group by attacking on the electron deficient carbon atom. The good leaving groups are weak base whose conjugate acids have low pKa value.

Interpretation Introduction

(b)

Interpretation: The better leaving group from the given pair is to be identified.

Concept introduction: The replacement or substitution of one functional group with another different functional group in any chemical reaction is termed as substitution reaction. In nucleophilic substitution reaction, nucleophile takes the position of leaving group by attacking on the electron deficient carbon atom. The good leaving groups are weak base whose conjugate acids have low pKa value.

Interpretation Introduction

(c)

Interpretation: The better leaving group from the given pair is to be identified.

Concept introduction: The replacement or substitution of one functional group with another different functional group in any chemical reaction is termed as substitution reaction. In nucleophilic substitution reaction, nucleophile takes the position of leaving group by attacking on the electron deficient carbon atom. The good leaving groups are weak base whose conjugate acids have low pKa value.

Answer 6

Chapter 7, Problem 7.10P

Interpretation Introduction

(a)

Interpretation: The better leaving group from the given pair is to be identified.

Concept introduction: The replacement or substitution of one functional group with another different functional group in any chemical reaction is termed as substitution reaction. In nucleophilic substitution reaction, nucleophile takes the position of leaving group by attacking on the electron deficient carbon atom. The good leaving groups are weak base whose conjugate acids have low pKa value.

Answer 7

Chapter 7, Problem 7.10P

Interpretation Introduction

(a)

Interpretation: The better leaving group from the given pair is to be identified.

Concept introduction: The replacement or substitution of one functional group with another different functional group in any chemical reaction is termed as substitution reaction. In nucleophilic substitution reaction, nucleophile takes the position of leaving group by attacking on the electron deficient carbon atom. The good leaving groups are weak base whose conjugate acids have low pKa value.

Answer 8

Interpretation Introduction

(b)

Interpretation: The better leaving group from the given pair is to be identified.

Concept introduction: The replacement or substitution of one functional group with another different functional group in any chemical reaction is termed as substitution reaction. In nucleophilic substitution reaction, nucleophile takes the position of leaving group by attacking on the electron deficient carbon atom. The good leaving groups are weak base whose conjugate acids have low pKa value.

Answer 9

Interpretation Introduction

(b)

Interpretation: The better leaving group from the given pair is to be identified.

Concept introduction: The replacement or substitution of one functional group with another different functional group in any chemical reaction is termed as substitution reaction. In nucleophilic substitution reaction, nucleophile takes the position of leaving group by attacking on the electron deficient carbon atom. The good leaving groups are weak base whose conjugate acids have low pKa value.

Answer 10

Interpretation Introduction

(c)

Interpretation: The better leaving group from the given pair is to be identified.

Concept introduction: The replacement or substitution of one functional group with another different functional group in any chemical reaction is termed as substitution reaction. In nucleophilic substitution reaction, nucleophile takes the position of leaving group by attacking on the electron deficient carbon atom. The good leaving groups are weak base whose conjugate acids have low pKa value.

Answer 11

Interpretation Introduction

(c)

Interpretation: The better leaving group from the given pair is to be identified.

Concept introduction: The replacement or substitution of one functional group with another different functional group in any chemical reaction is termed as substitution reaction. In nucleophilic substitution reaction, nucleophile takes the position of leaving group by attacking on the electron deficient carbon atom. The good leaving groups are weak base whose conjugate acids have low pKa value.

Answer 12

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Answer 23

Ch. 7 - Problem 7.1 Telfairine, a naturally occurring...Ch. 7 - Give the IUPAC name for each compound. a. b. c. d.Ch. 7 - Prob. 7.3P Ch. 7 - An sp3 hybridized CCl bond is more polar than an...Ch. 7 - Prob. 7.5P Ch. 7 - Problem 7.6 Identify the nucleophile and leaving...Ch. 7 - Prob. 7.7P Ch. 7 - Prob. 7.8P Ch. 7 - What neutral nucleophile is needed to convert...Ch. 7 - Prob. 7.10P

Solution Summary: The author explains that nucleophile takes the position of leaving group by attacking on the electron deficient carbon atom.

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