Chemistry
3rd Edition
ISBN: 9780073402734
Author: Julia Burdge
Publisher: MCGRAW-HILL HIGHER EDUCATION
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Textbook Question
Chapter 7, Problem 31QP
Explain the trends in
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How is the resonance structure formed to make the following reaction product. Please hand draw the arrows showing how the electrons move to the correct position. Do not use an AI answer. Please draw it yourself or don't bother.
Part II Calculate λ max of the following compounds using wood ward- Fiecer rules
a)
b)
c)
d)
e)
OH
OH
dissolved in dioxane
Br
Br
dissolved in methanol.
NH₂
OCH 3
OH
6. Match each of the lettered items in the column on
the left with the most appropriate numbered
item(s) in the column on the right. Some of the
numbered items may be used more than once
and some not at all.
a.
Z = 37
1.
b.
Mn
2.
C.
Pr
element in period 5 and group
14
element in period 5 and group
15
d. S
e. [Rn] 7s¹
f.
d block
metal
3. highest metallic character of all
the elements
4. paramagnetic with 5 unpaired
electrons
5. 4f36s2
6. isoelectronic with Ca²+ cation
7.
an alkaline metal
8. an f-block element
Chapter 7 Solutions
Chemistry
Ch. 7.1 - Practice Problem ATTEMPT What element(s) would you...Ch. 7.1 - Practice Problem BUILD
Arrange the following...Ch. 7.1 - Practice ProblemCONCEPTUALIZE Three different...Ch. 7.1 - 7.1.1 Which of the following elements would you...Ch. 7.1 - Prob. 2CPCh. 7.1 - Prob. 3CPCh. 7.2 - Practice Problem ATTEMPT Without using a periodic...Ch. 7.2 - Practice ProblemBUILD Identify the elements...Ch. 7.2 - Prob. 1PPCCh. 7.2 - 7.2.1 Which electron configuration is correct for...
Ch. 7.2 - Which of the following equations correctly...Ch. 7.3 - Practice Problem ATTEMPT Referring only to a...Ch. 7.3 - Practice Problem BUILD
For which of the following...Ch. 7.3 - Practice Problem CONCEPTUALIZE
Based on size and...Ch. 7.4 - Practice Problem ATTEMPT Which element. Mg or Al,...Ch. 7.4 - Prob. 1PPBCh. 7.4 - Practice ProblemCONCEPTUALIZE Imagine an...Ch. 7.4 - 7.4.1 Arrange the elements in order of increasing...Ch. 7.4 - Arrange the elements Li. Be. and B in order of...Ch. 7.4 - For each of the following pairs of elements,...Ch. 7.4 - Prob. 4CPCh. 7.5 - Practice ProblemATTEMPT Would you expect Mg or Al...Ch. 7.5 - Prob. 1PPBCh. 7.5 - Practice ProblemCONCEPTUALIZE In the same...Ch. 7.5 - Prob. 1CPCh. 7.5 - 7.5.2 Which of the following pairs are...Ch. 7.5 - 7.5.3 Select the correct ground-state electron...Ch. 7.5 - Prob. 4CPCh. 7.6 - Practice Problem ATTEMPT Between which two charges...Ch. 7.6 - Practice ProblemBUILD What must the distance be...Ch. 7.6 - Prob. 1PPCCh. 7.6 - Which of the following species are isoelectronic...Ch. 7.6 - Which of the following are arranged correctly in...Ch. 7.6 - 7.6.3 Which of the following is the most realistic...Ch. 7.6 - Which of the following is the most realistic...Ch. 7.7 - Practice Problem ATTEMPT Write electron...Ch. 7.7 - Practice ProblemBUILD List all the species (atoms...Ch. 7.7 - Practice Problem CONCEPTUALIZE
Select the correct...Ch. 7.8 - Practice Problem ATTEMPT
Write electron...Ch. 7.8 - Practice Problem BUILD
What common d-block ion...Ch. 7.8 - Prob. 1PPCCh. 7.9 - Practice ProblemATTEMPT Arrange the following...Ch. 7.9 - Practice Problem BUILD
List all the common ions...Ch. 7.9 - Practice ProblemCONCEPTUALIZE Which periodic...Ch. 7 - Often we can compare properties of two elements...Ch. 7 - 7.2
The colored spheres represent the ions Based...Ch. 7 - Group 8A exhibits the highest first ionization...Ch. 7 - Which of the following best describes why Z eff...Ch. 7 - 7.1 Briefly describe the significance of...Ch. 7 - What is Moseley's contribution to the modern...Ch. 7 - 7.3 Describe the general layout of a modern...Ch. 7 - 7.4 What is the most important relationship among...Ch. 7 - Prob. 5QPCh. 7 - Prob. 6QPCh. 7 - Prob. 7QPCh. 7 - 7.8 What is a main group element? Give names and...Ch. 7 - 7.9 Without referring to a periodic table, write...Ch. 7 - Prob. 10QPCh. 7 - You are given a sample of a dark, shiny solid and...Ch. 7 - What are valence electrons? For main group...Ch. 7 - Write the outer electron configurations for the...Ch. 7 - Use the first-row transition metals ( Sc to Cu )...Ch. 7 - Arsenic is not an essential element for the human...Ch. 7 - 7.16 In the periodic table, the element hydrogen...Ch. 7 - 7.17 A neutral atom of a certain element has 34...Ch. 7 - 7.18 Group the following electron configurations...Ch. 7 - Group the following electron configurations in...Ch. 7 - Prob. 20QPCh. 7 - Specify the group of the periodic table in which...Ch. 7 - Prob. 22QPCh. 7 - Explain why the atomic radius of Be is smaller...Ch. 7 - The electron configuration of B is 1 S 2 2 S 2 2 P...Ch. 7 - 7 25 The electron configuration of C is . (a) If...Ch. 7 - Define atomic radius. Does the size of an atom...Ch. 7 - How does atomic radius change (a) from left to...Ch. 7 - Prob. 28QPCh. 7 - Sketch the outline of the periodic table, and show...Ch. 7 - Prob. 30QPCh. 7 - Explain the trends in electron affinity from...Ch. 7 - A hydrogen-like ion is an ion containing only one...Ch. 7 - Prob. 33QPCh. 7 - On the basis of their positions in the periodic...Ch. 7 - 7.35 Arrange the following atoms in order of...Ch. 7 - 7.36 Which is the largest atom in the third period...Ch. 7 - Which is the smallest atom in Group 7A ?Ch. 7 - Based on size, identify the spheres shown as Na,...Ch. 7 - Based on size, identify the spheres shown as K,...Ch. 7 - Why is the radius of the lithium atom considerably...Ch. 7 - Use the second period of the periodic table as an...Ch. 7 - Arrange the following in order of increasing first...Ch. 7 - Arrange the following in order of increasing first...Ch. 7 - 7.44 Use the third period of the periodic table as...Ch. 7 - In general, the first ionization energy increases...Ch. 7 - Prob. 46QPCh. 7 - 7.47 Two atoms have the electron configurations ....Ch. 7 - Prob. 48QPCh. 7 - Specify which of the following elements you would...Ch. 7 - Considering their electron affinities, do you...Ch. 7 - Explain why alkali metals have a greater affinity...Ch. 7 - 7.52 How does the electron configuration of ions...Ch. 7 - 7.53 What do we mean when we say that two ions or...Ch. 7 - Prob. 54QPCh. 7 - Give three examples of first-row transition metal...Ch. 7 - A M 2+ ion derived from a metal in the first...Ch. 7 - A metal ion with a net +3 charge has five...Ch. 7 - Prob. 58QPCh. 7 - 7.59 Group the species that are isoelectronic: .
Ch. 7 - 7.60 Write the ground-state electron...Ch. 7 - Prob. 61QPCh. 7 - 7.62 Which of the following species are...Ch. 7 - Prob. 63QPCh. 7 - Prob. 64QPCh. 7 - Indicate which one of the two species in each of...Ch. 7 - Prob. 66QPCh. 7 - Prob. 67QPCh. 7 - Prob. 68QPCh. 7 - Prob. 69QPCh. 7 - Prob. 70QPCh. 7 - Prob. 71QPCh. 7 - Prob. 72QPCh. 7 - Prob. 73QPCh. 7 - Prob. 74QPCh. 7 - Prob. 75QPCh. 7 - Prob. 76QPCh. 7 - Prob. 77QPCh. 7 - Prob. 78QPCh. 7 - 7 79 Write balanced equations for the reactions...Ch. 7 - Write formulas for and name the binary hydrogen...Ch. 7 - Prob. 81QPCh. 7 - Prob. 82APCh. 7 - Prob. 83APCh. 7 - Write equations representing the following...Ch. 7 - Prob. 85APCh. 7 - Write the empirical (or molecular) formulas of...Ch. 7 - 7.87 Arrange the following species in...Ch. 7 - In which of the following are the species written...Ch. 7 - Which of the following properties show a clear...Ch. 7 - Prob. 90APCh. 7 - Prob. 91APCh. 7 - 7.92 For each pair of elements listed, give three...Ch. 7 - Prob. 93APCh. 7 - Explain why the first electron affinity of sulfur...Ch. 7 - Prob. 95APCh. 7 - 7.96 Predict the products of the following oxides...Ch. 7 - 7.97 write the formulas and names of the oxides of...Ch. 7 - Prob. 98APCh. 7 - The formula for calculating the energies of an...Ch. 7 - 7.100 Why do noble gases have negative electron...Ch. 7 - 7.101 The atomic radius of K is 227 pm and that of...Ch. 7 - 7.102 The atomic radius of F is 72 pm and that of ...Ch. 7 - Match each of the elements on the right with its...Ch. 7 - Prob. 104APCh. 7 - Prob. 105APCh. 7 - Prob. 106APCh. 7 - Prob. 107APCh. 7 - Explain, in terms of their electron...Ch. 7 - 7.109 Write the formulas and names of the hydrides...Ch. 7 - Prob. 110APCh. 7 - Prob. 111APCh. 7 - Prob. 112APCh. 7 - Most transition metal ions are colored. For...Ch. 7 - Prob. 114APCh. 7 - Prob. 115APCh. 7 - Prob. 116APCh. 7 - 7.117 Although it is possible to determine the...Ch. 7 - Prob. 118APCh. 7 - Prob. 119APCh. 7 - Predict the atomic number and ground-state...Ch. 7 - Prob. 121APCh. 7 - 7.122 Match each of the elements on the right with...Ch. 7 - One way to estimate the effective charge ( Z eff )...Ch. 7 - Use your knowledge of thermochemistry to calculate...Ch. 7 - Prob. 125APCh. 7 - 7.126 On one graph, plot the effective nuclear...Ch. 7 - 7.127 One allotropic form of an element X is a...Ch. 7 - 7.128 Calculate the maximum wavelength of light...Ch. 7 - Prob. 129APCh. 7 - Element M is a shiny and highly reactive metal (...Ch. 7 - Write the ground-state electron configurations of...Ch. 7 - Thallium (Tl) is a neurotoxin and exists mostly in...Ch. 7 - Both Mg 2+ and Ca 2+ are important biological...Ch. 7 - Prob. 134APCh. 7 - Prob. 135APCh. 7 - Prob. 136APCh. 7 - Prob. 137APCh. 7 - 7.138 The ionization energy of a certain element...Ch. 7 - 7.139 Experimentally, the electron affinity of an...Ch. 7 - A halogen has valence electrons in which orbitals?...Ch. 7 - Prob. 2SEPPCh. 7 - Prob. 3SEPPCh. 7 - Prob. 4SEPP
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- Draw all formal charges on the structures below as is and draw 1 resonance structure that is more stable.arrow_forwardPart II. xiao isolated a compound TAD (Ca H 10 N₂) from tobacco and obtained its IR spectrum. Xiao proposed a chemical structure shown below: % Transmittance 4000 3500 3000 2500 2000 Wavenumber (cm-1) 1500 1000 (a) Explain why her proposed structure is inconsistent with the IR spectrum obtained (b) TAD exists as a tautomer of the structure xiao proposed. Draw the structure and explain why it is more compatible with the obtained spectrum. (C) what is the possible source for the fairly intense signal at 1621cm1arrow_forwardAE>AE₁ (Y/N) AE=AE₁ (Y/N) AEarrow_forwardTreatment of 2-phenylpropan-2-amine with methyl 2,4-dibromobutanoate in the presence of a nonnucleophilic base, R3N, involves two successive SN2 reactions and gives compound A. ? NH2 Br Br Propose a structural formula for compound A. You do not have to explicitly draw H atoms. You do not have to consider stereochemistry. In cases where there is more than one answer, just draw one. R3N C14H19NO2 + 2 R3NH*Br Aarrow_forwardCorrectly name this compound using the IUPAC naming system by sorting the components into the correct order. Br IN Ν Harrow_forwardHow is the radical intermediate for this structure formed? Can you please draw arrows from the first radical to the resonance form that would result in this product? I'm lost.arrow_forwardPart VI. (a) calculate the λ max of the compound using woodward - Fieser rules. (b) what types of electronic transitions are present in the compound? (c) what are the prominent peaks in the IR spectrum of the compound?arrow_forwardDon't used Ai solutionarrow_forwardPlease correct answer and don't used hand raitingarrow_forward↑ 0 Quiz List - RCC430M_RU05 X Aktiv Learning App × Qdraw resonance structure ×Q draw resonance structure xb My Questions | bartleby ×+ https://app.aktiv.com Draw a resonance structure of pyrrole that has the same number of pi bonds as the original structure. Include all lone pairs in your structure. + N H a 5 19°F Cloudy Q Search Problem 12 of 15 Atoms, Bonds and Rings Charges and Lone Pairs myhp हजु Undo Reset Remove Done Submit Drag To Pan 2:15 PM 1/25/2025arrow_forwardDon't used hand raitingarrow_forwardDon't used hand raiting and don't used Ai solutionarrow_forwardarrow_back_iosSEE MORE QUESTIONSarrow_forward_ios
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