Chemistry
3rd Edition
ISBN: 9780073402734
Author: Julia Burdge
Publisher: MCGRAW-HILL HIGHER EDUCATION
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Textbook Question
Chapter 7, Problem 2QP
What is Moseley's contribution to the modern periodic table?
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Question 11 of 18 (1 point) Question Attempt: 3 of
How many signals do you expect in the 'H NMR spectrum for this molecule?
Br
Br
Write the answer below.
Also, in each of the drawing areas below is a copy of the molecule, with Hs shown. In each copy, one of the H atoms is colored red. Highlight in red all other H
atoms that would contribute to the same signal as the H already highlighted red.
Note for advanced students: In this question, any multiplet is counted as one signal.
Number of signals in the 'H NMR spectrum.
1
For the molecule in the top drawing area, highlight in red any other H atoms that will contribute to
the same signal as the H atom already highlighted red.
If no other H atoms will contribute, check the box at right.
No additional Hs to color in top
molecule
Check
For the molecule in the bottom drawing area, highlight in red any other H atoms that will contribute
to the same signal as the H atom already highlighted red.
If no other H atoms will contribute, check the box…
Organic Chemistry
Esterification reactions
1. Write the steps to prepare ester.
2. Write complete reaction of ethanol and acetic acid to make ester.
3. What does ester smell like? What are the uses of ester.
4. What the role of sulfuric acid in the esterification reaction
11. Complete the following esterification reaction with names of all the reactants and products under.
Hint: Remove the water and end up with ester
R-C-OH + ROH
R-C-OR + H₂O
A carboxylic acid
An alcohol
An ester
Water
BYJU'S
H-C-C
O-H
Нин
C-C-C-H
HAAA
H O-C-C-C-H
AAA
Ethanoic acid
Propanol
Water Propyl ethanoate
By com
CH3COOH + CH3CH2CH2CH₂CH₂OH →
Practice for alcohols aldehydes and ketones:
12. Draw the structures from the following names mixed of alcohol/aldehyde and ketone:
a. 4-methyl cyclohexanone
b. 3-methyl-2-pentenal
c. 2,3-dimethylcyclohexanone
d. 1,3propanediol or Propane 1,3 diol
13. Write systematic names for the following compounds identify
functional group:
a.
b. (CH3)2CH-C
OH
c) CH(CH₂)--
OH
-,-,
Chapter 7 Solutions
Chemistry
Ch. 7.1 - Practice Problem ATTEMPT What element(s) would you...Ch. 7.1 - Practice Problem BUILD
Arrange the following...Ch. 7.1 - Practice ProblemCONCEPTUALIZE Three different...Ch. 7.1 - 7.1.1 Which of the following elements would you...Ch. 7.1 - Prob. 2CPCh. 7.1 - Prob. 3CPCh. 7.2 - Practice Problem ATTEMPT Without using a periodic...Ch. 7.2 - Practice ProblemBUILD Identify the elements...Ch. 7.2 - Prob. 1PPCCh. 7.2 - 7.2.1 Which electron configuration is correct for...
Ch. 7.2 - Which of the following equations correctly...Ch. 7.3 - Practice Problem ATTEMPT Referring only to a...Ch. 7.3 - Practice Problem BUILD
For which of the following...Ch. 7.3 - Practice Problem CONCEPTUALIZE
Based on size and...Ch. 7.4 - Practice Problem ATTEMPT Which element. Mg or Al,...Ch. 7.4 - Prob. 1PPBCh. 7.4 - Practice ProblemCONCEPTUALIZE Imagine an...Ch. 7.4 - 7.4.1 Arrange the elements in order of increasing...Ch. 7.4 - Arrange the elements Li. Be. and B in order of...Ch. 7.4 - For each of the following pairs of elements,...Ch. 7.4 - Prob. 4CPCh. 7.5 - Practice ProblemATTEMPT Would you expect Mg or Al...Ch. 7.5 - Prob. 1PPBCh. 7.5 - Practice ProblemCONCEPTUALIZE In the same...Ch. 7.5 - Prob. 1CPCh. 7.5 - 7.5.2 Which of the following pairs are...Ch. 7.5 - 7.5.3 Select the correct ground-state electron...Ch. 7.5 - Prob. 4CPCh. 7.6 - Practice Problem ATTEMPT Between which two charges...Ch. 7.6 - Practice ProblemBUILD What must the distance be...Ch. 7.6 - Prob. 1PPCCh. 7.6 - Which of the following species are isoelectronic...Ch. 7.6 - Which of the following are arranged correctly in...Ch. 7.6 - 7.6.3 Which of the following is the most realistic...Ch. 7.6 - Which of the following is the most realistic...Ch. 7.7 - Practice Problem ATTEMPT Write electron...Ch. 7.7 - Practice ProblemBUILD List all the species (atoms...Ch. 7.7 - Practice Problem CONCEPTUALIZE
Select the correct...Ch. 7.8 - Practice Problem ATTEMPT
Write electron...Ch. 7.8 - Practice Problem BUILD
What common d-block ion...Ch. 7.8 - Prob. 1PPCCh. 7.9 - Practice ProblemATTEMPT Arrange the following...Ch. 7.9 - Practice Problem BUILD
List all the common ions...Ch. 7.9 - Practice ProblemCONCEPTUALIZE Which periodic...Ch. 7 - Often we can compare properties of two elements...Ch. 7 - 7.2
The colored spheres represent the ions Based...Ch. 7 - Group 8A exhibits the highest first ionization...Ch. 7 - Which of the following best describes why Z eff...Ch. 7 - 7.1 Briefly describe the significance of...Ch. 7 - What is Moseley's contribution to the modern...Ch. 7 - 7.3 Describe the general layout of a modern...Ch. 7 - 7.4 What is the most important relationship among...Ch. 7 - Prob. 5QPCh. 7 - Prob. 6QPCh. 7 - Prob. 7QPCh. 7 - 7.8 What is a main group element? Give names and...Ch. 7 - 7.9 Without referring to a periodic table, write...Ch. 7 - Prob. 10QPCh. 7 - You are given a sample of a dark, shiny solid and...Ch. 7 - What are valence electrons? For main group...Ch. 7 - Write the outer electron configurations for the...Ch. 7 - Use the first-row transition metals ( Sc to Cu )...Ch. 7 - Arsenic is not an essential element for the human...Ch. 7 - 7.16 In the periodic table, the element hydrogen...Ch. 7 - 7.17 A neutral atom of a certain element has 34...Ch. 7 - 7.18 Group the following electron configurations...Ch. 7 - Group the following electron configurations in...Ch. 7 - Prob. 20QPCh. 7 - Specify the group of the periodic table in which...Ch. 7 - Prob. 22QPCh. 7 - Explain why the atomic radius of Be is smaller...Ch. 7 - The electron configuration of B is 1 S 2 2 S 2 2 P...Ch. 7 - 7 25 The electron configuration of C is . (a) If...Ch. 7 - Define atomic radius. Does the size of an atom...Ch. 7 - How does atomic radius change (a) from left to...Ch. 7 - Prob. 28QPCh. 7 - Sketch the outline of the periodic table, and show...Ch. 7 - Prob. 30QPCh. 7 - Explain the trends in electron affinity from...Ch. 7 - A hydrogen-like ion is an ion containing only one...Ch. 7 - Prob. 33QPCh. 7 - On the basis of their positions in the periodic...Ch. 7 - 7.35 Arrange the following atoms in order of...Ch. 7 - 7.36 Which is the largest atom in the third period...Ch. 7 - Which is the smallest atom in Group 7A ?Ch. 7 - Based on size, identify the spheres shown as Na,...Ch. 7 - Based on size, identify the spheres shown as K,...Ch. 7 - Why is the radius of the lithium atom considerably...Ch. 7 - Use the second period of the periodic table as an...Ch. 7 - Arrange the following in order of increasing first...Ch. 7 - Arrange the following in order of increasing first...Ch. 7 - 7.44 Use the third period of the periodic table as...Ch. 7 - In general, the first ionization energy increases...Ch. 7 - Prob. 46QPCh. 7 - 7.47 Two atoms have the electron configurations ....Ch. 7 - Prob. 48QPCh. 7 - Specify which of the following elements you would...Ch. 7 - Considering their electron affinities, do you...Ch. 7 - Explain why alkali metals have a greater affinity...Ch. 7 - 7.52 How does the electron configuration of ions...Ch. 7 - 7.53 What do we mean when we say that two ions or...Ch. 7 - Prob. 54QPCh. 7 - Give three examples of first-row transition metal...Ch. 7 - A M 2+ ion derived from a metal in the first...Ch. 7 - A metal ion with a net +3 charge has five...Ch. 7 - Prob. 58QPCh. 7 - 7.59 Group the species that are isoelectronic: .
Ch. 7 - 7.60 Write the ground-state electron...Ch. 7 - Prob. 61QPCh. 7 - 7.62 Which of the following species are...Ch. 7 - Prob. 63QPCh. 7 - Prob. 64QPCh. 7 - Indicate which one of the two species in each of...Ch. 7 - Prob. 66QPCh. 7 - Prob. 67QPCh. 7 - Prob. 68QPCh. 7 - Prob. 69QPCh. 7 - Prob. 70QPCh. 7 - Prob. 71QPCh. 7 - Prob. 72QPCh. 7 - Prob. 73QPCh. 7 - Prob. 74QPCh. 7 - Prob. 75QPCh. 7 - Prob. 76QPCh. 7 - Prob. 77QPCh. 7 - Prob. 78QPCh. 7 - 7 79 Write balanced equations for the reactions...Ch. 7 - Write formulas for and name the binary hydrogen...Ch. 7 - Prob. 81QPCh. 7 - Prob. 82APCh. 7 - Prob. 83APCh. 7 - Write equations representing the following...Ch. 7 - Prob. 85APCh. 7 - Write the empirical (or molecular) formulas of...Ch. 7 - 7.87 Arrange the following species in...Ch. 7 - In which of the following are the species written...Ch. 7 - Which of the following properties show a clear...Ch. 7 - Prob. 90APCh. 7 - Prob. 91APCh. 7 - 7.92 For each pair of elements listed, give three...Ch. 7 - Prob. 93APCh. 7 - Explain why the first electron affinity of sulfur...Ch. 7 - Prob. 95APCh. 7 - 7.96 Predict the products of the following oxides...Ch. 7 - 7.97 write the formulas and names of the oxides of...Ch. 7 - Prob. 98APCh. 7 - The formula for calculating the energies of an...Ch. 7 - 7.100 Why do noble gases have negative electron...Ch. 7 - 7.101 The atomic radius of K is 227 pm and that of...Ch. 7 - 7.102 The atomic radius of F is 72 pm and that of ...Ch. 7 - Match each of the elements on the right with its...Ch. 7 - Prob. 104APCh. 7 - Prob. 105APCh. 7 - Prob. 106APCh. 7 - Prob. 107APCh. 7 - Explain, in terms of their electron...Ch. 7 - 7.109 Write the formulas and names of the hydrides...Ch. 7 - Prob. 110APCh. 7 - Prob. 111APCh. 7 - Prob. 112APCh. 7 - Most transition metal ions are colored. For...Ch. 7 - Prob. 114APCh. 7 - Prob. 115APCh. 7 - Prob. 116APCh. 7 - 7.117 Although it is possible to determine the...Ch. 7 - Prob. 118APCh. 7 - Prob. 119APCh. 7 - Predict the atomic number and ground-state...Ch. 7 - Prob. 121APCh. 7 - 7.122 Match each of the elements on the right with...Ch. 7 - One way to estimate the effective charge ( Z eff )...Ch. 7 - Use your knowledge of thermochemistry to calculate...Ch. 7 - Prob. 125APCh. 7 - 7.126 On one graph, plot the effective nuclear...Ch. 7 - 7.127 One allotropic form of an element X is a...Ch. 7 - 7.128 Calculate the maximum wavelength of light...Ch. 7 - Prob. 129APCh. 7 - Element M is a shiny and highly reactive metal (...Ch. 7 - Write the ground-state electron configurations of...Ch. 7 - Thallium (Tl) is a neurotoxin and exists mostly in...Ch. 7 - Both Mg 2+ and Ca 2+ are important biological...Ch. 7 - Prob. 134APCh. 7 - Prob. 135APCh. 7 - Prob. 136APCh. 7 - Prob. 137APCh. 7 - 7.138 The ionization energy of a certain element...Ch. 7 - 7.139 Experimentally, the electron affinity of an...Ch. 7 - A halogen has valence electrons in which orbitals?...Ch. 7 - Prob. 2SEPPCh. 7 - Prob. 3SEPPCh. 7 - Prob. 4SEPP
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- may you please show all steps! i am having a hard time understanding and applying in this format, thank you!arrow_forward10. Complete the substitution reaction of 2 pentanol with these reagents. Reagents & Reaction Conditions use practice sheet. Please write only major products, minor product like water, other gases are not required. Hint: In substitution of alcohol, we generally substitute OH group with Halogens like cl, Br, F using some reagent containing halogens. Ensure to add halogens to the same carbon number where you are removing OH from Examples Alcohols can be converted to Alkyl Halides with HX acids HBr H₂O HCI + H₂O HI + H₂O CH,CH₂OH + SOCI₂ CH,CH₂OH + PCI₁₂ A BBYJU'S CH CHCI + SO₂+ HCI CH₂CH CIP(OH), + HCI CH,CH₂OH + PCI CHCHCI + POCI + HCI CH,CH₂OH + PBr, CH,CH,Br + P(OH), + HBr 1. Reaction with HBr with 2 Pentanol 2.Reaction with HI with 2 pentanol © Byjus.com 3.Reaction with HCI+ZnCl,, with 2 pentanol (Zncl2 is catalyst no role) 4.Reaction with SOCI,, with 2 Pentanol 5.Reaction with PBr; or PCl, with 2 pentanolarrow_forward3. Is 2-methyl-2-propanol a primary, secondary, or tertiary alcohol? Write out the structures of 2-methyl-2-propanol and also any oxidation products of 2- methyl-2- propanol. If there is more than one oxidation product, give the structure of each of the products. 4. 2-Propanol is the IUPAC systematic name of this alcohol. It has a common name by which it is much better known (You'll see it in the grocery store or pharmacy). Give that common name 5. Aldehydes can be synthesized by the oxidation of. Please choose from below choices A. Primary alcohols B. Secondary alcohols C. Organic acids D. Inorganic acids 6. Tertiary alcohol Can undergo oxidation. yes or no. ? If yes then answer the product.arrow_forward
- Finish the reactions hand written pleasearrow_forwardPart A Identify each alcohol as primary, secondary, or tertiary Drag the appropriate items to their respective bins. CH₂ H₂C- -C-OH HO CH₂ Primary Он OH CH₂ OH CCH₂OH CH₂ сн Secondary Tertiary Reset Help CH,CH₂ (CH)CHCH,OH CH,CH,CH,CCH, CHOH CH₂ Different types of alcohol groups Alcohol and its reaction: 8. Combing two alcohol molecules below and completing the reaction with Product .( Hint Reaction called etherification as ether is formed and name the ether once you complete the reaction. Hint.: R-O-H+H-O-RR-O-R Do the reaction: CH₂OH + CH₂OH---→ + H-O-H 9. Write the reaction of formation of alcohol from alkene by adding water: Addition reaction also called hydration reaction as we are adding water which occur always in presence of acid Hint: Break the double bond and add H and OH if symmetrical then add anywhere if unsymmetrical then follow Markovnikov rule H should go to that double bone carbon which has more hydrogen CH2=CH2 + H₂O-→arrow_forwardComplete the reaction hand written pleasearrow_forward
- Predict the major products of this organic reaction: HBr (1 equiv) cold ? Some important notes: • Draw the major product, or products, of this reaction in the drawing area below. • You can draw the products in any arrangement you like. • Pay careful attention to the reaction conditions, and only include the major products. • Be sure to use wedge and dash bonds when necessary, for example to distinguish between major products that are enantiomers. • Note that there is only 1 equivalent of HBr reactant, so you need not consider the case of multiple additions. dm Re Explanation Check ©2025 McGraw Hill LLC. All Rights Reserved. Termarrow_forwardb) Use curved arrows to show the reaction of the radical with hydrogen bromide. Br: Br H .. Answer Bankarrow_forwardIndicate the reaction products when CH3COCH2COOCH2COOC2H5 (ethyl acetoacetoacetate) reacts with 1º OH-/H2O and 2º H3O+arrow_forward
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