Introductory Chemistry: A Foundation
Introductory Chemistry: A Foundation
9th Edition
ISBN: 9781337399425
Author: Steven S. Zumdahl, Donald J. DeCoste
Publisher: Cengage Learning
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Chapter 7, Problem 20CR
Interpretation Introduction

(a)

Interpretation:

Given chemical equation should be balanced. Whether the equation can be classified as oxidation-reduction reactions should be mentioned.

Concept Introduction:

Balanced chemical equation gives the details about the identities of the reactants and products and also how much of each reactant and product participate in the reaction. The numbers in the balanced equation (coefficients) enable us to determine how much product we can get from a given quantity of reactants.

Normally the unbalanced equations are balanced by inspection starting with the most complicated molecule. We should determine what coefficient is necessary to equalize the number of each type of atoms on both side of the arrow. The coefficients used should be the smallest integers which balance the equation.

The driving force involved in oxidation- reduction reaction is transfer of electrons between atoms and ions. While one substance is oxidized by losing electrons, another species takes up that electron and get reduced.

Expert Solution
Check Mark

Answer to Problem 20CR

FeO(s) + 2 HNO3(aq)  Fe(NO3)2(aq) + H2O(l)

This is not an oxidation reduction reaction.

Explanation of Solution

FeO(s) + HNO3(aq)  Fe(NO3)2(aq) + H2O(l)

In this unbalanced equation number of NO3 - ions in reactants side is one and two in the product side. So we place 2 before HNO3. Then the number of H atoms also gets balanced. Other atoms present in the equation are already balanced. So the balanced equation is,

FeO(s) + 2 HNO3(aq)  Fe(NO3)2(aq) + H2O(l)

This is not an oxidation reduction reaction. Any of those atoms have not changed their oxidation state. They simply have exchanged their anions. So this is a double displacement reaction, as well as due to the formation of water. This is also an acid base reaction.

Interpretation Introduction

(b)

Interpretation:

Given chemical equation should be balanced. Whether the equation can be classified as oxidation-reduction reactions should be mentioned.

Concept Introduction:

Balanced chemical equation gives the details about the identities of the reactants and products and also how much of each reactant and product participate in the reaction. The numbers in the balanced equation (coefficients) enable us to determine how much product we can get from a given quantity of reactants.

Normally the unbalanced equations are balanced by inspection starting with the most complicated molecule. We should determine what coefficient is necessary to equalize the number of each type of atoms on both side of the arrow. The coefficients used should be the smallest integers which balance the equation.

The driving force involved in oxidation- reduction reaction is transfer of electrons between atoms and ions. While one substance is oxidized by losing electrons, another species takes up that electron and get reduced.

Expert Solution
Check Mark

Answer to Problem 20CR

2 Mg(s) + 2 CO2(g) + O2(g)  2 MgCO3(s)

This is an oxidation reduction reaction.

Explanation of Solution

Mg(s) + CO2(g) + O2(g)  MgCO3(s)

There are four O atoms in the reactants side but only three in products side. In order to make the numbers equal in both sides, we place 2 before CO2 and MgCO3. Then number of Mg atom in the products side becomes two. Therefore we place 2 before Mg. So the balanced equation is,

2 Mg(s) + 2 CO2(g) + O2(g)  2 MgCO3(s)

Mg has oxidized from 0 oxidation state to + 2 oxidation state. O2 has reduced from its 0 oxidation state to -2 oxidation state. So this is an oxidation reduction reaction.

Interpretation Introduction

(c)

Interpretation:

Given chemical equation should be balanced. Whether the equation can be classified as oxidation-reduction reactions should be mentioned.

Concept Introduction:

Balanced chemical equation gives the details about the identities of the reactants and products and also how much of each reactant and product participate in the reaction. The numbers in the balanced equation (coefficients) enable us to determine how much product we can get from a given quantity of reactants.

Normally the unbalanced equations are balanced by inspection starting with the most complicated molecule. We should determine what coefficient is necessary to equalize the number of each type of atoms on both side of the arrow. The coefficients used should be the smallest integers which balance the equation.

The driving force involved in oxidation- reduction reaction is transfer of electrons between atoms and ions. While one substance is oxidized by losing electrons, another species takes up that electron and get reduced.

Expert Solution
Check Mark

Answer to Problem 20CR

2 NaOH(aq) + CuSO4(aq)  Cu(OH)2(s) + Na2SO4(aq)

This is not an oxidation reduction reaction.

Explanation of Solution

NaOH(aq) + CuSO4(aq)  Cu(OH)2(s) + Na2SO4(aq)

In the unbalanced equation, number of Na atoms in reactants side is one and in products side it’s two. So we place 2 before NaOH. Then the number of OH- ions in both sides becomes equal. Other atoms present in the equation are already balanced. So the balanced equation is,

2 NaOH(aq) + CuSO4(aq)  Cu(OH)2(s) + Na2SO4(aq)

This is not an oxidation reduction reaction as any atom does not change their oxidation state. This is a precipitation reaction as well as a double displacement reaction since the two compounds have simply exchanged their anions.

Interpretation Introduction

(d)

Interpretation:

Given chemical equation should be balanced. Whether the equation can be classified as oxidation-reduction reactions should be mentioned.

Concept Introduction:

Balanced chemical equation gives the details about the identities of the reactants and products and also how much of each reactant and product participate in the reaction. The numbers in the balanced equation (coefficients) enable us to determine how much product we can get from a given quantity of reactants.

Normally the unbalanced equations are balanced by inspection starting with the most complicated molecule. We should determine what coefficient is necessary to equalize the number of each type of atoms on both side of the arrow. The coefficients used should be the smallest integers which balance the equation.

The driving force involved in oxidation- reduction reaction is transfer of electrons between atoms and ions. While one substance is oxidized by losing electrons, another species takes up that electron and get reduced.

Expert Solution
Check Mark

Answer to Problem 20CR

HI(aq) + KOH(aq)  KI(aq) + H2O(l)

This is not an oxidation reduction reaction.

Explanation of Solution

The equation is already balanced. And this is not an oxidation reduction reaction as any atom in the equation does not change their oxidation states. This is an acid base reaction as well as a double displacement reaction, since the two reactants have simply exchanged their anions.

Interpretation Introduction

(e)

Interpretation:

Given chemical equation should be balanced. Whether the equation can be classified as oxidation-reduction reactions should be mentioned.

Concept Introduction:

Balanced chemical equation gives the details about the identities of the reactants and products and also how much of each reactant and product participate in the reaction. The numbers in the balanced equation (coefficients) enable us to determine how much product we can get from a given quantity of reactants.

Normally the unbalanced equations are balanced by inspection starting with the most complicated molecule. We should determine what coefficient is necessary to equalize the number of each type of atoms on both side of the arrow. The coefficients used should be the smallest integers which balance the equation.

The driving force involved in oxidation- reduction reaction is transfer of electrons between atoms and ions. While one substance is oxidized by losing electrons, another species takes up that electron and get reduced.

Expert Solution
Check Mark

Answer to Problem 20CR

C3H8(g) + 5 O2(g)  3 CO2(g) + 4 H2O(g)

This is an oxidation reduction reaction.

Explanation of Solution

C3H8(g) + O2(g)  CO2(g) + H2O(g)

In the unbalanced equation, number of C in reactants side is three but one in products side. So we place 3 before CO2. Number of H atoms in reactants side is eight, but only two in the products side. So we place 4 before H2 O. But then the number of O in the products side becomes 10, but there are only two in the reactants side. So we place 5 before O2. So the balanced equation is,

C3H8(g) + 5 O2(g)  3 CO2(g) + 4 H2O(g)

This is an oxidation reduction reaction. O2 is present as a reactant in this equation. If a non metal reacts with oxygen it is a sign of oxidation reduction reaction. Here the hydrocarbon is oxidized and Oxygen is reduced.

Interpretation Introduction

(f)

Interpretation:

Given chemical equation should be balanced. Whether the equation can be classified as oxidation-reduction reactions should be mentioned.

Concept Introduction:

Balanced chemical equation gives the details about the identities of the reactants and products and also how much of each reactant and product participate in the reaction. The numbers in the balanced equation (coefficients) enable us to determine how much product we can get from a given quantity of reactants.

Normally the unbalanced equations are balanced by inspection starting with the most complicated molecule. We should determine what coefficient is necessary to equalize the number of each type of atoms on both side of the arrow. The coefficients used should be the smallest integers which balance the equation.

The driving force involved in oxidation- reduction reaction is transfer of electrons between atoms and ions. While one substance is oxidized by losing electrons, another species takes up that electron and get reduced.

Expert Solution
Check Mark

Answer to Problem 20CR

Co(NH3)6Cl2(s) CoCl2(s) + 6 NH3(g)

This is not an oxidation-reduction reaction.

Explanation of Solution

Co(NH3)6Cl2(s) CoCl2(s) + NH3(g)

In the unbalanced equation, number of NH3 ligand in reactants side is six but one in products side. So we place 6 before NH3. All the other atoms in the equation are already balanced. So the balanced equation is,

Co(NH3)6Cl2(s) CoCl2(s) + 6 NH3(g)

This is not an oxidation reduction reaction as any atom in the equation does not change its oxidation state. This is a decomposition reaction.

Interpretation Introduction

(g)

Interpretation:

Given chemical equation should be balanced. Whether the equation can be classified as oxidation-reduction reactions should be mentioned.

Concept Introduction:

Balanced chemical equation gives the details about the identities of the reactants and products and also how much of each reactant and product participate in the reaction. The numbers in the balanced equation (coefficients) enable us to determine how much product we can get from a given quantity of reactants.

Normally the unbalanced equations are balanced by inspection starting with the most complicated molecule. We should determine what coefficient is necessary to equalize the number of each type of atoms on both side of the arrow. The coefficients used should be the smallest integers which balance the equation.

The driving force involved in oxidation- reduction reaction is transfer of electrons between atoms and ions. While one substance is oxidized by losing electrons, another species takes up that electron and get reduced.

Expert Solution
Check Mark

Answer to Problem 20CR

2 HCl(aq) + Pb(C2H3O2)2(aq)  2 HC2H3O2(aq) + PbCl2(s)

This is not an oxidation reduction reaction.

Explanation of Solution

HCl(aq) + Pb(C2H3O2)2(aq)  HC2H3O2(aq) + PbCl2(s)

In the unbalanced equation, number of C2 H3 O2 - ligand in the reactants side is two and one in the products side. So we place 2 before HC2 H3 O2. And the number of Cl atoms in reactants side is one but it is two in the product side. So we place 2 before HCl. Then all the other atoms become balanced. So the balanced equation is,

2 HCl(aq) + Pb(C2H3O2)2(aq)  2 HC2H3O2(aq) + PbCl2(s)

This is not an oxidation reduction reaction as any atom does not change their oxidation states. This is a precipitation reaction as well as a double displacement reaction, since the two reactants have exchanged their anions.

Interpretation Introduction

(h)

Interpretation:

Given chemical equation should be balanced. Whether the equation can be classified as oxidation-reduction reactions should be mentioned.

Concept Introduction:

Balanced chemical equation gives the details about the identities of the reactants and products and also how much of each reactant and product participate in the reaction. The numbers in the balanced equation (coefficients) enable us to determine how much product we can get from a given quantity of reactants.

Normally the unbalanced equations are balanced by inspection starting with the most complicated molecule. We should determine what coefficient is necessary to equalize the number of each type of atoms on both side of the arrow. The coefficients used should be the smallest integers which balance the equation.

The driving force involved in oxidation- reduction reaction is transfer of electrons between atoms and ions. While one substance is oxidized by losing electrons, another species takes up that electron and get reduced.

Expert Solution
Check Mark

Answer to Problem 20CR

C12H22O11(s)  12 C(S) + 11 H2O(g)

This is an oxidation reduction reaction.

Explanation of Solution

C12H22O11(s)  C(S) + H2O(g)

In the unbalanced equation, number of C atoms in the reactants side is twelve but in the products side it is one. So we place 12 before C. Number of H atoms in the reactants side is 22, but in the products side it is two. So we place 11 before H2 O. Then the number of O atoms also becomes equal in both sides. So the balanced equation is,

C12H22O11(s)  12 C(S) + 11 H2O(g)

This is an oxidation reduction reaction. C in C1 2 H2 2 O1 1 is reduced into C. And H in C1 2 H2 2 O1 1 has oxidized into H2 O. This is also a decomposition reaction.

Interpretation Introduction

(i)

Interpretation:

Given chemical equation should be balanced. Whether the equation can be classified as oxidation-reduction reactions should be mentioned.

Concept Introduction:

Balanced chemical equation gives the details about the identities of the reactants and products and also how much of each reactant and product participate in the reaction. The numbers in the balanced equation (coefficients) enable us to determine how much product we can get from a given quantity of reactants.

Normally the unbalanced equations are balanced by inspection starting with the most complicated molecule. We should determine what coefficient is necessary to equalize the number of each type of atoms on both side of the arrow. The coefficients used should be the smallest integers which balance the equation.

The driving force involved in oxidation- reduction reaction is transfer of electrons between atoms and ions. While one substance is oxidized by losing electrons, another species takes up that electron and get reduced.

Expert Solution
Check Mark

Answer to Problem 20CR

2 Al(s) + 6 HNO3  2 Al(NO3)3(aq) + 3 H2(g)

This is an oxidation reduction reaction.

Explanation of Solution

Al(s) + HNO3  Al(NO3)3(aq) + H2(g)

In the unbalanced equation, number of NO3 - ions in the reactants side is one but in the products side it is three. So we place 3 before HNO3. Then the number of H atoms in the reactants side becomes three, but in the products side it is two. So we place 6 before HNO3 and 3 before H2. Then the number of NO3 - ions becomes six in the reactants side. So we place 2 before Al(NO3 )3. Then number of Al atoms in the products side becomes two. So we place 2 before Al. finally the balanced equation is,

2 Al(s) + 6 HNO3  2 Al(NO3)3(aq) + 3 H2(g)

This is an oxidation reduction reaction. Al has oxidized form its 0 oxidation state to + 3 oxidation state and H has reduced from + 1 oxidation state into 0 oxidation state. This is also a single displacement reaction, since only H is displaced by Al in this reaction.

Interpretation Introduction

(j)

Interpretation:

Given chemical equation should be balanced. Whether the equation can be classified as oxidation-reduction reactions should be mentioned.

Concept Introduction:

Balanced chemical equation gives the details about the identities of the reactants and products and also how much of each reactant and product participate in the reaction. The numbers in the balanced equation (coefficients) enable us to determine how much product we can get from a given quantity of reactants.

Normally the unbalanced equations are balanced by inspection starting with the most complicated molecule. We should determine what coefficient is necessary to equalize the number of each type of atoms on both side of the arrow. The coefficients used should be the smallest integers which balance the equation.

The driving force involved in oxidation- reduction reaction is transfer of electrons between atoms and ions. While one substance is oxidized by losing electrons, another species takes up that electron and get reduced.

Expert Solution
Check Mark

Answer to Problem 20CR

4 B(s) + 3 O2(g)  2 B2O3(s) 

This is an oxidation reduction reaction.

Explanation of Solution

B(s) + O2(g)  B2O3(s) 

In the unbalanced equation, number of O atoms in the reactants side is two but in the products side it is three. So we place 3 before O2 and 2 before B2 O3. Then the number of B atoms in the products side becomes four. So we place 4 before B. So the balanced equation is,

4 B(s) + 3 O2(g)  2 B2O3(s) 

This is an oxidation reduction reaction. B has oxidized from 0 oxidation state to + 3 oxidation state and O has reduced from 0 oxidation state to -2 oxidation state. This is also a synthesis reaction, since all the reactants are natural state elements forming B2 O3.

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Chapter 7 Solutions

Introductory Chemistry: A Foundation

Ch. 7 - ixing an aqueous solution of potassium nitrate...Ch. 7 - Prob. 6ALQCh. 7 - se the Arrhenius definition of acids and bases to...Ch. 7 - Prob. 8ALQCh. 7 - hy is the formation of a gas evidence of a...Ch. 7 - Label each of the following statements as true or...Ch. 7 - Look at Fig. 7.2 in the text. It is possible for a...Ch. 7 - What is the purpose of spectator ions? If they are...Ch. 7 - Which of the following must be an...Ch. 7 - If an element is a reactant or product in a...Ch. 7 - Prob. 15ALQCh. 7 - On the basis of the general solubility rules given...Ch. 7 - Write the balanced formula and net ionic equation...Ch. 7 - hy is water an important solvent? Although you...Ch. 7 - hat is a “driving force”? What are some of the...Ch. 7 - Prob. 3QAPCh. 7 - Prob. 4QAPCh. 7 - escribe briefly what happens when an ionic...Ch. 7 - hen the ionic solute K3PO4is dissolved in water,...Ch. 7 - Prob. 7QAPCh. 7 - ow do chemists know that the ions behave...Ch. 7 - uppose you are trying to help your friend...Ch. 7 - Using the general solubility rules given in Table...Ch. 7 - On the basis of the general solubility rules given...Ch. 7 - On the basis of the general solubility rules given...Ch. 7 - On the basis of the general solubility rules given...Ch. 7 - On the basis of the general solubility rules given...Ch. 7 - On the basis of the general solubility rules given...Ch. 7 - Lead(II) nitrate is added to four separate beakers...Ch. 7 - On the basis of the general solubility rules given...Ch. 7 - On the basis of the general solubility rules given...Ch. 7 - Balance each of the following equations that...Ch. 7 - Balance each of the following equations that...Ch. 7 - For each of the following precipitation reactions,...Ch. 7 - A solution of zinc nitrate is mixed with a...Ch. 7 - What is a net ionic equation? What species are...Ch. 7 - Prob. 24QAPCh. 7 - Based on the general solubility rules given in...Ch. 7 - Write the balanced molecular, complete ionic, and...Ch. 7 - Many chromate salts are insoluble, and most have...Ch. 7 - The procedures and principles of qualitative...Ch. 7 - Many plants are poisonous because their stems and...Ch. 7 - Prob. 30QAPCh. 7 - What is meant by a strong acid? Are the strong...Ch. 7 - What is meant by a strong base? Are the strong...Ch. 7 - The same net ionic process takes place when any...Ch. 7 - Prob. 34QAPCh. 7 - If 1000 NaOH units were dissolved in a sample of...Ch. 7 - What is a salt? Give two balanced chemical...Ch. 7 - Write balanced equations showing how three of the...Ch. 7 - Prob. 38QAPCh. 7 - What salt would form when each of the following...Ch. 7 - Prob. 40QAPCh. 7 - Prob. 41QAPCh. 7 - Give an example of a simple chemical reaction that...Ch. 7 - What do we mean when we say that the transfer of...Ch. 7 - Prob. 44QAPCh. 7 - If atoms of the metal calcium were to react with...Ch. 7 - If oxygen molecules, were to react with magnesium...Ch. 7 - Prob. 47QAPCh. 7 - Prob. 48QAPCh. 7 - Prob. 49QAPCh. 7 - Prob. 50QAPCh. 7 - Prob. 51QAPCh. 7 - The reaction between ammonium perchlorate and...Ch. 7 - Identify each of the following unbalanced reaction...Ch. 7 - Prob. 54QAPCh. 7 - Prob. 55QAPCh. 7 - Prob. 56QAPCh. 7 - What is a synthesis or combination reaction? Give...Ch. 7 - What is a decomposition reaction? Give an example....Ch. 7 - Complete and balance each of the following...Ch. 7 - Prob. 60QAPCh. 7 - Prob. 61QAPCh. 7 - Prob. 62QAPCh. 7 - Balance each of the following equations that...Ch. 7 - Prob. 64QAPCh. 7 - Balance each of the following equations that...Ch. 7 - Prob. 66QAPCh. 7 - Distinguish between the molecular equation, the...Ch. 7 - Prob. 68APCh. 7 - Without first writing a full molecular or ionic...Ch. 7 - Complete and balance each of the following...Ch. 7 - Prob. 71APCh. 7 - Prob. 72APCh. 7 - Prob. 73APCh. 7 - Prob. 74APCh. 7 - For each of the following unbalanced molecular...Ch. 7 - Write the balanced molecular, complete ionic, and...Ch. 7 - What strong acid and what strong base would react...Ch. 7 - Prob. 78APCh. 7 - For the reaction 16Fe(s)+3S8(s)8Fe2S3(s), show how...Ch. 7 - Prob. 80APCh. 7 - Identify each of the following unbalanced reaction...Ch. 7 - Which of the following statements is/are true...Ch. 7 - Prob. 83APCh. 7 - Prob. 84APCh. 7 - Prob. 85APCh. 7 - Prob. 86APCh. 7 - Prob. 87APCh. 7 - For each of the following metals, how many...Ch. 7 - For each of the following nonmetals, how many...Ch. 7 - True or false? 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