Organic Chemistry
12th Edition
ISBN: 9781118875766
Author: T. W. Graham Solomons, Craig B. Fryhle, Scott A. Snyder
Publisher: WILEY
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Chapter 7, Problem 19PP
Interpretation Introduction
Interpretation:
The products of the given acid–base reactions are to be predicted and, in each case, the stronger acid, the stronger base, the weaker acid, and the weaker base are to be labeled.
Concept introduction:
Substitution reaction: A reaction in which one of the hydrogen atoms of a hydrocarbon, or a
Elimination reaction: A reaction in which two substituent groups are detached and a double bond is formed is called elimination reaction.
Addition reaction: It is the reaction in which unsaturated bonds are converted to saturated molecules by addition of molecules.
Sodium amide is a strong base that helps in the removal of terminal hydrogen of
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For the Brønsted acid-base reaction shown below, determine the conjugate acid- base pairs.
Then give the curved-arrow notation for the reaction in the left-to-right direction
:0:
:O:
Нзс-
H–Ö-H
->
Нзс
A
D
Fill in the blanks with the letters A,B,C, and D, representing the species in the reaction above.
(It doesn't matter which pair you list first.)
Pair 1:
Pair 2:
acid and its conjugate base
acid and its conjugate base
6. Predict the products of the following acid-base reactions, and predict whether the equilibrium lies to the left or to the right of the reaction arrow:
(a) O2-(aq) + H2O(1)<--->
(b) CH3COOH(aq) + HS-(aq)<--->
(c) NO2-(aq) + H2O(1)<--->
Group of answer choices
A.) (a) 2 OH-; 100% to products
(b) CH3COO- + H2S; towards products
(c) HNO2 + OH-; towards reactants
B.) (a) 2 OH-; 100% to products
(b) CH3COO- + H2S; 100% to products
(c) HNO2 + OH-; towards reactants
C.) (a) 2 OH-; 100% to products
(b) CH3COO- + H2S; towards products
(c) HNO2 + OH-; towards products
D.) (a) 2 OH-; towards reactants
(b) CH3COO- + H2S; towards products
(c) HNO2 + OH-; towards reactants
(a) Predict the products of the following acid-base reactions using curved-arrow
mechanisms to indicate electron flow. (b) Indicate the acid, base, conjugate acid, and
conjugate base of each reaction. (c) Indicate whether the reactants or products are favored at
equilibrium
a)
CH,COOH
CH3O
b)
CH,CH,OH
H2N
Chapter 7 Solutions
Organic Chemistry
Ch. 7 - Prob. 1PPCh. 7 - Prob. 2PPCh. 7 - Prob. 3PPCh. 7 - Prob. 4PPCh. 7 - Practice Problem 7.5
How many stereoisomers are...Ch. 7 - Prob. 6PPCh. 7 - Prob. 7PPCh. 7 - PRACTICE PROBLEM 7.8
Examine Solved Problem 7.3....Ch. 7 - Prob. 9PPCh. 7 - Practice Problem 7.10 When...
Ch. 7 - Practice Problem 7.11
(a) When...Ch. 7 - Prob. 12PPCh. 7 - Prob. 13PPCh. 7 - Practice Problem 7.14
Dehydration of 2-propanol...Ch. 7 - Practice Problem 7.15
Rank the following alcohols...Ch. 7 - Practice Problem 7.16
Acid-catalyzed dehydration...Ch. 7 - Practice Problem 7.17 Acid-catalyzed dehydration...Ch. 7 - Prob. 18PPCh. 7 - Prob. 19PPCh. 7 - Practice Problem 7.20
Show how you might...Ch. 7 - Prob. 21PPCh. 7 - Prob. 22PPCh. 7 - Practice Problem 7.23
Write the structure of...Ch. 7 - Prob. 24PPCh. 7 - Prob. 25PPCh. 7 - Practice Problem 7.26 (a) Devise retrosynthetic...Ch. 7 - Each of the following names is incorrect, Give the...Ch. 7 - Prob. 28PCh. 7 - Prob. 29PCh. 7 - Give the IUPAC names for each of the following:...Ch. 7 - Prob. 31PCh. 7 - Prob. 32PCh. 7 - Prob. 33PCh. 7 - Prob. 34PCh. 7 - 7.35. Write structural formulas for all the...Ch. 7 - 7.36. Explain the following observations: When...Ch. 7 - Prob. 37PCh. 7 - Arrange the following alcohols in order of their...Ch. 7 - Prob. 39PPCh. 7 - Prob. 40PPCh. 7 - Prob. 41PPCh. 7 - Prob. 42PPCh. 7 - Your task is to prepare isopropyl methyl ether by...Ch. 7 - Prob. 44PCh. 7 - Prob. 45PCh. 7 - Prob. 46PCh. 7 - 7.47. Starting with an appropriate alkyl halide...Ch. 7 - Prob. 48PCh. 7 - 7.49. What is the index of hydrogen deficiency...Ch. 7 - Prob. 50PCh. 7 - Prob. 51PCh. 7 - Compounds I and J both have the molecular formula...Ch. 7 - Prob. 53PCh. 7 - 7.54. Outline a synthesis of phenylethyne from...Ch. 7 - Prob. 55PPCh. 7 - Prob. 56PPCh. 7 - Prob. 57PPCh. 7 - cis-4-Bromocyclohexanol tBuOHtBuO racemic C6H10O...Ch. 7 - Prob. 59PPCh. 7 - Consider the interconversion of cis-2-butene and...Ch. 7 - Prob. 61PCh. 7 - (a) Using reactions studied in this chapter, show...Ch. 7 - Prob. 63PCh. 7 - Prob. 64PCh. 7 - 1. Write the structure(s) of the major product(s)...Ch. 7 - Prob. 2LGPCh. 7 - (a) Write the structure of the product(s) formed...Ch. 7 - Prob. 4LGP
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Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.Similar questions
- 1. (a) For each of the Brønsted acid-base reactions shown below, label the conjugate acid-base pairs. (b) Use curved arrows to illustrate electron flow for each reaction going from left to right. H I H-N+-H H CH3 H3C-C-0 CH3 YoY H H OH- OH- H-CI но H-C-S-CI но H I H-N H CH3 H3C-C-OH CH3 T *N+ I H H H YNY H₂O H₂O CI- но H-C=S-CIarrow_forwardIf the G for a reaction is 4.5 kcal/mol at 298 K, what is the Keq for this reaction? What is the change in entropy of this reaction if H = 3.2 kcal/mol?arrow_forward5. (a) The molecule shown below can react with a base, and lose one of the five protons to form an anionic intermediate. Draw this anionic intermediate, and explain why that proton is removed instead of one of the others. CI H Cl -H H H Cl (b) The same molecule can react with Ag", and lose one of the three chlorine atoms to form a cationic intermediate. Draw this cationic intermediate, and explain why that chlorine atom is removed, while neither of the other two are removed. CI H Cl -H H H H CIarrow_forward
- 3.27 For each pair of structures below, identify the stronger acid, and explain your choice: H H N=H -N H H H (a) (c) H -" :0 H ΝΞΗ I H ΗΘΗ `N' H CONTA ΘΝ H (b) (d) H H H N H I Harrow_forward1. 1a) 1b) 1c) 1d) For each of the following reactions: Draw a reaction mechanism (curved arrows) and comeplete the reaction on the right side. Then predict which side of the equilibrium is favored, left, right or either. Circle the stronger acid. If the strength are euqal, circle both. Give one word from the HIRE rules to state the most important factor in your determination and put it in the box. O N SH + F3C OH + + _N_ + OH Oo. 8arrow_forward(i) Arrange the following compounds in an increasing order of basic strength :C6H5NH2, C6H5N(CH3)2, (C2H5)2NH and CH3NH2(ii) Arrange the following compounds in a decreasing order of pKb values :C2H5NH2, C6H5NHCH3, (C2H5)2NH and C6H5NHarrow_forward
- Given the following: [H3O+] = 5.112 x 10-13, please calculate the pOH.(Note please use 3 sig. figs for your answer.)arrow_forwardWhat would be the product from this reaction? || CH (A) (B) (C) (D) O=C do OH CH C=O 1. 2. H₂O, H+ Li -CHarrow_forward3.41 Write an equation for the proton transfer reaction that occurs when each of the following acids reacts with water. In each case, draw curved arrows that show a mechanism for the proton transfer: (a) HBr (b) O=S=O H-O-S-O-H (c) L -Harrow_forward
- 5. Which one of the following equations would make more products upon addition of acid (H)? Briefly explain. H,SO,(aq) 2 HSO, (aq) + H (aq) HCl(aq) 2H(aq) + Cl'(aq) NH, (aq) + OH(aq) 2 NH;(aq) +H,O(1) 2 Fe,0;(s) 2 2 FeO(s) + O>(g) H(aq) + NH;(1)2 NH, (aq)arrow_forwardHow to do C?arrow_forwardreaction 1 reversed: 2CO2 + 3H20→C2H; OH + 302 Express your answer numerically in kilojoules per mole.arrow_forward
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