Organic Chemistry
8th Edition
ISBN: 9781305580350
Author: William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. Foote
Publisher: Cengage Learning
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Textbook Question
Chapter 6.3, Problem 6.2P
Name and draw a structural formula for the product of each
(a) 
(b) 
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(a) The following synthesis of the molecule shown in the circle has a major problem. What is this problem? (2
pts)
1) HBr
(no peroxides)
2) H-
NaNH2
Br
3) NaNH,
4) CH3Br
5) H2, Pd
(b) Starting with the molecule shown below and any other materials with two carbons or less, write out an
alternate synthesis of the circled molecule. More than one step is needed. Indicate the reagent(s) and the major
product in all the steps in your synthesis. (5 pts)
2024 Fall Term (1) Organic Chemistry 1 (Lec)
CHEM 22204 02[6386] (Hunter College)
(c) Using the same starting material as in part (b) and any other materials win two carpons or less, write out
syntheses of the circled molecules shown below. More than one step is needed in each case. Indicate the
reagent(s) and the major product in all the steps in your synthesis. You may use reactions and products from
your synthesis in part (b). (5 pts)
alt
ons for
Free Response Questions
FRQ 1:
0/5
To spectrophotometrically determine the mass percent of cobalt in an ore containing cobalt and
some inert materials, solutions with known [Co?) are prepared and absorbance of each of the
solutions is measured at the wavelength of optimum absorbance. The data are used to create a
calibration plot, shown below.
0.90-
0.80-
0.70
0.60
0.50
0.40-
0.30
0.20-
0.10-
0.00-
0.005
0.010
Concentration (M)
0.015
A 0.630 g sample of the ore is completely dissolved in concentrated HNO3(aq). The mixture is diluted
with water to a final volume of 50.00 ml. Assume that all the cobalt in the ore sample is converted to
Co2+(aq).
a. What is the [Co2] in the solution if the absorbance of a sample of the solution is 0.74?
13
✗
b. Calculate the number of moles of Co2+(aq) in the 50.00 mL solution.
0.008 mols Co
Please correct answer and don't used hand raiting
Chapter 6 Solutions
Organic Chemistry
Ch. 6.2 - Using the BDE values from Appendix 3, calculate...Ch. 6.3 - Name and draw a structural formula for the product...Ch. 6.3 - Prob. 6.3PCh. 6.3 - Propose a mechanism for the addition of HI to...Ch. 6.3 - Prob. 6.5PCh. 6.3 - Propose a mechanism for the acid-catalyzed...Ch. 6.3 - The acid-catalyzed hydration of...Ch. 6.3 - Complete these reactions. (a) (b)Ch. 6.3 - Draw the structure of the chlorohydrin formed by...Ch. 6.4 - Draw structural formulas for the alkene that gives...
Ch. 6.5 - Prob. 6.11PCh. 6.5 - Prob. 6.12PCh. 6.5 - What alkene with the molecular formula C6H12, when...Ch. 6 - Prob. 6.15PCh. 6 - Prob. 6.16PCh. 6 - Predict the organic product(s) of the reaction of...Ch. 6 - Prob. 6.18PCh. 6 - Prob. 6.20PCh. 6 - Draw a structural formula for an alkene with the...Ch. 6 - Account for the fact that addition of HCl to...Ch. 6 - Account for the fact that treating propenoic acid...Ch. 6 - Draw a structural formula for the alkene with the...Ch. 6 - Draw the alternative chair conformations for the...Ch. 6 - Draw a structural formula for the cycloalkene with...Ch. 6 - Reaction of this bicycloalkene with bromine in...Ch. 6 - Terpin, prepared commercially by the...Ch. 6 - Propose a mechanism for this reaction and account...Ch. 6 - Treating 2-methylpropene with methanol in the...Ch. 6 - When 2-pentene is treated with Cl2 in methanol,...Ch. 6 - Treating cyclohexene with HBr in the presence of...Ch. 6 - Propose a mechanism for this reaction. 1-Pentane...Ch. 6 - Treating 4-penten-1-ol with bromine in water forms...Ch. 6 - Prob. 6.35PCh. 6 - Prob. 6.36PCh. 6 - Reaction of -pinene with borane followed by...Ch. 6 - Write structural formulas for the major organic...Ch. 6 - Draw the structural formula of the alkene that...Ch. 6 - Consider the following reaction. (a) Draw a...Ch. 6 - Prob. 6.42PCh. 6 - Prob. 6.43PCh. 6 - Show how to convert ethylene to these compounds....Ch. 6 - Show how to convert cyclopentene into these...Ch. 6 - Prob. 6.46PCh. 6 - Describe the stereochemistry of the bromohydrin...Ch. 6 - Prob. 6.49PCh. 6 - Treating 1,3-butadiene with 1 mole of HBr gives a...Ch. 6 - In this chapter, we studied the mechanism of the...Ch. 6 - As we have seen in this chapter, carbon-carbon...Ch. 6 - Prob. 6.53PCh. 6 - Prob. 6.54P
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