The reason why heat of hydrogenation for cis isomer is larger than trans isomer has to be indicated. Concept Introduction: Hydrogenation: It is the reaction between compounds with unsaturated bonds and within H 2 presence of catalyst that results to add hydrogens across the double bonds present in the compound. Syn addition: When two substituents are added over double or triple bond on same side of the compound simultaneously is called syn addition. Syn elimination: When two substituents bonded in same side of a compound gets cleaved from the substance simultaneously then the elimination is called syn elimination. cis isomer: The compound with two functional groups are present on same side of the carbon chain. Trans isomer: The compound with two functional groups are present on opposite side of the carbon chain.

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Answer 1

Question

Chapter 6, Problem 6.43P

(a)

Interpretation Introduction

Interpretation:

The reason why heat of hydrogenation for cis isomer is larger than trans isomer has to be indicated.

Concept Introduction:

Hydrogenation: It is the reaction between compounds with unsaturated bonds and within H2 presence of catalyst that results to add hydrogens across the double bonds present in the compound.

Syn addition: When two substituents are added over double or triple bond on same side of the compound simultaneously is called syn addition.

Syn elimination: When two substituents bonded in same side of a compound gets cleaved from the substance simultaneously then the elimination is called syn elimination.

cis isomer: The compound with two functional groups are present on same side of the carbon chain.

Trans isomer: The compound with two functional groups are present on opposite side of the carbon chain.

(b)

Interpretation Introduction

Interpretation:

The ration of trans to cis isomer has to be determined.

Concept Introduction:

Hydrogenation: It is the reaction between compound with unsaturated bonds and with H2 in presence of catalyst that results to add hydrogens across the double bonds present in the compound.

Syn addition: When two substituents are added over double or triple bond on same side of the compound simultaneously is called syn addition.

Syn elimination: When two substituents bonded in same side of a compound gets cleaved from the substance simultaneously then the elimination is called syn elimination.

cis isomer: The compound with two functional groups are present on same side of the carbon chain.

Trans isomer: The compound with two functional groups are present on opposite side of the carbon chain.

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Comment on the following paragraph. In halides, MXn stoichiometry does not require a value of n so large as to prevent the approach of M+ ions, for steric or electrostatic reasons.

Answer 2

Question

Chapter 6, Problem 6.43P

(a)

Interpretation Introduction

Interpretation:

The reason why heat of hydrogenation for cis isomer is larger than trans isomer has to be indicated.

Concept Introduction:

Hydrogenation: It is the reaction between compounds with unsaturated bonds and within H2 presence of catalyst that results to add hydrogens across the double bonds present in the compound.

Syn addition: When two substituents are added over double or triple bond on same side of the compound simultaneously is called syn addition.

Syn elimination: When two substituents bonded in same side of a compound gets cleaved from the substance simultaneously then the elimination is called syn elimination.

cis isomer: The compound with two functional groups are present on same side of the carbon chain.

Trans isomer: The compound with two functional groups are present on opposite side of the carbon chain.

(b)

Interpretation Introduction

Interpretation:

The ration of trans to cis isomer has to be determined.

Concept Introduction:

Hydrogenation: It is the reaction between compound with unsaturated bonds and with H2 in presence of catalyst that results to add hydrogens across the double bonds present in the compound.

Syn addition: When two substituents are added over double or triple bond on same side of the compound simultaneously is called syn addition.

Syn elimination: When two substituents bonded in same side of a compound gets cleaved from the substance simultaneously then the elimination is called syn elimination.

cis isomer: The compound with two functional groups are present on same side of the carbon chain.

Trans isomer: The compound with two functional groups are present on opposite side of the carbon chain.

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Answer 3

Question

Chapter 6, Problem 6.43P

(a)

Interpretation Introduction

Interpretation:

The reason why heat of hydrogenation for cis isomer is larger than trans isomer has to be indicated.

Concept Introduction:

Hydrogenation: It is the reaction between compounds with unsaturated bonds and within H2 presence of catalyst that results to add hydrogens across the double bonds present in the compound.

Syn addition: When two substituents are added over double or triple bond on same side of the compound simultaneously is called syn addition.

Syn elimination: When two substituents bonded in same side of a compound gets cleaved from the substance simultaneously then the elimination is called syn elimination.

cis isomer: The compound with two functional groups are present on same side of the carbon chain.

Trans isomer: The compound with two functional groups are present on opposite side of the carbon chain.

(b)

Interpretation Introduction

Interpretation:

The ration of trans to cis isomer has to be determined.

Concept Introduction:

Hydrogenation: It is the reaction between compound with unsaturated bonds and with H2 in presence of catalyst that results to add hydrogens across the double bonds present in the compound.

Syn addition: When two substituents are added over double or triple bond on same side of the compound simultaneously is called syn addition.

Syn elimination: When two substituents bonded in same side of a compound gets cleaved from the substance simultaneously then the elimination is called syn elimination.

cis isomer: The compound with two functional groups are present on same side of the carbon chain.

Trans isomer: The compound with two functional groups are present on opposite side of the carbon chain.

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Answer 4

Question

Chapter 6, Problem 6.43P

(a)

Interpretation Introduction

Interpretation:

The reason why heat of hydrogenation for cis isomer is larger than trans isomer has to be indicated.

Concept Introduction:

Hydrogenation: It is the reaction between compounds with unsaturated bonds and within H2 presence of catalyst that results to add hydrogens across the double bonds present in the compound.

Syn addition: When two substituents are added over double or triple bond on same side of the compound simultaneously is called syn addition.

Syn elimination: When two substituents bonded in same side of a compound gets cleaved from the substance simultaneously then the elimination is called syn elimination.

cis isomer: The compound with two functional groups are present on same side of the carbon chain.

Trans isomer: The compound with two functional groups are present on opposite side of the carbon chain.

(b)

Interpretation Introduction

Interpretation:

The ration of trans to cis isomer has to be determined.

Concept Introduction:

Hydrogenation: It is the reaction between compound with unsaturated bonds and with H2 in presence of catalyst that results to add hydrogens across the double bonds present in the compound.

Syn addition: When two substituents are added over double or triple bond on same side of the compound simultaneously is called syn addition.

Syn elimination: When two substituents bonded in same side of a compound gets cleaved from the substance simultaneously then the elimination is called syn elimination.

cis isomer: The compound with two functional groups are present on same side of the carbon chain.

Trans isomer: The compound with two functional groups are present on opposite side of the carbon chain.

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Answer 5

Chapter 6, Problem 6.43P

(a)

Interpretation Introduction

Interpretation:

The reason why heat of hydrogenation for cis isomer is larger than trans isomer has to be indicated.

Concept Introduction:

Hydrogenation: It is the reaction between compounds with unsaturated bonds and within H2 presence of catalyst that results to add hydrogens across the double bonds present in the compound.

Syn addition: When two substituents are added over double or triple bond on same side of the compound simultaneously is called syn addition.

Syn elimination: When two substituents bonded in same side of a compound gets cleaved from the substance simultaneously then the elimination is called syn elimination.

cis isomer: The compound with two functional groups are present on same side of the carbon chain.

Trans isomer: The compound with two functional groups are present on opposite side of the carbon chain.

(b)

Interpretation Introduction

Interpretation:

The ration of trans to cis isomer has to be determined.

Concept Introduction:

Hydrogenation: It is the reaction between compound with unsaturated bonds and with H2 in presence of catalyst that results to add hydrogens across the double bonds present in the compound.

Syn addition: When two substituents are added over double or triple bond on same side of the compound simultaneously is called syn addition.

Syn elimination: When two substituents bonded in same side of a compound gets cleaved from the substance simultaneously then the elimination is called syn elimination.

cis isomer: The compound with two functional groups are present on same side of the carbon chain.

Trans isomer: The compound with two functional groups are present on opposite side of the carbon chain.

Answer 6

Chapter 6, Problem 6.43P

(a)

Interpretation Introduction

Interpretation:

The reason why heat of hydrogenation for cis isomer is larger than trans isomer has to be indicated.

Concept Introduction:

Hydrogenation: It is the reaction between compounds with unsaturated bonds and within H2 presence of catalyst that results to add hydrogens across the double bonds present in the compound.

Syn addition: When two substituents are added over double or triple bond on same side of the compound simultaneously is called syn addition.

Syn elimination: When two substituents bonded in same side of a compound gets cleaved from the substance simultaneously then the elimination is called syn elimination.

cis isomer: The compound with two functional groups are present on same side of the carbon chain.

Trans isomer: The compound with two functional groups are present on opposite side of the carbon chain.

Answer 7

Chapter 6, Problem 6.43P

(a)

Interpretation Introduction

Interpretation:

The reason why heat of hydrogenation for cis isomer is larger than trans isomer has to be indicated.

Concept Introduction:

Hydrogenation: It is the reaction between compounds with unsaturated bonds and within H2 presence of catalyst that results to add hydrogens across the double bonds present in the compound.

Syn addition: When two substituents are added over double or triple bond on same side of the compound simultaneously is called syn addition.

Syn elimination: When two substituents bonded in same side of a compound gets cleaved from the substance simultaneously then the elimination is called syn elimination.

cis isomer: The compound with two functional groups are present on same side of the carbon chain.

Trans isomer: The compound with two functional groups are present on opposite side of the carbon chain.

Answer 8

(b)

Interpretation Introduction

Interpretation:

The ration of trans to cis isomer has to be determined.

Concept Introduction:

Hydrogenation: It is the reaction between compound with unsaturated bonds and with H2 in presence of catalyst that results to add hydrogens across the double bonds present in the compound.

Syn addition: When two substituents are added over double or triple bond on same side of the compound simultaneously is called syn addition.

Syn elimination: When two substituents bonded in same side of a compound gets cleaved from the substance simultaneously then the elimination is called syn elimination.

cis isomer: The compound with two functional groups are present on same side of the carbon chain.

Trans isomer: The compound with two functional groups are present on opposite side of the carbon chain.

Answer 9

(b)

Interpretation Introduction

Interpretation:

The ration of trans to cis isomer has to be determined.

Concept Introduction:

Hydrogenation: It is the reaction between compound with unsaturated bonds and with H2 in presence of catalyst that results to add hydrogens across the double bonds present in the compound.

Syn addition: When two substituents are added over double or triple bond on same side of the compound simultaneously is called syn addition.

Syn elimination: When two substituents bonded in same side of a compound gets cleaved from the substance simultaneously then the elimination is called syn elimination.

cis isomer: The compound with two functional groups are present on same side of the carbon chain.

Trans isomer: The compound with two functional groups are present on opposite side of the carbon chain.

Answer 10

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Answer 13

Ch. 6.2 - Using the BDE values from Appendix 3, calculate...Ch. 6.3 - Name and draw a structural formula for the product...Ch. 6.3 - Prob. 6.3P Ch. 6.3 - Propose a mechanism for the addition of HI to...Ch. 6.3 - Prob. 6.5P Ch. 6.3 - Propose a mechanism for the acid-catalyzed...Ch. 6.3 - The acid-catalyzed hydration of...Ch. 6.3 - Complete these reactions. (a) (b)Ch. 6.3 - Draw the structure of the chlorohydrin formed by...Ch. 6.4 - Draw structural formulas for the alkene that gives...

Solution Summary: The author explains the reason why the heat of hydrogenation for cis isomer is larger than that for trans.

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