(a)
Interpretation:
The
pH definition:
The concentration of hydrogen ion is measured using
The
On rearranging, the concentration of hydrogen ion
(a)

Answer to Problem 6D.17E
The
Explanation of Solution
The proton transfer equilibrium reaction for the base of
The equilibrium expression for the above reaction is given below.
Initial concentration | 0.63 | 0 | 0 |
Change in concentration | -x | +x | +x |
Equilibrium concentration | 0.63-x | x | x |
The
The equilibrium concentration values obtained in the above table is substituted in the above equation and is given below.
The
The above equation, assume that the x present in
The
The general equilibrium expression to find out the pH of the solution is given below,
Therefore, the calculated
(b)
Interpretation:
The
Concept introduction:
Refer to part (a).
(b)

Answer to Problem 6D.17E
The
Explanation of Solution
The proton transfer equilibrium reaction for the base of
The equilibrium expression for the above reaction is given below.
Initial concentration | 0.65 | 0 | 0 |
Change in concentration | -x | +x | +x |
Equilibrium concentration | 0.65-x | x | x |
The
The equilibrium concentration values obtained in the above table is substituted in the above equation and is given below.
The
The above equation, assume that the x present in
The
The general equilibrium expression to find out the pH of the solution is given below,
Therefore, the calculated
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Chapter 6 Solutions
ACHIEVE/CHEMICAL PRINCIPLES ACCESS 2TERM
- 2. Copper (II) oxide crystalizes in monoclinic unit cell (included below; blue spheres 2+ represent Cu²+, red - O²-). Use Kapustinski's equation (4.5) to calculate lattice energy for CuO. You will need some data from Resource section of your textbook (p.901). (4 points) CuOarrow_forwardWhat is the IUPAC name of the following compound? OH (2S, 4R)-4-chloropentan-2-ol O (2R, 4R)-4-chloropentan-2-ol O (2R, 4S)-4-chloropentan-2-ol O(2S, 4S)-4-chloropentan-2-olarrow_forwardIn the answer box, type the number of maximum stereoisomers possible for the following compound. A H H COH OH = H C Br H.C OH CHarrow_forward
- Select the major product of the following reaction. Br Br₂, light D Br Br Br Brarrow_forwardSelect all molecules which are chiral. Brarrow_forwardUse the reaction coordinate diagram to answer the below questions. Type your answers into the answer box for each question. (Watch your spelling) Energy A B C D Reaction coordinate E A) Is the reaction step going from D to F endothermic or exothermic? A F G B) Does point D represent a reactant, product, intermediate or transition state? A/ C) Which step (step 1 or step 2) is the rate determining step? Aarrow_forward
- 1. Using radii from Resource section 1 (p.901) and Born-Lande equation, calculate the lattice energy for PbS, which crystallizes in the NaCl structure. Then, use the Born-Haber cycle to obtain the value of lattice energy for PbS. You will need the following data following data: AH Pb(g) = 196 kJ/mol; AHƒ PbS = −98 kJ/mol; electron affinities for S(g)→S¯(g) is -201 kJ/mol; S¯(g) (g) is 640kJ/mol. Ionization energies for Pb are listed in Resource section 2, p.903. Remember that enthalpies of formation are calculated beginning with the elements in their standard states (S8 for sulfur). The formation of S2, AHF: S2 (g) = 535 kJ/mol. Compare the two values, and explain the difference. (8 points)arrow_forwardIn the answer box, type the number of maximum stereoisomers possible for the following compound. A H H COH OH = H C Br H.C OH CHarrow_forward7. Magnesium is found in nature in the form of carbonates and sulfates. One of the major natural sources of zinc is zinc blende (ZnS). Use relevant concepts of acid-base theory to explain this combination of cations and anions in these minerals. (2 points)arrow_forward
- 6. AlF3 is insoluble in liquid HF but dissolves if NaF is present. When BF3 is added to the solution, AlF3 precipitates. Write out chemical processes and explain them using the principles of Lewis acid-base theory. (6 points)arrow_forward5. Zinc oxide is amphoteric. Write out chemical reactions for dissolution of ZnO in HCl(aq) and in NaOH(aq). (3 points)arrow_forwardDraw the product(s) formed when alkene A is reacted with ozone, followed by Zn and H₂O. If no second product is formed, do not draw a structure in the second box. Higher Molecular Weight Product A Lower Molecular Weight Product draw structure ... draw structure ...arrow_forward
- Chemistry: Principles and ReactionsChemistryISBN:9781305079373Author:William L. Masterton, Cecile N. HurleyPublisher:Cengage LearningChemistry: The Molecular ScienceChemistryISBN:9781285199047Author:John W. Moore, Conrad L. StanitskiPublisher:Cengage Learning

