The balanced chemical equation for the given reaction has to be written. Concept Introduction: Balanced chemical equation: In a chemical reaction the number of atoms for each element in the reaction and the total charge are the same for both the reactants and the products.

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Answer 1

Question

Chapter 6, Problem 6.69CP

a)

Interpretation Introduction

Interpretation:

The balanced chemical equation for the given reaction has to be written.

Concept Introduction:

Balanced chemical equation: In a chemical reaction the number of atoms for each element in the reaction and the total charge are the same for both the reactants and the products.

b)

Interpretation Introduction

Interpretation:

The no.of mole of gas produced by the reaction has to be calculated.

Concept Introduction:

Mole: The amount of substance containing as many elementary entities (atoms, molecules, ions, etc.) as there are atoms in 12 grams of carbon-12.

Mole calculation:

No.of moles =Mass molar mass Number of mole is obtained dividing Mass by molar mass.

Mass Calculation:No.of moles × molar mass = Mass Multiplying no.of mole and molar mass gives mass of the substance.

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The beta-lactamase hydrolyzes the lactam-ring in penicillin. Describe the mechanism of hydrolysis, insuring to include the involvement of S, D, & K in the reaction sequence. Please help

To map the active site of beta-lactamase, the enzyme was hydrolyzed with trypsin to yield a hexapeptide (P1) with the following amino acids. Glu, Lys, Leu, Phe, Met, and Ser. Treatment of P1 with phenyl isothiocyanate yielded a PTH derivative of phenylalanine and a peptide (P2). Treatment of P1 with cyanogenbromide gave an acidic tetrapeptide (P3) and a dipeptide (P4).Treatment of P2 with 1-fluoro-2,4-dinitrobenzene, followed by complete hydrolysis, yields N-2,4-dinitrophenyl-Glu. P1, P2, and P3 contain the active site serine. Why doesn't D in this hexapeptide not participate in the hydrolysis of the beta-lactam ring even though S, K, and D are involved in the catalyst?

To map the active site of -lactamase, the enzyme was hydrolyzed with trypsin to yield a hexapeptide (P1) with the following amino acids. Glu, Lys, Leu, Phe, Met, and Ser. Treatment of P1 with phenyl isothiocyanate yielded a PTH derivative of phenylalanine and a peptide (P2). Treatment of P1 with cyanogenbromide gave an acidic tetrapeptide (P3) and a dipeptide (P4).Treatment of P2 with 1-fluoro-2,4-dinitrobenzene, followed by complete hydrolysis, yields N-2,4-dinitrophenyl-Glu. P1, P2, and P3 contain the active site serine. Using the experimental results described above derive the primary sequence of the active site hexapeptide. Please help!

Answer 2

Question

Chapter 6, Problem 6.69CP

a)

Interpretation Introduction

Interpretation:

The balanced chemical equation for the given reaction has to be written.

Concept Introduction:

Balanced chemical equation: In a chemical reaction the number of atoms for each element in the reaction and the total charge are the same for both the reactants and the products.

b)

Interpretation Introduction

Interpretation:

The no.of mole of gas produced by the reaction has to be calculated.

Concept Introduction:

Mole: The amount of substance containing as many elementary entities (atoms, molecules, ions, etc.) as there are atoms in 12 grams of carbon-12.

Mole calculation:

No.of moles =Mass molar mass Number of mole is obtained dividing Mass by molar mass.

Mass Calculation:No.of moles × molar mass = Mass Multiplying no.of mole and molar mass gives mass of the substance.

Expert Solution & Answer

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Answer 3

Question

Chapter 6, Problem 6.69CP

a)

Interpretation Introduction

Interpretation:

The balanced chemical equation for the given reaction has to be written.

Concept Introduction:

Balanced chemical equation: In a chemical reaction the number of atoms for each element in the reaction and the total charge are the same for both the reactants and the products.

b)

Interpretation Introduction

Interpretation:

The no.of mole of gas produced by the reaction has to be calculated.

Concept Introduction:

Mole: The amount of substance containing as many elementary entities (atoms, molecules, ions, etc.) as there are atoms in 12 grams of carbon-12.

Mole calculation:

No.of moles =Mass molar mass Number of mole is obtained dividing Mass by molar mass.

Mass Calculation:No.of moles × molar mass = Mass Multiplying no.of mole and molar mass gives mass of the substance.

Expert Solution & Answer

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Check out a sample textbook solution

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Answer 4

Question

Chapter 6, Problem 6.69CP

a)

Interpretation Introduction

Interpretation:

The balanced chemical equation for the given reaction has to be written.

Concept Introduction:

Balanced chemical equation: In a chemical reaction the number of atoms for each element in the reaction and the total charge are the same for both the reactants and the products.

b)

Interpretation Introduction

Interpretation:

The no.of mole of gas produced by the reaction has to be calculated.

Concept Introduction:

Mole: The amount of substance containing as many elementary entities (atoms, molecules, ions, etc.) as there are atoms in 12 grams of carbon-12.

Mole calculation:

No.of moles =Mass molar mass Number of mole is obtained dividing Mass by molar mass.

Mass Calculation:No.of moles × molar mass = Mass Multiplying no.of mole and molar mass gives mass of the substance.

Expert Solution & Answer

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Answer 5

Chapter 6, Problem 6.69CP

a)

Interpretation Introduction

Interpretation:

The balanced chemical equation for the given reaction has to be written.

Concept Introduction:

Balanced chemical equation: In a chemical reaction the number of atoms for each element in the reaction and the total charge are the same for both the reactants and the products.

b)

Interpretation Introduction

Interpretation:

The no.of mole of gas produced by the reaction has to be calculated.

Concept Introduction:

Mole: The amount of substance containing as many elementary entities (atoms, molecules, ions, etc.) as there are atoms in 12 grams of carbon-12.

Mole calculation:

No.of moles =Mass molar mass Number of mole is obtained dividing Mass by molar mass.

Mass Calculation:No.of moles × molar mass = Mass Multiplying no.of mole and molar mass gives mass of the substance.

Answer 6

Chapter 6, Problem 6.69CP

a)

Interpretation Introduction

Interpretation:

The balanced chemical equation for the given reaction has to be written.

Concept Introduction:

Balanced chemical equation: In a chemical reaction the number of atoms for each element in the reaction and the total charge are the same for both the reactants and the products.

Answer 7

Chapter 6, Problem 6.69CP

a)

Interpretation Introduction

Interpretation:

The balanced chemical equation for the given reaction has to be written.

Concept Introduction:

Balanced chemical equation: In a chemical reaction the number of atoms for each element in the reaction and the total charge are the same for both the reactants and the products.

Answer 8

b)

Interpretation Introduction

Interpretation:

The no.of mole of gas produced by the reaction has to be calculated.

Concept Introduction:

Mole: The amount of substance containing as many elementary entities (atoms, molecules, ions, etc.) as there are atoms in 12 grams of carbon-12.

Mole calculation:

No.of moles =Mass molar mass Number of mole is obtained dividing Mass by molar mass.

Mass Calculation:No.of moles × molar mass = Mass Multiplying no.of mole and molar mass gives mass of the substance.

Answer 9

b)

Interpretation Introduction

Interpretation:

The no.of mole of gas produced by the reaction has to be calculated.

Concept Introduction:

Mole: The amount of substance containing as many elementary entities (atoms, molecules, ions, etc.) as there are atoms in 12 grams of carbon-12.

Mole calculation:

No.of moles =Mass molar mass Number of mole is obtained dividing Mass by molar mass.

Mass Calculation:No.of moles × molar mass = Mass Multiplying no.of mole and molar mass gives mass of the substance.

Answer 10

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Answer 11

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Answer 12

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Answer 13

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The balanced chemical equation for the given reaction has to be written. Concept Introduction: Balanced chemical equation: In a chemical reaction the number of atoms for each element in the reaction and the total charge are the same for both the reactants and the products.

Solution Summary: The author explains the balanced chemical equation for a given reaction. The number of atoms for each element in the reaction and the total charge are the same.

Videos

Interpretation:

The balanced chemical equation for the given reaction has to be written.

Concept Introduction:

Balanced chemical equation: In a chemical reaction the number of atoms for each element in the reaction and the total charge are the same for both the reactants and the products.

Want to see the full answer?

Chapter 6 Solutions

The balanced chemical equation for the given reaction has to be written. Concept Introduction: Balanced chemical equation: In a chemical reaction the number of atoms for each element in the reaction and the total charge are the same for both the reactants and the products.

Solution Summary: The author explains the balanced chemical equation for a given reaction. The number of atoms for each element in the reaction and the total charge are the same.

Videos

Interpretation: The balanced chemical equation for the given reaction has to be written. Concept Introduction: Balanced chemical equation: In a chemical reaction the number of atoms for each element in the reaction and the total charge are the same for both the reactants and the products.

Want to see the full answer?

Chapter 6 Solutions

Interpretation:

The balanced chemical equation for the given reaction has to be written.

Concept Introduction:

Balanced chemical equation: In a chemical reaction the number of atoms for each element in the reaction and the total charge are the same for both the reactants and the products.