Introductory Chemistry: A Foundation
9th Edition
ISBN: 9781337399425
Author: Steven S. Zumdahl, Donald J. DeCoste
Publisher: Cengage Learning
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Chapter 6, Problem 57AP
A common demonstration in chemistry courses involves adding a tiny speck of manganese(IV) oxide to a concentrated hydrogen peroxide,
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(c) The following data have been obtained for the hydrolysis of sucrose, C12H22O11, to
glucose, C6H12O6, and fructose C6H12O6, in acidic solution:
C12H22O11 + H2O → C6H12O6 + C6H12O6
[sucrose]/mol dm³
t/min
0
0.316
14
0.300
39
0.274
60
0.256
80
0.238
110
0.211
(i) Graphically prove the order of the reaction and determine the rate constant of the
reaction.
(ii) Determine the half-life, t½ for the hydrolysis of sucrose.
(III) adsorbent
(b) Adsorption of the hexacyanoferrate (III) ion, [Fe(CN)6] ³, on y-Al2O3 from aqueous
solution was examined. The adsorption was modelled using a modified Langmuir
isotherm, yielding the following values of Kat pH = 6.5:
(ii)
T/K
10-10 K
280
2.505
295
1.819
310
1.364
325
1.050
Determine the enthalpy of adsorption, AadsHⓇ.
If the reported value of entropy of adsorption, Aads Se = 146 J K-1 mol-1 under the above
conditions, determine Aads Gº.
with full details solution please
Chapter 6 Solutions
Introductory Chemistry: A Foundation
Ch. 6.2 - Prob. 6.1SCCh. 6.3 - Prob. 1CTCh. 6.3 - One part of the problem-solving strategy for...Ch. 6.3 - Prob. 6.2SCCh. 6.3 - Prob. 6.3SCCh. 6 - The following are actual student responses to the...Ch. 6 - Prob. 2ALQCh. 6 - Given the equation for the reaction:N2+H2NH3 ,...Ch. 6 - Prob. 4ALQCh. 6 - Can the subscripts in a chemical formula be...
Ch. 6 - Prob. 6ALQCh. 6 - Changing the subscripts of chemicals can...Ch. 6 - Table 6.1 lists some clues that a chemical...Ch. 6 - Use molecular-level drawings to show the...Ch. 6 - It is stated in Section 6.3 of the text that to...Ch. 6 - Prob. 11ALQCh. 6 - Consider the generic chemical equationaA+bBcC+dD...Ch. 6 - Prob. 13ALQCh. 6 - Which of the following correctly describes the...Ch. 6 - Which of the following correctly balances the...Ch. 6 - The reaction of an element X() with element Y() is...Ch. 6 - Prob. 1QAPCh. 6 - Prob. 2QAPCh. 6 - Although these days many people have...Ch. 6 - Prob. 4QAPCh. 6 - You have probably had the unpleasant experience of...Ch. 6 - If you’ve ever left bread in a toaster too long,...Ch. 6 - What are the substances to theleftof the arrow in...Ch. 6 - Prob. 8QAPCh. 6 - In a chemical reaction, the total number of atoms...Ch. 6 - Prob. 10QAPCh. 6 - Prob. 11QAPCh. 6 - The notation “(l)” after a substance’s formula...Ch. 6 - A common experiment to determine the relative...Ch. 6 - A common lecture demonstration called “elephant’s...Ch. 6 - If a sample of pure hydrogen gas is ignited very...Ch. 6 - Liquid hydrazine, has been used as a fuel for...Ch. 6 - If electricity of sufficient voltage is passed...Ch. 6 - Silver oxide may be decomposed by strong heating...Ch. 6 - Elemental boron is produced in one industrial...Ch. 6 - Many over-the-counter antacid tablets are now...Ch. 6 - Phosphorus trichloride is used in the manufacture...Ch. 6 - Pure silicon, which is needed in the manufacturing...Ch. 6 - Nitrous oxide gas (systematic name: dinitrogen...Ch. 6 - Solid zinc is added to an aqueous solution...Ch. 6 - Acetylene gas (C2H2) is often used by plumbers,...Ch. 6 - The burning of high-sulfur fuels has been shown to...Ch. 6 - The Group 2 metals (Ba, Ca, Sr) can be produced in...Ch. 6 - There are fears that the protective ozone layer...Ch. 6 - Carbon tetrachloride was widely used for many...Ch. 6 - When elemental phosphorus, P4, burns in oxygen...Ch. 6 - Calcium oxide is sometimes very challenging to...Ch. 6 - Prob. 32QAPCh. 6 - The element tin often occurs in nature as the...Ch. 6 - Nitric acid, HNO3 , can be produced by reacting...Ch. 6 - When balancing chemical equations, beginning...Ch. 6 - The “Chemistry in Focus” segment The Beetle That...Ch. 6 - Balance each of the following chemical equations....Ch. 6 - Balance the equations for the reaction of...Ch. 6 - Balance each of the following chemical equations....Ch. 6 - Balance each of the following chemical equations....Ch. 6 - Balance each of the following chemical equations....Ch. 6 - Prob. 42QAPCh. 6 - Prob. 43QAPCh. 6 - Prob. 44QAPCh. 6 - Acetylene gas, C2H2 , is used in welding because...Ch. 6 - When balancing a chemical equation, which of the...Ch. 6 - Crude gunpowders often contain a mixture of...Ch. 6 - The following demonstration takes place in a...Ch. 6 - Methanol (methyl alcohol), CH3OH , is a very...Ch. 6 - The Hall process is an important method by which...Ch. 6 - Iron oxide ores, commonly a mixture of FeO and...Ch. 6 - True or false? Coefficients can be fractions when...Ch. 6 - When steel wool (iron) is heated in pure oxygen...Ch. 6 - One method of producing hydrogen peroxide is to...Ch. 6 - When elemental boron, B, is burned in oxygen gas,...Ch. 6 - A common experiment in introductory chemistry...Ch. 6 - A common demonstration in chemistry courses...Ch. 6 - Write a balanced chemical equation for the...Ch. 6 - Prob. 59APCh. 6 - Prob. 60APCh. 6 - If you had a “sour stomach,” you might try an...Ch. 6 - When iron wire is heated in the presence of...Ch. 6 - When finely divided solid sodium is dropped into a...Ch. 6 - If aqueous solutions of potassium chromate and...Ch. 6 - When hydrogen sulfide, H2S , gas is bubbled...Ch. 6 - If an electric current is passed through aqueous...Ch. 6 - When a strip of magnesium metal is heated in...Ch. 6 - Prob. 68APCh. 6 - When solid red phosphorus, is burned in air, the...Ch. 6 - When copper (II) oxide is boiled in an aqueous...Ch. 6 - When lead(II) sulfide is heated lo high...Ch. 6 - Which of the following statements about chemical...Ch. 6 - Prob. 73APCh. 6 - Prob. 74APCh. 6 - Prob. 75APCh. 6 - Using different shapes to distinguish between...Ch. 6 - Which of the following statements about chemical...Ch. 6 - Prob. 78CPCh. 6 - Balance the following chemical equations....
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- Zeroth Order Reaction In a certain experiment the decomposition of hydrogen iodide on finely divided gold is zeroth order with respect to HI. 2HI(g) Au H2(g) + 12(9) Rate = -d[HI]/dt k = 2.00x104 mol L-1 s-1 If the experiment has an initial HI concentration of 0.460 mol/L, what is the concentration of HI after 28.0 minutes? 1 pts Submit Answer Tries 0/5 How long will it take for all of the HI to decompose? 1 pts Submit Answer Tries 0/5 What is the rate of formation of H2 16.0 minutes after the reaction is initiated? 1 pts Submit Answer Tries 0/5arrow_forwardangelarodriguezmunoz149@gmail.com Hi i need help with this question i am not sure what the right answers are.arrow_forwardPlease correct answer and don't used hand raitingarrow_forward
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