General, Organic, and Biological Chemistry - 4th edition
4th Edition
ISBN: 9781259883989
Author: by Janice Smith
Publisher: McGraw-Hill Education
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Textbook Question
Chapter 6, Problem 46P
Consider the representation depicted in the molecular art for the reaction
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The table includes macrostates characterized by 4 energy levels (&) that are
equally spaced but with different degrees of occupation.
a) Calculate the energy of all the macrostates (in joules). See if they all have
the same energy and number of particles.
b) Calculate the macrostate that is most likely to exist. For this macrostate,
show that the population of the levels is consistent with the Boltzmann
distribution.
macrostate 1 macrostate 2 macrostate 3
ε/k (K) Populations
Populations
Populations
300
5
3
4
200
7
9
8
100
15
17
16
0
33
31
32
DATO: k = 1,38×10-23 J K-1
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In an experiment, the viscosity of water was measured at different
temperatures and the table was constructed from the data obtained.
a) Calculate the activation energy of viscous flow (kJ/mol).
b) Calculate the viscosity at 30°C.
T/°C
0
20
40
60
80
η/cpoise 1,972 1,005 0,656 0,469 0,356
Chapter 6 Solutions
General, Organic, and Biological Chemistry - 4th edition
Ch. 6.1 - Prob. 6.1PPCh. 6.1 - Prob. 6.1PCh. 6.1 - Prob. 6.2PPCh. 6.1 - Prob. 6.2PCh. 6.2 - Using the values in Table 6.2, give H for each...Ch. 6.2 - Prob. 6.4PPCh. 6.2 - Answer the following questions using the given...Ch. 6.2 - Given the H and balanced equation in Sample...Ch. 6.2 - Prob. 6.6PPCh. 6.3 - Prob. 6.7PP
Ch. 6.4 - Consider the reaction of ozone (O3) with nitrogen...Ch. 6.4 - Draw an energy diagram for an uncatalyzed...Ch. 6.5 - Identify the forward and reverse reactions in each...Ch. 6.5 - Write the expression for the equilibrium constant...Ch. 6.5 - Consider the reversible reaction AB, with K=1....Ch. 6.5 - Given each equilibrium constant, state whether the...Ch. 6.5 - Consider the following reaction:...Ch. 6.5 - Using the equilibrium mixture of reactants and...Ch. 6.5 - Calculate the equilibrium constant for each...Ch. 6.5 - Consider the representation depicted in the...Ch. 6.6 - Prob. 6.13PPCh. 6.6 - Prob. 6.14PPCh. 6.6 - wThe conversion of H2O to H2 and O2 is an...Ch. 6.6 - The reaction of O2 with NO to form NO2 and O2 is...Ch. 6.6 - wIn which direction is the equilibrium shifted in...Ch. 6.6 - Label each statement about the following...Ch. 6 - Prob. 11PCh. 6 - Prob. 12PCh. 6 - Prob. 13PCh. 6 - Prob. 14PCh. 6 - Prob. 15PCh. 6 - Prob. 16PCh. 6 - Prob. 17PCh. 6 - Prob. 18PCh. 6 - Prob. 19PCh. 6 - Prob. 20PCh. 6 - Prob. 21PCh. 6 - Prob. 22PCh. 6 - Prob. 23PCh. 6 - Prob. 24PCh. 6 - Prob. 25PCh. 6 - Prob. 26PCh. 6 - Prob. 27PCh. 6 - Ammonia ( NH3 ) decomposes to hydrogen and...Ch. 6 - Prob. 29PCh. 6 - Ethanol ( C2H6O ), a gasoline additive, is formed...Ch. 6 - Prob. 31PCh. 6 - Prob. 32PCh. 6 - Prob. 33PCh. 6 - Prob. 34PCh. 6 - Draw an energy diagram for the following reaction...Ch. 6 - Prob. 36PCh. 6 - State two reasons why increasing temperature...Ch. 6 - Why does decreasing concentration decrease the...Ch. 6 - Prob. 39PCh. 6 - Prob. 40PCh. 6 - Which of the following affect the rate of a...Ch. 6 - Prob. 42PCh. 6 - How does a catalyst affect each of the following:...Ch. 6 - What is the difference between a catalyst and an...Ch. 6 - Prob. 45PCh. 6 - Consider the representation depicted in the...Ch. 6 - For each value, are the reactants or products...Ch. 6 - Prob. 48PCh. 6 - Prob. 49PCh. 6 - Prob. 50PCh. 6 - Prob. 51PCh. 6 - Consider three different equilibrium mixtures...Ch. 6 - Write an expression for the equilibrium constant...Ch. 6 - Write an expression for the equilibrium constant...Ch. 6 - Prob. 55PCh. 6 - Use each expression for the equilibrium constant...Ch. 6 - Prob. 57PCh. 6 - Consider the following reaction:...Ch. 6 - Prob. 59PCh. 6 - Which of the following representations ([1][3]) of...Ch. 6 - Consider the following reaction....Ch. 6 - Consider the following reaction. H2(g)+I2(g)2HI(g)...Ch. 6 - Prob. 63PCh. 6 - Prob. 64PCh. 6 - Consider the reaction of N2(g)+O2(g)2NO(g). What...Ch. 6 - Consider the reaction of H2(g)+F2(g)2HF(g). What...Ch. 6 - Prob. 67PCh. 6 - Consider the reversible reaction ABA+B, shown at...Ch. 6 - Consider the endothermic conversion of oxygen to...Ch. 6 - Consider the exothermic reaction:...Ch. 6 - Consider the exothermic reaction:...Ch. 6 - Consider the endothermic reaction:...Ch. 6 - Consider the gas-phase reaction of ethylene...Ch. 6 - Methanol (CHO), which is used as a fuel in race...Ch. 6 - Prob. 75PCh. 6 - How does a catalytic converter clean up automobile...Ch. 6 - Prob. 77PCh. 6 - The reaction of salicylic acid with acetic acid...Ch. 6 - Prob. 79PCh. 6 - Prob. 80PCh. 6 - Prob. 81PCh. 6 - Prob. 82PCh. 6 - Prob. 83CPCh. 6 - Prob. 84CP
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- Don't used Ai solutionarrow_forwardLet's see if you caught the essentials of the animation. What is the valence value of carbon? a) 4 b) 2 c) 8 d) 6arrow_forwardA laser emits a line at 632.8 nm. If the cavity is 12 cm long, how many modes oscillate in the cavity? How long does it take for the radiation to travel the entire cavity? What is the frequency difference between 2 consecutive modes?(refractive index of the medium n = 1).arrow_forward
- A laser emits a line at 632.8 nm. If the cavity is 12 cm long, how many modes oscillate in the cavity? How long does it take for the radiation to travel the entire cavity? What is the frequency difference between 2 consecutive modes?(refractive index of the medium n = 1).arrow_forwardThe number of microstates corresponding to each macrostate is given by N. The dominant macrostate or configuration of a system is the macrostate with the greatest weight W. Are both statements correct?arrow_forwardFor the single step reaction: A + B → 2C + 25 kJ If the activation energy for this reaction is 35.8 kJ, sketch an energy vs. reaction coordinate diagram for this reaction. Be sure to label the following on your diagram: each of the axes, reactant compounds and product compounds, enthalpy of reaction, activation energy of the forward reaction with the correct value, activation energy of the backwards reaction with the correct value and the transition state. In the same sketch you drew, after the addition of a homogeneous catalyst, show how it would change the graph. Label any new line "catalyst" and label any new activation energy.arrow_forward
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