(a) Interpretation: The point on the graph corresponding the reactants needs to be indicated. Concept introduction: In chemistry, reactants are the raw chemical substances which are involvedin a chemical reaction at the beginning. An energy diagram shows the energy changes which occurs during a chemical reaction.

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Answer 1

Question

Chapter 6, Problem 31P

Interpretation Introduction

(a)

Interpretation:

The point on the graph corresponding the reactants needs to be indicated.

Concept introduction:

In chemistry, reactants are the raw chemical substances which are involvedin a chemical reaction at the beginning. An energy diagram shows the energy changes which occurs during a chemical reaction.

Interpretation Introduction

(b)

Interpretation:

The point on the graph corresponding to the products needs to be indicated.

Concept introduction:

In a chemical reaction, products are the final chemical substances which form at the end of a chemical reaction. An energy diagram shows the energy changes which occur during a chemical reaction.

Interpretation Introduction

(c)

Interpretation:

The transition state on the graph needs to be determined.

Concept introduction:

Transition state is the state relevant to the highest energy through the reaction coordinate. So, these transition states are shown as the highest peaks in the energy diagram.

Interpretation Introduction

(d)

Interpretation:

The energy gap between the reactant and the transition state in the graph needs to be identified.

Concept introduction:

Activation energy of a reactionis the amount of energy that must be provided to start a chemical reaction.

Interpretation Introduction

(e)

Interpretation:

The energy difference between reactants and products should be considered.

Concept introduction:

Enthalpy ( ΔH) of a reaction is the energy change occurs in the system, during the particular reaction.

Interpretation Introduction

(f)

Interpretation:

The highest energy peak position present in the reaction coordinate should be selected.

Concept introduction:

Highest energy position in the reaction coordinate is represented by the highest energy, least stable chemical species form in the reaction.

Interpretation Introduction

(g)

Interpretation:

The lowest energy position, the exothermic/endothermic nature of the reaction should be considered.

Concept introduction:

In an exothermic reaction heat is released thus, the energy of product is lower than that of reactant. On the other hand, in an endothermic reaction heat is absorbed thus, the energy of product is higher than that of reactant.

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4. Refer to the data below to answer the following questions: The octapeptide saralasin is a specific antagonist of angiotensin II. A derivative of saralasin is used therapeutically as an antihypertensive. Amino acid analysis of saralasin show the presence of the following amino acids: Ala, Arg, His, Pro, Sar, Tyr, Val, Val A.Sar is the abbreviation for sarcosine, N-methyl aminoethanoic acid. Draw the structure of sarcosine. B. N-Terminal analysis by the Edman method shows saralasin contains sarcosine at the N-terminus. Partial hydrolysis of saralasin with dilute hydrochloric acid yields the following fragments: Tyr-Val-His Sar-Arg-Val His-Pro-Ala Val-Tyr-Val Arg-Val-Tyr What is the structure of saralasin?

Answer 2

Question

Chapter 6, Problem 31P

Interpretation Introduction

(a)

Interpretation:

The point on the graph corresponding the reactants needs to be indicated.

Concept introduction:

In chemistry, reactants are the raw chemical substances which are involvedin a chemical reaction at the beginning. An energy diagram shows the energy changes which occurs during a chemical reaction.

Interpretation Introduction

(b)

Interpretation:

The point on the graph corresponding to the products needs to be indicated.

Concept introduction:

In a chemical reaction, products are the final chemical substances which form at the end of a chemical reaction. An energy diagram shows the energy changes which occur during a chemical reaction.

Interpretation Introduction

(c)

Interpretation:

The transition state on the graph needs to be determined.

Concept introduction:

Transition state is the state relevant to the highest energy through the reaction coordinate. So, these transition states are shown as the highest peaks in the energy diagram.

Interpretation Introduction

(d)

Interpretation:

The energy gap between the reactant and the transition state in the graph needs to be identified.

Concept introduction:

Activation energy of a reactionis the amount of energy that must be provided to start a chemical reaction.

Interpretation Introduction

(e)

Interpretation:

The energy difference between reactants and products should be considered.

Concept introduction:

Enthalpy ( ΔH) of a reaction is the energy change occurs in the system, during the particular reaction.

Interpretation Introduction

(f)

Interpretation:

The highest energy peak position present in the reaction coordinate should be selected.

Concept introduction:

Highest energy position in the reaction coordinate is represented by the highest energy, least stable chemical species form in the reaction.

Interpretation Introduction

(g)

Interpretation:

The lowest energy position, the exothermic/endothermic nature of the reaction should be considered.

Concept introduction:

In an exothermic reaction heat is released thus, the energy of product is lower than that of reactant. On the other hand, in an endothermic reaction heat is absorbed thus, the energy of product is higher than that of reactant.

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Answer 3

Question

Chapter 6, Problem 31P

Interpretation Introduction

(a)

Interpretation:

The point on the graph corresponding the reactants needs to be indicated.

Concept introduction:

In chemistry, reactants are the raw chemical substances which are involvedin a chemical reaction at the beginning. An energy diagram shows the energy changes which occurs during a chemical reaction.

Interpretation Introduction

(b)

Interpretation:

The point on the graph corresponding to the products needs to be indicated.

Concept introduction:

In a chemical reaction, products are the final chemical substances which form at the end of a chemical reaction. An energy diagram shows the energy changes which occur during a chemical reaction.

Interpretation Introduction

(c)

Interpretation:

The transition state on the graph needs to be determined.

Concept introduction:

Transition state is the state relevant to the highest energy through the reaction coordinate. So, these transition states are shown as the highest peaks in the energy diagram.

Interpretation Introduction

(d)

Interpretation:

The energy gap between the reactant and the transition state in the graph needs to be identified.

Concept introduction:

Activation energy of a reactionis the amount of energy that must be provided to start a chemical reaction.

Interpretation Introduction

(e)

Interpretation:

The energy difference between reactants and products should be considered.

Concept introduction:

Enthalpy ( ΔH) of a reaction is the energy change occurs in the system, during the particular reaction.

Interpretation Introduction

(f)

Interpretation:

The highest energy peak position present in the reaction coordinate should be selected.

Concept introduction:

Highest energy position in the reaction coordinate is represented by the highest energy, least stable chemical species form in the reaction.

Interpretation Introduction

(g)

Interpretation:

The lowest energy position, the exothermic/endothermic nature of the reaction should be considered.

Concept introduction:

In an exothermic reaction heat is released thus, the energy of product is lower than that of reactant. On the other hand, in an endothermic reaction heat is absorbed thus, the energy of product is higher than that of reactant.

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Answer 4

Question

Chapter 6, Problem 31P

Interpretation Introduction

(a)

Interpretation:

The point on the graph corresponding the reactants needs to be indicated.

Concept introduction:

In chemistry, reactants are the raw chemical substances which are involvedin a chemical reaction at the beginning. An energy diagram shows the energy changes which occurs during a chemical reaction.

Interpretation Introduction

(b)

Interpretation:

The point on the graph corresponding to the products needs to be indicated.

Concept introduction:

In a chemical reaction, products are the final chemical substances which form at the end of a chemical reaction. An energy diagram shows the energy changes which occur during a chemical reaction.

Interpretation Introduction

(c)

Interpretation:

The transition state on the graph needs to be determined.

Concept introduction:

Transition state is the state relevant to the highest energy through the reaction coordinate. So, these transition states are shown as the highest peaks in the energy diagram.

Interpretation Introduction

(d)

Interpretation:

The energy gap between the reactant and the transition state in the graph needs to be identified.

Concept introduction:

Activation energy of a reactionis the amount of energy that must be provided to start a chemical reaction.

Interpretation Introduction

(e)

Interpretation:

The energy difference between reactants and products should be considered.

Concept introduction:

Enthalpy ( ΔH) of a reaction is the energy change occurs in the system, during the particular reaction.

Interpretation Introduction

(f)

Interpretation:

The highest energy peak position present in the reaction coordinate should be selected.

Concept introduction:

Highest energy position in the reaction coordinate is represented by the highest energy, least stable chemical species form in the reaction.

Interpretation Introduction

(g)

Interpretation:

The lowest energy position, the exothermic/endothermic nature of the reaction should be considered.

Concept introduction:

In an exothermic reaction heat is released thus, the energy of product is lower than that of reactant. On the other hand, in an endothermic reaction heat is absorbed thus, the energy of product is higher than that of reactant.

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Answer 5

Chapter 6, Problem 31P

Interpretation Introduction

(a)

Interpretation:

The point on the graph corresponding the reactants needs to be indicated.

Concept introduction:

In chemistry, reactants are the raw chemical substances which are involvedin a chemical reaction at the beginning. An energy diagram shows the energy changes which occurs during a chemical reaction.

Interpretation Introduction

(b)

Interpretation:

The point on the graph corresponding to the products needs to be indicated.

Concept introduction:

In a chemical reaction, products are the final chemical substances which form at the end of a chemical reaction. An energy diagram shows the energy changes which occur during a chemical reaction.

Interpretation Introduction

(c)

Interpretation:

The transition state on the graph needs to be determined.

Concept introduction:

Transition state is the state relevant to the highest energy through the reaction coordinate. So, these transition states are shown as the highest peaks in the energy diagram.

Interpretation Introduction

(d)

Interpretation:

The energy gap between the reactant and the transition state in the graph needs to be identified.

Concept introduction:

Activation energy of a reactionis the amount of energy that must be provided to start a chemical reaction.

Interpretation Introduction

(e)

Interpretation:

The energy difference between reactants and products should be considered.

Concept introduction:

Enthalpy ( ΔH) of a reaction is the energy change occurs in the system, during the particular reaction.

Interpretation Introduction

(f)

Interpretation:

The highest energy peak position present in the reaction coordinate should be selected.

Concept introduction:

Highest energy position in the reaction coordinate is represented by the highest energy, least stable chemical species form in the reaction.

Interpretation Introduction

(g)

Interpretation:

The lowest energy position, the exothermic/endothermic nature of the reaction should be considered.

Concept introduction:

In an exothermic reaction heat is released thus, the energy of product is lower than that of reactant. On the other hand, in an endothermic reaction heat is absorbed thus, the energy of product is higher than that of reactant.

Answer 6

Chapter 6, Problem 31P

Interpretation Introduction

(a)

Interpretation:

The point on the graph corresponding the reactants needs to be indicated.

Concept introduction:

In chemistry, reactants are the raw chemical substances which are involvedin a chemical reaction at the beginning. An energy diagram shows the energy changes which occurs during a chemical reaction.

Answer 7

Chapter 6, Problem 31P

Interpretation Introduction

(a)

Interpretation:

The point on the graph corresponding the reactants needs to be indicated.

Concept introduction:

In chemistry, reactants are the raw chemical substances which are involvedin a chemical reaction at the beginning. An energy diagram shows the energy changes which occurs during a chemical reaction.

Answer 8

Interpretation Introduction

(b)

Interpretation:

The point on the graph corresponding to the products needs to be indicated.

Concept introduction:

In a chemical reaction, products are the final chemical substances which form at the end of a chemical reaction. An energy diagram shows the energy changes which occur during a chemical reaction.

Answer 9

Interpretation Introduction

(b)

Interpretation:

The point on the graph corresponding to the products needs to be indicated.

Concept introduction:

In a chemical reaction, products are the final chemical substances which form at the end of a chemical reaction. An energy diagram shows the energy changes which occur during a chemical reaction.

Answer 10

Interpretation Introduction

(c)

Interpretation:

The transition state on the graph needs to be determined.

Concept introduction:

Transition state is the state relevant to the highest energy through the reaction coordinate. So, these transition states are shown as the highest peaks in the energy diagram.

Answer 11

Interpretation Introduction

(c)

Interpretation:

The transition state on the graph needs to be determined.

Concept introduction:

Transition state is the state relevant to the highest energy through the reaction coordinate. So, these transition states are shown as the highest peaks in the energy diagram.

Answer 12

Interpretation Introduction

(d)

Interpretation:

The energy gap between the reactant and the transition state in the graph needs to be identified.

Concept introduction:

Activation energy of a reactionis the amount of energy that must be provided to start a chemical reaction.

Answer 13

Interpretation Introduction

(d)

Interpretation:

The energy gap between the reactant and the transition state in the graph needs to be identified.

Concept introduction:

Activation energy of a reactionis the amount of energy that must be provided to start a chemical reaction.

Answer 14

Interpretation Introduction

(e)

Interpretation:

The energy difference between reactants and products should be considered.

Concept introduction:

Enthalpy ( ΔH) of a reaction is the energy change occurs in the system, during the particular reaction.

Answer 15

Interpretation Introduction

(e)

Interpretation:

The energy difference between reactants and products should be considered.

Concept introduction:

Enthalpy ( ΔH) of a reaction is the energy change occurs in the system, during the particular reaction.

Answer 16

Interpretation Introduction

(f)

Interpretation:

The highest energy peak position present in the reaction coordinate should be selected.

Concept introduction:

Highest energy position in the reaction coordinate is represented by the highest energy, least stable chemical species form in the reaction.

Answer 17

Interpretation Introduction

(f)

Interpretation:

The highest energy peak position present in the reaction coordinate should be selected.

Concept introduction:

Highest energy position in the reaction coordinate is represented by the highest energy, least stable chemical species form in the reaction.

Answer 18

Interpretation Introduction

(g)

Interpretation:

The lowest energy position, the exothermic/endothermic nature of the reaction should be considered.

Concept introduction:

In an exothermic reaction heat is released thus, the energy of product is lower than that of reactant. On the other hand, in an endothermic reaction heat is absorbed thus, the energy of product is higher than that of reactant.

Answer 19

Interpretation Introduction

(g)

Interpretation:

The lowest energy position, the exothermic/endothermic nature of the reaction should be considered.

Concept introduction:

In an exothermic reaction heat is released thus, the energy of product is lower than that of reactant. On the other hand, in an endothermic reaction heat is absorbed thus, the energy of product is higher than that of reactant.

Answer 20

Expert Solution & Answer

Answer 21

Expert Solution & Answer

Answer 22

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Answer 23

Ch. 6.1 - Prob. 6.1PP Ch. 6.1 - Prob. 6.1P Ch. 6.1 - Prob. 6.2PP Ch. 6.1 - Prob. 6.2P Ch. 6.2 - Using the values in Table 6.2, give H for each...Ch. 6.2 - Prob. 6.4PP Ch. 6.2 - Answer the following questions using the given...Ch. 6.2 - Given the H and balanced equation in Sample...Ch. 6.2 - Prob. 6.6PP Ch. 6.3 - Prob. 6.7PP

Solution Summary: The author explains how the graph corresponding to reactants, products, and transition states needs to be indicated.

Concept explainers

(c)

Interpretation:

The transition state on the graph needs to be determined.

Concept introduction:

Transition state is the state relevant to the highest energy through the reaction coordinate. So, these transition states are shown as the highest peaks in the energy diagram.

(d)

Interpretation:

The energy gap between the reactant and the transition state in the graph needs to be identified.

Concept introduction:

Activation energy of a reactionis the amount of energy that must be provided to start a chemical reaction.

(e)

Interpretation:

The energy difference between reactants and products should be considered.

Concept introduction:

Enthalpy ( ΔH) of a reaction is the energy change occurs in the system, during the particular reaction.

(f)

Interpretation:

The highest energy peak position present in the reaction coordinate should be selected.

Concept introduction:

Highest energy position in the reaction coordinate is represented by the highest energy, least stable chemical species form in the reaction.

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Chapter 6 Solutions

Solution Summary: The author explains how the graph corresponding to reactants, products, and transition states needs to be indicated.

Concept explainers

(c) Interpretation: The transition state on the graph needs to be determined. Concept introduction: Transition state is the state relevant to the highest energy through the reaction coordinate. So, these transition states are shown as the highest peaks in the energy diagram.

(d) Interpretation: The energy gap between the reactant and the transition state in the graph needs to be identified. Concept introduction: Activation energy of a reactionis the amount of energy that must be provided to start a chemical reaction.

(e) Interpretation: The energy difference between reactants and products should be considered. Concept introduction: Enthalpy ( ΔH) of a reaction is the energy change occurs in the system, during the particular reaction.

(f) Interpretation: The highest energy peak position present in the reaction coordinate should be selected. Concept introduction: Highest energy position in the reaction coordinate is represented by the highest energy, least stable chemical species form in the reaction.

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Chapter 6 Solutions

(c)

Interpretation:

The transition state on the graph needs to be determined.

Concept introduction:

Transition state is the state relevant to the highest energy through the reaction coordinate. So, these transition states are shown as the highest peaks in the energy diagram.

(d)

Interpretation:

The energy gap between the reactant and the transition state in the graph needs to be identified.

Concept introduction:

Activation energy of a reactionis the amount of energy that must be provided to start a chemical reaction.

(e)

Interpretation:

The energy difference between reactants and products should be considered.

Concept introduction:

Enthalpy ( ΔH) of a reaction is the energy change occurs in the system, during the particular reaction.

(f)

Interpretation:

The highest energy peak position present in the reaction coordinate should be selected.

Concept introduction:

Highest energy position in the reaction coordinate is represented by the highest energy, least stable chemical species form in the reaction.