Custom eBook for Organic Chemistry
Custom eBook for Organic Chemistry
2nd Edition
ISBN: 9798214171104
Author: Straumanis
Publisher: Cengage Custom
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Chapter 6, Problem 2E
(a)
Interpretation Introduction

Interpretation: The H atom that is anti to R3 and gauche to R3 needs to be determined.

Concept Introduction: Organic compounds are the compounds which are mainly composed C and H atoms. This is the branch of chemistry that deals with preparation, reactions, and properties of organic compounds. The molecular formula of organic compound represents the number of bonded atoms with their atomic symbols.

The structural formula represents all the bonded atoms with chemical bonds and the arrangement of atoms in the molecule. The compounds with same molecular formula and different structural formula are called as isomers. Isomers can be classified as constitutional isomers and stereoisomers.

Constitutional isomers can be defined as the pair of molecules with the same molecular formula but different structural formula. Stereoisomers have same molecular and structural formula but they have different arrangement of atoms in the three-dimensional space.

(b)
Interpretation Introduction

Interpretation: Therelation between R1 with R3 and R2 with R3 needs to be explained.

Concept Introduction: Organic compounds are the compounds which are mainly composed C and H atoms. This is the branch of chemistry that deals with preparation, reactions, and properties of organic compounds. The molecular formula of organic compound represents the number of bonded atoms with their atomic symbols.

The structural formula represents all the bonded atoms with chemical bonds and the arrangement of atoms in the molecule. The compounds with same molecular formula and different structural formula are called as isomers. Isomers can be classified as constitutional isomers and stereoisomers.

Constitutional isomers can be defined as the pair of molecules with the same molecular formula but different structural formula. Stereoisomers have same molecular and structural formula but they have different arrangement of atoms in the three-dimensional space.

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3. Consider the compounds below and determine if they are aromatic, antiaromatic, or non-aromatic. In case of aromatic or anti-aromatic, please indicate number of I electrons in the respective systems. (Hint: 1. Not all lone pair electrons were explicitly drawn and you should be able to tell that the bonding electrons and lone pair electrons should reside in which hybridized atomic orbital 2. You should consider ring strain- flexibility and steric repulsion that facilitates adoption of aromaticity or avoidance of anti- aromaticity) H H N N: NH2 N Aromaticity (Circle) Aromatic Aromatic Aromatic Aromatic Aromatic Antiaromatic Antiaromatic Antiaromatic Antiaromatic Antiaromatic nonaromatic nonaromatic nonaromatic nonaromatic nonaromatic aromatic TT electrons Me H Me Aromaticity (Circle) Aromatic Aromatic Aromatic Aromatic Aromatic Antiaromatic Antiaromatic Antiaromatic Antiaromatic Antiaromatic nonaromatic nonaromatic nonaromatic nonaromatic nonaromatic aromatic πT electrons H HH…

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