Custom eBook for Organic Chemistry
Custom eBook for Organic Chemistry
2nd Edition
ISBN: 9798214171104
Author: Straumanis
Publisher: Cengage Custom
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Chapter 6, Problem 16E
Interpretation Introduction

Interpretation: The reason for no Z or E form for 1-butene unlike 2-butene needs to be explained.

Concept introduction:

Based on IUPAC rules, the geometric isomers of alkene are named as cis or trans depending on the arrangement of groups. Here, the longest chains of carbon atoms are considered. But in case the chain is not long and is between two carbon molecule, and E-Z system comes to play which is based on CIP sequence rules. Here, the rules are based on priority. This comes to apply when the cis-trans system cannot be applied.

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6. Consider the following exothermic reaction below. 2Cu2+(aq) +41 (aq)2Cul(s) + 12(aq) a. If Cul is added, there will be a shift left/shift right/no shift (circle one). b. If Cu2+ is added, there will be a shift left/shift right/no shift (circle one). c. If a solution of AgNO3 is added, there will be a shift left/shift right/no shift (circle one). d. If the solvent hexane (C6H14) is added, there will be a shift left/shift right/no shift (circle one). Hint: one of the reaction species is more soluble in hexane than in water. e. If the reaction is cooled, there will be a shift left/shift right/no shift (circle one). f. Which of the changes above will change the equilibrium constant, K?
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