The name of Al(BrO 3 ) 3 .9H 2 O and chemical formula of cobalt(II) perchlorate pentahydrate is to be stated. Concept introduction: Few chemical compounds on crystallization from water solution produces crystals that contains water molecules as a part of their crystal structure. These water molecules of the crystals are called as water of crystallization or water of hydration. The crystals that results from the process of crystallization is referred as hydrate. Conversely, the water molecules can be driven away from the crystals by applying heat energy to afford anhydrous chemical compounds. The well-known example of a compound having water crystallization is CuSO 4 .5H 2 O. The anhydrous chemical compound CuSO 4 (colorless) is combined with 5 H 2 O molecules on crystallization from a water solution result in hydrated CuSO 4 .5H 2 O (blue). The name of this chemical compound is denoted as copper(II) sulfate penta hydrate. In this case, the prefix ‘penta’ is usually referred as the presence of 5 molecules (water).

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Chapter 6, Problem 17PE

Interpretation Introduction

Interpretation:

The name of Al(BrO₃)₃.9H₂O and chemical formula of cobalt(II) perchlorate pentahydrate is to be stated.

Concept introduction:

Few chemical compounds on crystallization from water solution produces crystals that contains water molecules as a part of their crystal structure. These water molecules of the crystals are called as water of crystallization or water of hydration. The crystals that results from the process of crystallization is referred as hydrate. Conversely, the water molecules can be driven away from the crystals by applying heat energy to afford anhydrous chemical compounds. The well-known example of a compound having water crystallization is CuSO₄.5H₂O. The anhydrous chemical compound CuSO₄ (colorless) is combined with 5 H₂O molecules on crystallization from a water solution result in hydrated CuSO₄.5H₂O (blue). The name of this chemical compound is denoted as copper(II) sulfate penta hydrate. In this case, the prefix ‘penta’ is usually referred as the presence of 5 molecules (water).

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Instructions: Complete the questions in the space provided. Show all your work 1. You are trying to determine the rate law expression for a reaction that you are completing at 25°C. You measure the initial reaction rate and the starting concentrations of the reactions for 4 trials. BrO³¯ (aq) + 5Br¯ (aq) + 6H* (aq) → 3Br₂ (l) + 3H2O (l) Initial rate Trial [BrO3] [H*] [Br] (mol/L) (mol/L) | (mol/L) (mol/L.s) 1 0.10 0.10 0.10 8.0 2 0.20 0.10 0.10 16 3 0.10 0.20 0.10 16 4 0.10 0.10 0.20 32 a. Based on the above data what is the rate law expression? b. Solve for the value of k (make sure to include proper units) 2. The proposed reaction mechanism is as follows: i. ii. BrО¸¯ (aq) + H+ (aq) → HBrO3 (aq) HBrO³ (aq) + H* (aq) → H₂BrO3* (aq) iii. H₂BrO³* (aq) + Br¯ (aq) → Br₂O₂ (aq) + H2O (l) [Fast] [Medium] [Slow] iv. Br₂O₂ (aq) + 4H*(aq) + 4Br‍(aq) → 3Br₂ (l) + H2O (l) [Fast] Evaluate the validity of this proposed reaction. Justify your answer.

е. Д CH3 D*, D20