Chemistry
Chemistry
4th Edition
ISBN: 9780078021527
Author: Julia Burdge
Publisher: McGraw-Hill Education
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Chapter 6, Problem 116AP
Interpretation Introduction

Interpretation:

The uncertainty in the position of the electron with given speed is to be determined, a comment on the result is to be stated, and the uncertainty in the position of the ball is to be determined.

Concept introduction:

Heisenberg gave the uncertainty principle, which statethat the product of the uncertainty in position and momentum of a particle cannot be less than h4π .

It is represented as follows:

ΔxΔph4π 

Here, h is Planck’s constant (6.63×1034 Js), and the uncertainty in position and momentum is Δx and Δp, respectively.

As momentum is the product of mass and velocity, the equation of Heisenberg uncertainty principle can also be represented as shown below:

ΔxmΔuh4π 

Here, Δx is uncertainty in the position of a particle, m is the mass of the particle, Δu is uncertainty in velocity, and h is Planck’s constant (6.63×1034 Js).

The minimum uncertainty in speed is calculated by using the following relation:

Δu=Speed×Uncertainty  of  speed

The uncertainty in momentum can be evaluated as

Δp=momentum×Uncertainty  of  momentum

The relationship between J and kg m2 s2 can be expressed as 1J=1 kg m2 s2.

The conversion factor is 1 kg m2 s21 J.

Expert Solution & Answer
Check Mark

Answer to Problem 116AP

Solution:

(a) 6×1011 m/s

(b) 7.9×1029 m

Explanation of Solution

a)The minimum uncertainty in an electron’s position

The mass of the electron is 9.1094×1031 kg.

The radius of a hydrogen atom is 5.29×1011 m.

The speed of the electron is 5×106 m/s.

The uncertainty in speed can be evaluated as

Δu=Speed×Uncertainty  of  speed

Δu=5×106 m/s×(0.2)=1×106 m/s

So, the uncertainty in the speed of the electronis 1×106 m/s.

The uncertainty in the position of theelectron can be evaluated as

Δx(9.1094×1031 kg)(1×106 m/s)=6.63×1034 Js4π Δx=6.63×1034 Js4π(9.1094×1031 kg)(1×106 m/s) (1 kg m2 s21 J)=5.8×1011 m/s=6×1011 m/s

Therefore, the uncertainty in the position of the electronis 6×1011 m/s.

Since the value for Δx of electron is greater than the radius of the hydrogen atom, it is hard to predict the exact location of the electron in the atom.

The momentum of 0.15 kg ball is 6.7 kgm/s.

b) Uncertainty in baseball’s position.

The momentum of 0.15 kg ball is 6.7 kgm/s.

The uncertainty in momentum can be evaluated as

Δp=momentum×Uncertainty  of  momentum

Δp=(1.0×107)(6.7 kgm/s)=6.7×107kgm/s

So, the uncertainty in the momentum of the baseball is 6.7×107kgm/s.

The value for Δx of the baseball can be evaluated as

ΔxΔp=h4π Δx(6.7×107kgm/s)=6.63×1034 Js4π Δx=6.63×1034 Js4π(6.7×107kgm/s) (1 kg m2 s21 J)=7.9×1029 m

Therefore, the value for Δx of the baseball is 7.9×1029 m.

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Chapter 6 Solutions

Chemistry

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