General Chemistry: Atoms First
2nd Edition
ISBN: 9780321809261
Author: John E. McMurry, Robert C. Fay
Publisher: Prentice Hall
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Textbook Question
Chapter 5.7, Problem 5.15P
Draw two electron-dot resonance structures for the formate ion, HCO2−, and sketch a π molecular orbital showing how the π electrons are delocalized over both oxygen atoms.
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Predict the major products of this organic reaction:
HBr (1 equiv)
cold
?
Some important notes:
• Draw the major product, or products, of this reaction in the drawing area below.
• You can draw the products in any arrangement you like.
• Pay careful attention to the reaction conditions, and only include the major products.
• Be sure to use wedge and dash bonds when necessary, for example to distinguish between major products that are enantiomers.
• Note that there is only 1 equivalent of HBr reactant, so you need not consider the case of multiple additions.
Erase something
Explanation
Check
2025 McGraw Hill LLC. All Rights Reserved. Ter
Q14. Fill this chart: (please refer to ppt notes/browser to answer these questions)
What alcohol is also called wood alcohol?
What is the common name of ethanol?
Draw the structure of phenol and thiophene?
Are bigger chain alcohol like heptanol and octanol
are soluble or insoluble in water and explain it ?
Are ethers soluble or insoluble in water?
What suffix and prefix are used for alcohol while
naming alcohol and ether?
What the process called when we add water to any
alkene to make alcohol?
Q16. Draw the diagram of following aromatic compound (practice from previous module)
Aniline
Phenol
Benzoic acid
Methyl benzoate
Q17. a. Write the oxidation reactions for the 2 propanol.
b. Write the oxidation reaction of the ethanol.
Question 11 of 18 (1 point) Question Attempt: 3 of
How many signals do you expect in the 'H NMR spectrum for this molecule?
Br
Br
Write the answer below.
Also, in each of the drawing areas below is a copy of the molecule, with Hs shown. In each copy, one of the H atoms is colored red. Highlight in red all other H
atoms that would contribute to the same signal as the H already highlighted red.
Note for advanced students: In this question, any multiplet is counted as one signal.
Number of signals in the 'H NMR spectrum.
1
For the molecule in the top drawing area, highlight in red any other H atoms that will contribute to
the same signal as the H atom already highlighted red.
If no other H atoms will contribute, check the box at right.
No additional Hs to color in top
molecule
Check
For the molecule in the bottom drawing area, highlight in red any other H atoms that will contribute
to the same signal as the H atom already highlighted red.
If no other H atoms will contribute, check the box…
Chapter 5 Solutions
General Chemistry: Atoms First
Ch. 5.1 - Predict the shapes of the following molecules or...Ch. 5.1 - Acetic acid, CH3CO2H, is the main organic...Ch. 5.1 - Benzene, C6H6, is a cyclic molecule in which all...Ch. 5.1 - What is the geometrical arrangement of charge...Ch. 5.3 - Describe the bonding in propane, C3H8, a fuel...Ch. 5.4 - Describe the hybridization of the carbon atom in...Ch. 5.4 - Describe the hybridization of each carbon atom in...Ch. 5.4 - Describe the hybridization of the carbon atom in...Ch. 5.4 - Describe the hybridization of the carbon atom in...Ch. 5.4 - Describe the hybridization of the carbon atom in...
Ch. 5.4 - Identify each of the following sets of hybrid...Ch. 5.4 - The following ball-and-stick molecular model is a...Ch. 5.5 - Construct an MO diagram for the He2+ ion. Is this...Ch. 5.6 - The B2 and C2 molecules have MO diagrams similar...Ch. 5.7 - Draw two electron-dot resonance structures for the...Ch. 5.7 - Why is molecular shape so important in biological...Ch. 5.7 - Prob. 5.17CPCh. 5 - What is the geometry around the central atom in...Ch. 5 - Prob. 5.19CPCh. 5 - Prob. 5.20CPCh. 5 - Prob. 5.21CPCh. 5 - Prob. 5.22CPCh. 5 - Prob. 5.23CPCh. 5 - Prob. 5.24SPCh. 5 - Prob. 5.25SPCh. 5 - Prob. 5.26SPCh. 5 - How many charge clouds are there around central...Ch. 5 - Prob. 5.28SPCh. 5 - Prob. 5.29SPCh. 5 - What shape do you expect for each of the following...Ch. 5 - Prob. 5.31SPCh. 5 - Prob. 5.32SPCh. 5 - Prob. 5.33SPCh. 5 - What bond angles do you expect for each of the...Ch. 5 - Prob. 5.35SPCh. 5 - Prob. 5.36SPCh. 5 - Prob. 5.37SPCh. 5 - Prob. 5.38SPCh. 5 - A potential replacement for the chlorofluorocarbon...Ch. 5 - Prob. 5.40SPCh. 5 - Prob. 5.41SPCh. 5 - Prob. 5.42SPCh. 5 - Prob. 5.43SPCh. 5 - What hybridization do you expect for atoms that...Ch. 5 - Prob. 5.45SPCh. 5 - Prob. 5.46SPCh. 5 - What hybridization would you expect for the...Ch. 5 - Prob. 5.48SPCh. 5 - Prob. 5.49SPCh. 5 - Prob. 5.50SPCh. 5 - Prob. 5.51SPCh. 5 - Prob. 5.52SPCh. 5 - Prob. 5.53SPCh. 5 - Prob. 5.54SPCh. 5 - Prob. 5.55SPCh. 5 - Prob. 5.56SPCh. 5 - Prob. 5.57SPCh. 5 - Prob. 5.58SPCh. 5 - Prob. 5.59SPCh. 5 - Prob. 5.60SPCh. 5 - Prob. 5.61SPCh. 5 - Prob. 5.62CHPCh. 5 - The following molecular model is a representation...Ch. 5 - Prob. 5.64CHPCh. 5 - Prob. 5.65CHPCh. 5 - Prob. 5.66CHPCh. 5 - Prob. 5.67CHPCh. 5 - Calcium carbide, CaC2, reacts with water to...Ch. 5 - Prob. 5.69CHPCh. 5 - The N2O5 molecule has six NO bonds and two NO ...Ch. 5 - In the cyanate ion, OCN, carbon is the central...Ch. 5 - Aspirin has the following connections among atoms....Ch. 5 - Prob. 5.73CHPCh. 5 - At high temperatures, sulfur vapor is...Ch. 5 - Carbon monoxide is produced by incomplete...Ch. 5 - Prob. 5.76CHPCh. 5 - Prob. 5.77CHPCh. 5 - Prob. 5.78CHPCh. 5 - The diatomic cyanide ion (CN) and nitrosonium ion...Ch. 5 - Prob. 5.80MPCh. 5 - Prob. 5.81MPCh. 5 - Prob. 5.82MP
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- Organic Chemistry Esterification reactions 1. Write the steps to prepare ester. 2. Write complete reaction of ethanol and acetic acid to make ester. 3. What does ester smell like? What are the uses of ester. 4. What the role of sulfuric acid in the esterification reactionarrow_forward11. Complete the following esterification reaction with names of all the reactants and products under. Hint: Remove the water and end up with ester R-C-OH + ROH R-C-OR + H₂O A carboxylic acid An alcohol An ester Water BYJU'S H-C-C O-H Нин C-C-C-H HAAA H O-C-C-C-H AAA Ethanoic acid Propanol Water Propyl ethanoate By com CH3COOH + CH3CH2CH2CH₂CH₂OH → Practice for alcohols aldehydes and ketones: 12. Draw the structures from the following names mixed of alcohol/aldehyde and ketone: a. 4-methyl cyclohexanone b. 3-methyl-2-pentenal c. 2,3-dimethylcyclohexanone d. 1,3propanediol or Propane 1,3 diol 13. Write systematic names for the following compounds identify functional group: a. b. (CH3)2CH-C OH c) CH(CH₂)-- OH -,-,arrow_forwardmay you please show all steps! i am having a hard time understanding and applying in this format, thank you!arrow_forward
- 10. Complete the substitution reaction of 2 pentanol with these reagents. Reagents & Reaction Conditions use practice sheet. Please write only major products, minor product like water, other gases are not required. Hint: In substitution of alcohol, we generally substitute OH group with Halogens like cl, Br, F using some reagent containing halogens. Ensure to add halogens to the same carbon number where you are removing OH from Examples Alcohols can be converted to Alkyl Halides with HX acids HBr H₂O HCI + H₂O HI + H₂O CH,CH₂OH + SOCI₂ CH,CH₂OH + PCI₁₂ A BBYJU'S CH CHCI + SO₂+ HCI CH₂CH CIP(OH), + HCI CH,CH₂OH + PCI CHCHCI + POCI + HCI CH,CH₂OH + PBr, CH,CH,Br + P(OH), + HBr 1. Reaction with HBr with 2 Pentanol 2.Reaction with HI with 2 pentanol © Byjus.com 3.Reaction with HCI+ZnCl,, with 2 pentanol (Zncl2 is catalyst no role) 4.Reaction with SOCI,, with 2 Pentanol 5.Reaction with PBr; or PCl, with 2 pentanolarrow_forward3. Is 2-methyl-2-propanol a primary, secondary, or tertiary alcohol? Write out the structures of 2-methyl-2-propanol and also any oxidation products of 2- methyl-2- propanol. If there is more than one oxidation product, give the structure of each of the products. 4. 2-Propanol is the IUPAC systematic name of this alcohol. It has a common name by which it is much better known (You'll see it in the grocery store or pharmacy). Give that common name 5. Aldehydes can be synthesized by the oxidation of. Please choose from below choices A. Primary alcohols B. Secondary alcohols C. Organic acids D. Inorganic acids 6. Tertiary alcohol Can undergo oxidation. yes or no. ? If yes then answer the product.arrow_forwardFinish the reactions hand written pleasearrow_forward
- Part A Identify each alcohol as primary, secondary, or tertiary Drag the appropriate items to their respective bins. CH₂ H₂C- -C-OH HO CH₂ Primary Он OH CH₂ OH CCH₂OH CH₂ сн Secondary Tertiary Reset Help CH,CH₂ (CH)CHCH,OH CH,CH,CH,CCH, CHOH CH₂ Different types of alcohol groups Alcohol and its reaction: 8. Combing two alcohol molecules below and completing the reaction with Product .( Hint Reaction called etherification as ether is formed and name the ether once you complete the reaction. Hint.: R-O-H+H-O-RR-O-R Do the reaction: CH₂OH + CH₂OH---→ + H-O-H 9. Write the reaction of formation of alcohol from alkene by adding water: Addition reaction also called hydration reaction as we are adding water which occur always in presence of acid Hint: Break the double bond and add H and OH if symmetrical then add anywhere if unsymmetrical then follow Markovnikov rule H should go to that double bone carbon which has more hydrogen CH2=CH2 + H₂O-→arrow_forwardComplete the reaction hand written pleasearrow_forwardPredict the major products of this organic reaction: HBr (1 equiv) cold ? Some important notes: • Draw the major product, or products, of this reaction in the drawing area below. • You can draw the products in any arrangement you like. • Pay careful attention to the reaction conditions, and only include the major products. • Be sure to use wedge and dash bonds when necessary, for example to distinguish between major products that are enantiomers. • Note that there is only 1 equivalent of HBr reactant, so you need not consider the case of multiple additions. dm Re Explanation Check ©2025 McGraw Hill LLC. All Rights Reserved. Termarrow_forward
- b) Use curved arrows to show the reaction of the radical with hydrogen bromide. Br: Br H .. Answer Bankarrow_forwardIndicate the reaction products when CH3COCH2COOCH2COOC2H5 (ethyl acetoacetoacetate) reacts with 1º OH-/H2O and 2º H3O+arrow_forwardDraw the formula of the compound 4-cyclohexyl butanamide?arrow_forward
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