General Chemistry: Atoms First
2nd Edition
ISBN: 9780321809261
Author: John E. McMurry, Robert C. Fay
Publisher: Prentice Hall
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Textbook Question
Chapter 5, Problem 5.30SP
What shape do you expect for each of the following molecules or ions?
- (a) SbF5
- (b) IF4+
- (c) SeO32−
- (d) CrO42−
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1.
Draw the Lewis structures for each of the following ions or molecules. For each, give (i) the
molecular shape, (ii) the electron pair geometry at the central atom, and (iii) the hybridization of the central
atom.
(a) POF3
(b) XeO₂F3+
(c) BrCl₂
(d) N3 (the central atom is N; two other N's are bonded to it)
(e) PF3
What are the electron-pair geometry and the molecular structure of each of the following molecules or ions?(a) ClF5(b) ClO2−(c) TeCl42−(d) PCl3(e) SeF4(f) PH2−
Determine the electron-group arrangement, molecular shape, and ideal bond angle(s) for each of the following:(a) SO₄²⁻(b) NO₂⁻(c) PH
Chapter 5 Solutions
General Chemistry: Atoms First
Ch. 5.1 - Predict the shapes of the following molecules or...Ch. 5.1 - Acetic acid, CH3CO2H, is the main organic...Ch. 5.1 - Benzene, C6H6, is a cyclic molecule in which all...Ch. 5.1 - What is the geometrical arrangement of charge...Ch. 5.3 - Describe the bonding in propane, C3H8, a fuel...Ch. 5.4 - Describe the hybridization of the carbon atom in...Ch. 5.4 - Describe the hybridization of each carbon atom in...Ch. 5.4 - Describe the hybridization of the carbon atom in...Ch. 5.4 - Describe the hybridization of the carbon atom in...Ch. 5.4 - Describe the hybridization of the carbon atom in...
Ch. 5.4 - Identify each of the following sets of hybrid...Ch. 5.4 - The following ball-and-stick molecular model is a...Ch. 5.5 - Construct an MO diagram for the He2+ ion. Is this...Ch. 5.6 - The B2 and C2 molecules have MO diagrams similar...Ch. 5.7 - Draw two electron-dot resonance structures for the...Ch. 5.7 - Why is molecular shape so important in biological...Ch. 5.7 - Prob. 5.17CPCh. 5 - What is the geometry around the central atom in...Ch. 5 - Prob. 5.19CPCh. 5 - Prob. 5.20CPCh. 5 - Prob. 5.21CPCh. 5 - Prob. 5.22CPCh. 5 - Prob. 5.23CPCh. 5 - Prob. 5.24SPCh. 5 - Prob. 5.25SPCh. 5 - Prob. 5.26SPCh. 5 - How many charge clouds are there around central...Ch. 5 - Prob. 5.28SPCh. 5 - Prob. 5.29SPCh. 5 - What shape do you expect for each of the following...Ch. 5 - Prob. 5.31SPCh. 5 - Prob. 5.32SPCh. 5 - Prob. 5.33SPCh. 5 - What bond angles do you expect for each of the...Ch. 5 - Prob. 5.35SPCh. 5 - Prob. 5.36SPCh. 5 - Prob. 5.37SPCh. 5 - Prob. 5.38SPCh. 5 - A potential replacement for the chlorofluorocarbon...Ch. 5 - Prob. 5.40SPCh. 5 - Prob. 5.41SPCh. 5 - Prob. 5.42SPCh. 5 - Prob. 5.43SPCh. 5 - What hybridization do you expect for atoms that...Ch. 5 - Prob. 5.45SPCh. 5 - Prob. 5.46SPCh. 5 - What hybridization would you expect for the...Ch. 5 - Prob. 5.48SPCh. 5 - Prob. 5.49SPCh. 5 - Prob. 5.50SPCh. 5 - Prob. 5.51SPCh. 5 - Prob. 5.52SPCh. 5 - Prob. 5.53SPCh. 5 - Prob. 5.54SPCh. 5 - Prob. 5.55SPCh. 5 - Prob. 5.56SPCh. 5 - Prob. 5.57SPCh. 5 - Prob. 5.58SPCh. 5 - Prob. 5.59SPCh. 5 - Prob. 5.60SPCh. 5 - Prob. 5.61SPCh. 5 - Prob. 5.62CHPCh. 5 - The following molecular model is a representation...Ch. 5 - Prob. 5.64CHPCh. 5 - Prob. 5.65CHPCh. 5 - Prob. 5.66CHPCh. 5 - Prob. 5.67CHPCh. 5 - Calcium carbide, CaC2, reacts with water to...Ch. 5 - Prob. 5.69CHPCh. 5 - The N2O5 molecule has six NO bonds and two NO ...Ch. 5 - In the cyanate ion, OCN, carbon is the central...Ch. 5 - Aspirin has the following connections among atoms....Ch. 5 - Prob. 5.73CHPCh. 5 - At high temperatures, sulfur vapor is...Ch. 5 - Carbon monoxide is produced by incomplete...Ch. 5 - Prob. 5.76CHPCh. 5 - Prob. 5.77CHPCh. 5 - Prob. 5.78CHPCh. 5 - The diatomic cyanide ion (CN) and nitrosonium ion...Ch. 5 - Prob. 5.80MPCh. 5 - Prob. 5.81MPCh. 5 - Prob. 5.82MP
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Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.Similar questions
- (a) Why do stable xenon fluorides have an even number of F atoms? (b) Why do the ionic species XeF₃⁺ and XeF₇⁻ have odd numbers of F atoms? (c) Predict the shape of XeF₃⁺ .arrow_forwardThe Lewis structure of BH2Cl (a) Is the molecule polar or nonpolar? (b) What is the hybridization of the carbon atom? (c) What is the geometric shape of the molecule?arrow_forwardIdentify the electron pair geometry and the molecular structure of each of the following molecules or ions:(a) IF6+(b) CF4(c) BF3(d) SiF5−(e) BeCl2arrow_forward
- Predict the electron pair geometry and the molecular structure of each of the following molecules or ions:(a) SF6(b) PCl5(c) BeH2(d) CH3+arrow_forwardWhich of these molecules has a linear molecular geometry and the molecule is polar? (A) CO2 (B) Cl2O (C) N2O (D) SO2arrow_forward. Assume that the third-period element phosphorus forms a diatomic molecule, P2, in an analogous way as nitrogen does to form N2. (a) Write the electronic configuration for P2. Use [Ne2] to represent the electron configuration for the first two periods. (b) Calculate its bond order. (c) What are its magnetic properties (diamagnetic or paramagnetic)?arrow_forward
- Give the hybridization of the metalloid and the molecular geometry for each of the following compounds or ions. (a) GeH4(b) SbF3(c) Te(OH)6(d) H2Te(e) GeF2(f) TeCl4(g) SiF62−(h) SbCl5(i) TeF6arrow_forward(a) Methane (CH4) and the perchlorate ion (ClO4- ) are bothdescribed as tetrahedral. What does this indicate about theirbond angles? (b) The NH3 molecule is trigonal pyramidal, while BF3 is trigonal planar. Which of these molecules is flat?arrow_forwardWhich of the following molecules or ions contain polar bonds?(a) O3(b) S8(c) O22−(d) NO3−(e) CO2(f) H2S(g) BH4−arrow_forward
- Determine the electron-group arrangement, molecular shape, and ideal bond angle(s) for each of the following:(a) O₃(b) H₃O⁺(c) NF₃arrow_forwardWhich of the following molecules does not have a dipole moment? (a) CH3Cl (b) CH2Cl2 (c) CFCl3 (d) CHCl3arrow_forwardSodium azide is a shock-sensitive compound that releases N2upon physical impact. The compound is used in automobileairbags. The azide ion is N3-. (a) Draw the Lewis structure of theazide ion that minimizes formal charge (it does not form a triangle).Is it linear or bent? (b) State the hybridization of the centralN atom in the azide ion. (c) How many σ bonds and how manyπ bonds does the central nitrogen atom make in the azide ion?arrow_forward
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