EBK BASIC CHEMISTRY
5th Edition
ISBN: 8220101472335
Author: Timberlake
Publisher: PEARSON
expand_more
expand_more
format_list_bulleted
Concept explainers
Textbook Question
Chapter 5.6, Problem 5.59QAP
Write the group number and draw the Lewis symbol for each of the following elements:
a. sulfur
b. nitrogen
c. calcium
d. sodium
e. gallium
Expert Solution & Answer
Want to see the full answer?
Check out a sample textbook solutionStudents have asked these similar questions
Part VII. The H-NMR of a compound with molecular formula C5 H 10 O2 is given below.
Find the following:
(a) The no. of protons corresponding to each signal in the spectra
(6) Give the structure of the compound and assign the signals to each
proton in the compound.
a
70.2
Integration Values
C5H10O2
b
47.7
C
46.5
d
69.5
3.6 3.5
3.4 3.3 3.2 3.1 3.0
2.9 2.8
2.7
2.6 2.5
2.4 2.3 2.2 2.1 2.0
Chemical Shift (ppm)
1.9
1.8
1.7 1.6
1.5
1.4 1.3 1.2
1.1 1.0
0.9 0.8
Part 111. 1 H-NMR spectrum of a compound with integration values in red is given below.
Answer the following:
(a) write the signals in the 'H-NMR spectrum to the corresponding protons on the structure
of the molecule below.
(b) Identify the theoretical multiplicities for each proton in the compound. Also give the possible.
complex splitting patterns assuming J values are not similar.
там
Br
22
2
3
6
4 7.2 7.0 6.8 6.6 6.4 6.2 6.0 5.8 5.6 5.4 5.2 5.0 4.8 4.6 4.4 4.2 4.0 3.8 3.6 3.4 3.2 3.0 2.8 2.6 2.4 2.2 2.0 1.8 1.6 1.4 1.2 1.0 0.8 0
Chemical Shift (ppm)
ra.
Br
2
3
6
6
2.5
2.4
2.3
2.2
2.1
2.0
1.9
1.8
1.7
1.6
1.5
1.4
1.3
1.2
1.1
1.0
0.9
0.8
Chemical Shift (ppm)
2
2
Br
7.3
7.2
7.1
7.0 6.9
6.7 6.6 6.5
6.4
6.3
6.2
6.1
6.0
Chemical Shift (ppm)
5.9
5.8 5.7
5.5 5.4 5.3 5.2
5.0 4.9
1600°
1538°C
1493°C
In the diagram, the letter L indicates
that it is a liquid. Indicate its
components in the upper region
where only L is indicated.
The
iron-iron carbide phase
diagram.
Temperature (°C)
1400
8
1394°C
y+L
1200
2.14
y, Austenite
10000
912°C
800a
0.76
0.022
600
400
(Fe)
a, Ferrite
Composition (at% C)
15
1147°C
a + Fe3C
2
3
Composition (wt% C)
L
2500
4.30
2000
y + Fe3C
727°C
1500
Cementite (Fe3C)
1000
4
5
6
6.70
Temperature (°F)
Chapter 5 Solutions
EBK BASIC CHEMISTRY
Ch. 5.1 - What is meant by the wavelength of UV light?Ch. 5.1 - How are the wavelength and frequency of light...Ch. 5.1 - What is the difference between “white” light and...Ch. 5.1 - Prob. 5.4QAPCh. 5.1 - Prob. 5.5QAPCh. 5.1 - AM radio waves have a frequency of 8105s-1 ....Ch. 5.1 - Prob. 5.7QAPCh. 5.1 - Prob. 5.8QAPCh. 5.1 - Which ty pe of electromagnetic radiation, cell...Ch. 5.1 - Prob. 5.10QAP
Ch. 5.1 - Prob. 5.11QAPCh. 5.1 - Prob. 5.12QAPCh. 5.1 - Place the following types of electromagnetic...Ch. 5.1 - Prob. 5.14QAPCh. 5.2 - What feature of an atomic spectrum indicates that...Ch. 5.2 - Prob. 5.16QAPCh. 5.2 - Prob. 5.17QAPCh. 5.2 - Prob. 5.18QAPCh. 5.2 - Prob. 5.19QAPCh. 5.2 - Identify the photon in each pair with the greater...Ch. 5.3 - Describe the shape of each of the following...Ch. 5.3 - Prob. 5.22QAPCh. 5.3 - Prob. 5.23QAPCh. 5.3 - Prob. 5.24QAPCh. 5.3 - Prob. 5.25QAPCh. 5.3 - Prob. 5.26QAPCh. 5.3 - Prob. 5.27QAPCh. 5.3 - Prob. 5.28QAPCh. 5.4 - Compare the terms electron configuration and...Ch. 5.4 - Prob. 5.30QAPCh. 5.4 - 5.31 Draw the orbital diagram for each of the...Ch. 5.4 - 5.32 Draw the orbital diagram for each of the...Ch. 5.4 - Prob. 5.33QAPCh. 5.4 - Prob. 5.34QAPCh. 5.4 - Prob. 5.35QAPCh. 5.4 - Prob. 5.36QAPCh. 5.4 - Prob. 5.37QAPCh. 5.4 - Prob. 5.38QAPCh. 5.4 - Prob. 5.39QAPCh. 5.4 - Prob. 5.40QAPCh. 5.5 - Use the sublevel blocks on the periodic table to...Ch. 5.5 - Prob. 5.42QAPCh. 5.5 - Prob. 5.43QAPCh. 5.5 - Prob. 5.44QAPCh. 5.5 - Prob. 5.45QAPCh. 5.5 - Prob. 5.46QAPCh. 5.5 - Use the periodic table to give the symbol of the...Ch. 5.5 - Prob. 5.48QAPCh. 5.5 - Prob. 5.49QAPCh. 5.5 - Use the periodic table to give the number of...Ch. 5.6 - What do the group numbers from 1A (1) to 8A (18)...Ch. 5.6 - Prob. 5.52QAPCh. 5.6 - Write the group number using both A/B and 1 to 18...Ch. 5.6 - Prob. 5.54QAPCh. 5.6 - Prob. 5.55QAPCh. 5.6 - Prob. 5.56QAPCh. 5.6 - Prob. 5.57QAPCh. 5.6 - Indicate the number of valence electrons in each...Ch. 5.6 - Write the group number and draw the Lewis symbol...Ch. 5.6 - Prob. 5.60QAPCh. 5.6 - Prob. 5.61QAPCh. 5.6 - Prob. 5.62QAPCh. 5.6 - Prob. 5.63QAPCh. 5.6 - Prob. 5.64QAPCh. 5.6 - Prob. 5.65QAPCh. 5.6 - Prob. 5.66QAPCh. 5.6 - Prob. 5.67QAPCh. 5.6 - Prob. 5.68QAPCh. 5.6 - Prob. 5.69QAPCh. 5.6 - Prob. 5.70QAPCh. 5.6 - Prob. 5.71QAPCh. 5.6 - Fill in each of the following blanks using higher...Ch. 5.6 - Prob. 5.73QAPCh. 5.6 - Prob. 5.74QAPCh. 5.6 - Prob. 5.75QAPCh. 5.6 - Prob. 5.76QAPCh. 5 - Prob. 5.77FUCh. 5 - Prob. 5.78FUCh. 5 - Prob. 5.79UTCCh. 5 - Prob. 5.80UTCCh. 5 - Prob. 5.81UTCCh. 5 - Prob. 5.82UTCCh. 5 - Prob. 5.83UTCCh. 5 - Prob. 5.84UTCCh. 5 - Prob. 5.85UTCCh. 5 - Prob. 5.86UTCCh. 5 - Prob. 5.87AQAPCh. 5 - Prob. 5.88AQAPCh. 5 - Prob. 5.89AQAPCh. 5 - Prob. 5.90AQAPCh. 5 - Prob. 5.91AQAPCh. 5 - Prob. 5.92AQAPCh. 5 - 5.93 a. What electron sublevel starts to fill...Ch. 5 - Prob. 5.94AQAPCh. 5 - Prob. 5.95AQAPCh. 5 - Prob. 5.96AQAPCh. 5 - Prob. 5.97AQAPCh. 5 - Prob. 5.98AQAPCh. 5 - Prob. 5.99AQAPCh. 5 - Prob. 5.100AQAPCh. 5 - Prob. 5.101AQAPCh. 5 - Prob. 5.102AQAPCh. 5 - Prob. 5.103AQAPCh. 5 - Why is the ionization energy of Br lower than that...Ch. 5 - Prob. 5.105AQAPCh. 5 - Prob. 5.106AQAPCh. 5 - Prob. 5.107AQAPCh. 5 - Prob. 5.108AQAPCh. 5 - Prob. 5.109AQAPCh. 5 - Prob. 5.110AQAPCh. 5 - Prob. 5.111AQAPCh. 5 - Prob. 5.112AQAPCh. 5 - Prob. 5.113CQCh. 5 - Prob. 5.114CQCh. 5 - Prob. 5.115CQCh. 5 - Prob. 5.116CQCh. 5 - Prob. 5.117CQCh. 5 - Prob. 5.118CQCh. 5 - Prob. 5.119CQCh. 5 - Prob. 5.120CQ
Knowledge Booster
Learn more about
Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.Similar questions
- Nonearrow_forwardPart II. Given below are the 'H-NMR spectrum at 300 MHz in CDC13 and mass spectrum using electron ionization of compound Brian. The FTIR of the said compound showed a strong peak at 1710 cm"). Determine the following: (a) molecular Formula and Degree of unsaturation of compound Brian (b) Basing on the given H-NMR spectrum tabulate the following (i) chemical shifts (ii) integration, ciii) multiplicity and (iv) interferences made for each signal (c) Draw the structure of compound Brian. ) ΕΙ 43 41 27 71 114 (M+) Hmmm 20 30 40 50 60 70 80 90 100 110 120 1H NMR spectrum 300 MHz in CDCl3 2.0 alle 1.0arrow_forwardThe iron-iron carbide phase diagram. In the diagram, the letter L indicates that it is a liquid. Indicate what its components are. Temperature (°C) 1600 10 Composition (at% C) 15 25 1538°C -1493°C 8 1400 1200 1394°C y+L L 2500 1147°C y. Austenite 2.14 4.30 2000 1000 912°C y + Fe3C 800ㅏ 0.76 0.022 600 a, Ferrite a + Fe3C 400 0 (Fe) Composition (wt% C) 727°C 1500 Cementite (Fe3C) 1000 6 6.70 Temperature (°F)arrow_forward
- Part V. Choose which isomer would give the 1H-NMR spectrum below. Justify your reasoning by assigning important signals to the Corresponding protons of the correct molecule. A D on of of of H H 88 2 90 7.8 7.6 7.4 80 5 6 [ppm] 7.2 6.8 6.6 6.4 ō [ppm]arrow_forwardShow work with explanation. don't give Ai generated solutionarrow_forwardQ7. a. Draw the line-bond structure of the major product for the following reaction, if a reaction occurs, assume monohalogenation. b. Calculate the product ratios using the following information (hint: use the number of hydrogens in each category present to calculate the ratios). Chlorination: 1° Reactivity=1 2° Reactivity=4 Heat + Cl2 3° Reactivity=5arrow_forward
- Please correct answer and don't use hand rating and don't use Ai solutionarrow_forwardQ10: Alkane halogenation a. Give the name and structures of the five isomeric hexanes. Page 4 of 5 Chem 0310 Organic Chemistry 1 Recitations b. For each isomer, give all the free radical monochlorination and monobromination products that are structurally isomeric.arrow_forwardQ9. The insecticide DDT (in the box below) is useful in controlling mosquito populations and has low toxicity to humans, but is dangerous to birds and fish. Hoping to alleviate the dangers, little Johnny Whizbang, an aspiring chemist, proposes a new version of DDT ("Bromo-DDT") and shows his synthesis to his boss. Will Johnny Whizbang's synthesis work? Or will he be fired? Assume there is an excess of bromine and polybrominated products can be separated. Explain why. CH3 Br2, light CBR3 ok-ok Br Br Br Br CI "Bromo-DDT" CCl 3 DDT (dichlorodiphenyltrichloroethane) CIarrow_forward
- Differentiate the terms Monotectic, Eutectic, Eutectoid, Peritectic, Peritectoid.arrow_forwardQ5. Predict the organic product(s) for the following transformations. If no reaction will take place (or the reaction is not synthetically useful), write "N.R.". Determine what type of transition state is present for each reaction (think Hammond Postulate). I Br₂ CH3 F2, light CH3 Heat CH3 F₂ Heat Br2, light 12, light CH3 Cl2, lightarrow_forwarda. For the following indicated bonds, rank them in order of decreasing AH° for homolytic cleavage. Based on your answer, which bond would be most likely to break homolytically? (a) (c) H3C CH3 .CH3 CH3 CH3 (b) Page 1 of 5 Chem 0310 Organic Chemistry 1 Recitations b. Draw all the possible radical products for 2-methylbutane, and determine which bond is most likely to be broken.arrow_forward
arrow_back_ios
SEE MORE QUESTIONS
arrow_forward_ios
Recommended textbooks for you
- Chemistry: Matter and ChangeChemistryISBN:9780078746376Author:Dinah Zike, Laurel Dingrando, Nicholas Hainen, Cheryl WistromPublisher:Glencoe/McGraw-Hill School Pub CoIntroductory Chemistry: A FoundationChemistryISBN:9781337399425Author:Steven S. Zumdahl, Donald J. DeCostePublisher:Cengage LearningChemistry for Today: General, Organic, and Bioche...ChemistryISBN:9781305960060Author:Spencer L. Seager, Michael R. Slabaugh, Maren S. HansenPublisher:Cengage Learning
- Chemical Principles in the LaboratoryChemistryISBN:9781305264434Author:Emil Slowinski, Wayne C. Wolsey, Robert RossiPublisher:Brooks Cole
Chemistry: Matter and Change
Chemistry
ISBN:9780078746376
Author:Dinah Zike, Laurel Dingrando, Nicholas Hainen, Cheryl Wistrom
Publisher:Glencoe/McGraw-Hill School Pub Co
Introductory Chemistry: A Foundation
Chemistry
ISBN:9781337399425
Author:Steven S. Zumdahl, Donald J. DeCoste
Publisher:Cengage Learning
Chemistry for Today: General, Organic, and Bioche...
Chemistry
ISBN:9781305960060
Author:Spencer L. Seager, Michael R. Slabaugh, Maren S. Hansen
Publisher:Cengage Learning
Chemical Principles in the Laboratory
Chemistry
ISBN:9781305264434
Author:Emil Slowinski, Wayne C. Wolsey, Robert Rossi
Publisher:Brooks Cole
The Bohr Model of the atom and Atomic Emission Spectra: Atomic Structure tutorial | Crash Chemistry; Author: Crash Chemistry Academy;https://www.youtube.com/watch?v=apuWi_Fbtys;License: Standard YouTube License, CC-BY