EBK BASIC CHEMISTRY
EBK BASIC CHEMISTRY
5th Edition
ISBN: 8220101472335
Author: Timberlake
Publisher: PEARSON
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Chapter 5, Problem 5.108AQAP
Interpretation Introduction

(a)

Interpretation:

The element which is a halogen should be identified.

Concept Introduction:

According to periodic trends, the atomic size of the element increases from top to bottom, thus, the amount of energy required removing an electron from its outermost shell decreases and it can easily give an electron and show metallic characteristic. Thus, on moving top to bottom, metallic character of an element increases.

Similarly, on moving left to right in a period, atomic size decreases thus, amount of energy required to remove an electron increases and it is difficult to remove an electron. Thus, non-metallic character increases.

Interpretation Introduction

(b)

Interpretation:

The element which has the smallest atomic size should be identified.

Concept Introduction:

According to periodic trends, the atomic size of the element increases from top to bottom, thus, the amount of energy required removing an electron from its outermost shell decreases and it can easily give an electron and show metallic characteristic. Thus, on moving top to bottom, metallic character of an element increases.

Similarly, on moving left to right in a period, atomic size decreases thus, amount of energy required to remove an electron increases and it is difficult to remove an electron. Thus, non-metallic character increases.

Interpretation Introduction

(c)

Interpretation:

The element which has the lowest ionization energy should be identified.

Concept Introduction:

According to periodic trends, the atomic size of the element increases from top to bottom, thus, the amount of energy required removing an electron from its outermost shell decreases and it can easily give an electron and show metallic characteristic. Thus, on moving top to bottom, metallic character of an element increases.

Similarly, on moving left to right in a period, atomic size decreases thus, amount of energy required to remove an electron increases and it is difficult to remove an electron. Thus, non-metallic character increases.

Interpretation Introduction

(d)

Interpretation:

The element which requires the most energy to remove an electron from its outermost shell should be identified.

Concept Introduction:

According to periodic trends, the atomic size of the element increases from top to bottom, thus, the amount of energy required removing an electron from its outermost shell decreases and it can easily give an electron and show metallic characteristic. Thus, on moving top to bottom, metallic character of an element increases.

Similarly, on moving left to right in a period, atomic size decreases thus, amount of energy required to remove an electron increases and it is difficult to remove an electron. Thus, non-metallic character increases.

Interpretation Introduction

(e)

Interpretation:

The element which is found in group 2A (2) and period 4 should be identified.

Concept Introduction:

According to periodic trends, the atomic size of the element increases from top to bottom, thus, the amount of energy required removing an electron from its outermost shell decreases and it can easily give an electron and show metallic characteristic. Thus, on moving top to bottom, metallic character of an element increases.

Similarly, on moving left to right in a period, atomic size decreases thus, amount of energy required to remove an electron increases and it is difficult to remove an electron. Thus, non-metallic character increases.

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2. Predict the NMR spectra for each of these two compounds by listing, in the NMR tables below, the chemical shift, the splitting, and the number of hydrogens associated with each predicted peak. Sort the peaks from largest chemical shift to lowest. **Not all slots must be filled** Peak Chemical Shift (d) 5.7 1 Multiplicity multiplate .......... 5.04 double of doublet 2 4.98 double of doublet 3 4.05 doublet of quartet 4 5 LO 3.80 quartet 1.3 doublet 6 Peak Chemical Shift (d) Multiplicity
Interpreting NMR spectra is a skill that often requires some amount of practice, which, in turn, necessitates access to a collection of NMR spectra. Beyond Labz Organic Synthesis and Organic Qualitative Analysis have spectral libraries containing over 700 1H NMR spectra. In this assignment, you will take advantage of this by first predicting the NMR spectra for two closely related compounds and then checking your predictions by looking up the actual spectra in the spectra library. After completing this assignment, you may wish to select other compounds for additional practice. 1. Write the IUPAC names for the following two structures: Question 2 Question 3 2. Predict the NMR spectra for each of these two compounds by listing, in the NMR tables below, the chemical shift, the splitting, and the number of hydrogens associated with each predicted peak. Sort the peaks from largest chemical shift to lowest. **Not all slots must be filled**
11:14 ... worksheets.beyondlabz.com 3. To check your predictions, click this link for Interpreting NMR Spectra 1. You will see a list of all the - compounds in the spectra library in alphabetical order by IUPAC name. Hovering over a name in the list will show the structure on the chalkboard. The four buttons on the top of the Spectra tab in the tray are used to select the different spectroscopic techniques for the selected compound. Make sure the NMR button has been selected. 4. Scroll through the list of names to find the names for the two compounds you have been given and click on the name to display the NMR spectrum for each. In the NMR tables below, list the chemical shift, the splitting, and the number of hydrogens associated with each peak for each compound. Compare your answers to your predictions. **Not all slots must be filled** Peak Chemical Shift (d) Multiplicity 1 2 3 4 5

Chapter 5 Solutions

EBK BASIC CHEMISTRY

Ch. 5.1 - Prob. 5.11QAPCh. 5.1 - Prob. 5.12QAPCh. 5.1 - Place the following types of electromagnetic...Ch. 5.1 - Prob. 5.14QAPCh. 5.2 - What feature of an atomic spectrum indicates that...Ch. 5.2 - Prob. 5.16QAPCh. 5.2 - Prob. 5.17QAPCh. 5.2 - Prob. 5.18QAPCh. 5.2 - Prob. 5.19QAPCh. 5.2 - Identify the photon in each pair with the greater...Ch. 5.3 - Describe the shape of each of the following...Ch. 5.3 - Prob. 5.22QAPCh. 5.3 - Prob. 5.23QAPCh. 5.3 - Prob. 5.24QAPCh. 5.3 - Prob. 5.25QAPCh. 5.3 - Prob. 5.26QAPCh. 5.3 - Prob. 5.27QAPCh. 5.3 - Prob. 5.28QAPCh. 5.4 - Compare the terms electron configuration and...Ch. 5.4 - Prob. 5.30QAPCh. 5.4 - 5.31 Draw the orbital diagram for each of the...Ch. 5.4 - 5.32 Draw the orbital diagram for each of the...Ch. 5.4 - Prob. 5.33QAPCh. 5.4 - Prob. 5.34QAPCh. 5.4 - Prob. 5.35QAPCh. 5.4 - Prob. 5.36QAPCh. 5.4 - Prob. 5.37QAPCh. 5.4 - Prob. 5.38QAPCh. 5.4 - Prob. 5.39QAPCh. 5.4 - Prob. 5.40QAPCh. 5.5 - Use the sublevel blocks on the periodic table to...Ch. 5.5 - Prob. 5.42QAPCh. 5.5 - Prob. 5.43QAPCh. 5.5 - Prob. 5.44QAPCh. 5.5 - Prob. 5.45QAPCh. 5.5 - Prob. 5.46QAPCh. 5.5 - Use the periodic table to give the symbol of the...Ch. 5.5 - Prob. 5.48QAPCh. 5.5 - Prob. 5.49QAPCh. 5.5 - Use the periodic table to give the number of...Ch. 5.6 - What do the group numbers from 1A (1) to 8A (18)...Ch. 5.6 - Prob. 5.52QAPCh. 5.6 - Write the group number using both A/B and 1 to 18...Ch. 5.6 - Prob. 5.54QAPCh. 5.6 - Prob. 5.55QAPCh. 5.6 - Prob. 5.56QAPCh. 5.6 - Prob. 5.57QAPCh. 5.6 - Indicate the number of valence electrons in each...Ch. 5.6 - Write the group number and draw the Lewis symbol...Ch. 5.6 - Prob. 5.60QAPCh. 5.6 - Prob. 5.61QAPCh. 5.6 - Prob. 5.62QAPCh. 5.6 - Prob. 5.63QAPCh. 5.6 - Prob. 5.64QAPCh. 5.6 - Prob. 5.65QAPCh. 5.6 - Prob. 5.66QAPCh. 5.6 - Prob. 5.67QAPCh. 5.6 - Prob. 5.68QAPCh. 5.6 - Prob. 5.69QAPCh. 5.6 - Prob. 5.70QAPCh. 5.6 - Prob. 5.71QAPCh. 5.6 - Fill in each of the following blanks using higher...Ch. 5.6 - Prob. 5.73QAPCh. 5.6 - Prob. 5.74QAPCh. 5.6 - Prob. 5.75QAPCh. 5.6 - Prob. 5.76QAPCh. 5 - Prob. 5.77FUCh. 5 - Prob. 5.78FUCh. 5 - Prob. 5.79UTCCh. 5 - Prob. 5.80UTCCh. 5 - Prob. 5.81UTCCh. 5 - Prob. 5.82UTCCh. 5 - Prob. 5.83UTCCh. 5 - Prob. 5.84UTCCh. 5 - Prob. 5.85UTCCh. 5 - Prob. 5.86UTCCh. 5 - Prob. 5.87AQAPCh. 5 - Prob. 5.88AQAPCh. 5 - Prob. 5.89AQAPCh. 5 - Prob. 5.90AQAPCh. 5 - Prob. 5.91AQAPCh. 5 - Prob. 5.92AQAPCh. 5 - 5.93 a. What electron sublevel starts to fill...Ch. 5 - Prob. 5.94AQAPCh. 5 - Prob. 5.95AQAPCh. 5 - Prob. 5.96AQAPCh. 5 - Prob. 5.97AQAPCh. 5 - Prob. 5.98AQAPCh. 5 - Prob. 5.99AQAPCh. 5 - Prob. 5.100AQAPCh. 5 - Prob. 5.101AQAPCh. 5 - Prob. 5.102AQAPCh. 5 - Prob. 5.103AQAPCh. 5 - Why is the ionization energy of Br lower than that...Ch. 5 - Prob. 5.105AQAPCh. 5 - Prob. 5.106AQAPCh. 5 - Prob. 5.107AQAPCh. 5 - Prob. 5.108AQAPCh. 5 - Prob. 5.109AQAPCh. 5 - Prob. 5.110AQAPCh. 5 - Prob. 5.111AQAPCh. 5 - Prob. 5.112AQAPCh. 5 - Prob. 5.113CQCh. 5 - Prob. 5.114CQCh. 5 - Prob. 5.115CQCh. 5 - Prob. 5.116CQCh. 5 - Prob. 5.117CQCh. 5 - Prob. 5.118CQCh. 5 - Prob. 5.119CQCh. 5 - Prob. 5.120CQ
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Periodic Properties of Elements | Chemistry | IIT-JEE | NEET | CBSE | Misostudy; Author: Misostudy;https://www.youtube.com/watch?v=L26rRWz4_AI;License: Standard YouTube License, CC-BY
Periodic Trends: Electronegativity, Ionization Energy, Atomic Radius - TUTOR HOTLINE; Author: Melissa Maribel;https://www.youtube.com/watch?v=0h8q1GIQ-H4;License: Standard YouTube License, CC-BY