Basic Chemistry (5th Edition)
5th Edition
ISBN: 9780134138046
Author: Karen C. Timberlake
Publisher: PEARSON
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Textbook Question
Chapter 5.2, Problem 5.15QAP
What feature of an atomic spectrum indicates that the energy emitted by heating an element is not continuous?
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10.
Stereochemistry. Assign R/S stereochemistry for the chiral center indicated on the
following compound. In order to recieve full credit, you MUST SHOW YOUR WORK!
H₂N
CI
OH
CI
カー
11. () Stereochemistry. Draw all possible stereoisomers of the following compound. Assign
R/S configurations for all stereoisomers and indicate the relationship between each as
enantiomer, diastereomer, or meso.
NH2
H
HNH,
-18
b)
8.
Indicate whether the following carbocation rearrangements are likely to occur
Please explain your rational using 10 words or less
not likely to occur
• The double bond is still in the
Same position
+
Likely
to oc
occur
WHY?
-3
H3C
Brave
Chair Conformers. Draw the chair conformer of the following substituted
cyclohexane. Peform a RING FLIP and indicate the most stable
conformation and briefly explain why using 20 words or less.
CI
2
-cobs ??
MUST INDICATE H -2
-2
Br
EQ
Cl
OR
AT
Br
H&
most stable
WHY?
- 4
CH
12
Conformational Analysis. Draw all 6 conformers (one above each letter) of the
compound below looking down the indicated bond. Write the letter of the
conformer with the HIGHEST and LOWEST in energies on the lines provided.
NOTE: Conformer A MUST be the specific conformer of the structure as drawn below
-4 NOT
HOH
OH
3
Conformer A:
Br
OH
A
Samo
Br H
04
Br
H
H3
CH₂
H
anti
stagere
Br CH
clipsed
H
Brott
H
IV
H
MISSING 2
-2
B
C
D
E
F
X
6
Conformer with HIGHEST ENERGY:
13. (1
structure
LOWEST ENERGY:
Nomenclature. a) Give the systematic (IUPAC) name structure. b) Draw the
corresponding to this name. HINT: Do not forget to indicate stereochemistry
when applicable.
a)
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2
"Br
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Parent name (noname)
4 Bromo
Sub = 2-methylethyl-4 Bromo nonane
b) (3R,4S)-3-chloro-4-ethyl-2,7-dimethyloctane
# -2
-2
Chapter 5 Solutions
Basic Chemistry (5th Edition)
Ch. 5.1 - What is meant by the wavelength of UV light?Ch. 5.1 - How are the wavelength and frequency of light...Ch. 5.1 - What is the difference between “white” light and...Ch. 5.1 - Prob. 5.4QAPCh. 5.1 - Prob. 5.5QAPCh. 5.1 - AM radio waves have a frequency of 8105s-1 ....Ch. 5.1 - Prob. 5.7QAPCh. 5.1 - Prob. 5.8QAPCh. 5.1 - Which ty pe of electromagnetic radiation, cell...Ch. 5.1 - Prob. 5.10QAP
Ch. 5.1 - Prob. 5.11QAPCh. 5.1 - Prob. 5.12QAPCh. 5.1 - Place the following types of electromagnetic...Ch. 5.1 - Prob. 5.14QAPCh. 5.2 - What feature of an atomic spectrum indicates that...Ch. 5.2 - Prob. 5.16QAPCh. 5.2 - Prob. 5.17QAPCh. 5.2 - Prob. 5.18QAPCh. 5.2 - Prob. 5.19QAPCh. 5.2 - Identify the photon in each pair with the greater...Ch. 5.3 - Describe the shape of each of the following...Ch. 5.3 - Prob. 5.22QAPCh. 5.3 - Prob. 5.23QAPCh. 5.3 - Prob. 5.24QAPCh. 5.3 - Prob. 5.25QAPCh. 5.3 - Prob. 5.26QAPCh. 5.3 - Prob. 5.27QAPCh. 5.3 - Prob. 5.28QAPCh. 5.4 - Compare the terms electron configuration and...Ch. 5.4 - Prob. 5.30QAPCh. 5.4 - 5.31 Draw the orbital diagram for each of the...Ch. 5.4 - 5.32 Draw the orbital diagram for each of the...Ch. 5.4 - Prob. 5.33QAPCh. 5.4 - Prob. 5.34QAPCh. 5.4 - Prob. 5.35QAPCh. 5.4 - Prob. 5.36QAPCh. 5.4 - Prob. 5.37QAPCh. 5.4 - Prob. 5.38QAPCh. 5.4 - Prob. 5.39QAPCh. 5.4 - Prob. 5.40QAPCh. 5.5 - Use the sublevel blocks on the periodic table to...Ch. 5.5 - Prob. 5.42QAPCh. 5.5 - Prob. 5.43QAPCh. 5.5 - Prob. 5.44QAPCh. 5.5 - Prob. 5.45QAPCh. 5.5 - Prob. 5.46QAPCh. 5.5 - Use the periodic table to give the symbol of the...Ch. 5.5 - Prob. 5.48QAPCh. 5.5 - Prob. 5.49QAPCh. 5.5 - Use the periodic table to give the number of...Ch. 5.6 - What do the group numbers from 1A (1) to 8A (18)...Ch. 5.6 - Prob. 5.52QAPCh. 5.6 - Write the group number using both A/B and 1 to 18...Ch. 5.6 - Prob. 5.54QAPCh. 5.6 - Prob. 5.55QAPCh. 5.6 - Prob. 5.56QAPCh. 5.6 - Prob. 5.57QAPCh. 5.6 - Indicate the number of valence electrons in each...Ch. 5.6 - Write the group number and draw the Lewis symbol...Ch. 5.6 - Prob. 5.60QAPCh. 5.6 - Prob. 5.61QAPCh. 5.6 - Prob. 5.62QAPCh. 5.6 - Prob. 5.63QAPCh. 5.6 - Prob. 5.64QAPCh. 5.6 - Prob. 5.65QAPCh. 5.6 - Prob. 5.66QAPCh. 5.6 - Prob. 5.67QAPCh. 5.6 - Prob. 5.68QAPCh. 5.6 - Prob. 5.69QAPCh. 5.6 - Prob. 5.70QAPCh. 5.6 - Prob. 5.71QAPCh. 5.6 - Fill in each of the following blanks using higher...Ch. 5.6 - Prob. 5.73QAPCh. 5.6 - Prob. 5.74QAPCh. 5.6 - Prob. 5.75QAPCh. 5.6 - Prob. 5.76QAPCh. 5 - Prob. 5.77FUCh. 5 - Prob. 5.78FUCh. 5 - Prob. 5.79UTCCh. 5 - Prob. 5.80UTCCh. 5 - Prob. 5.81UTCCh. 5 - Prob. 5.82UTCCh. 5 - Prob. 5.83UTCCh. 5 - Prob. 5.84UTCCh. 5 - Prob. 5.85UTCCh. 5 - Prob. 5.86UTCCh. 5 - Prob. 5.87AQAPCh. 5 - Prob. 5.88AQAPCh. 5 - Prob. 5.89AQAPCh. 5 - Prob. 5.90AQAPCh. 5 - Prob. 5.91AQAPCh. 5 - Prob. 5.92AQAPCh. 5 - 5.93 a. What electron sublevel starts to fill...Ch. 5 - Prob. 5.94AQAPCh. 5 - Prob. 5.95AQAPCh. 5 - Prob. 5.96AQAPCh. 5 - Prob. 5.97AQAPCh. 5 - Prob. 5.98AQAPCh. 5 - Prob. 5.99AQAPCh. 5 - Prob. 5.100AQAPCh. 5 - Prob. 5.101AQAPCh. 5 - Prob. 5.102AQAPCh. 5 - Prob. 5.103AQAPCh. 5 - Why is the ionization energy of Br lower than that...Ch. 5 - Prob. 5.105AQAPCh. 5 - Prob. 5.106AQAPCh. 5 - Prob. 5.107AQAPCh. 5 - Prob. 5.108AQAPCh. 5 - Prob. 5.109AQAPCh. 5 - Prob. 5.110AQAPCh. 5 - Prob. 5.111AQAPCh. 5 - Prob. 5.112AQAPCh. 5 - Prob. 5.113CQCh. 5 - Prob. 5.114CQCh. 5 - Prob. 5.115CQCh. 5 - Prob. 5.116CQCh. 5 - Prob. 5.117CQCh. 5 - Prob. 5.118CQCh. 5 - Prob. 5.119CQCh. 5 - Prob. 5.120CQ
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