(a) Interpretation: The cause of pressure of the gas in terms of the kinetic molecular theory should be explained. Concept Introduction: When the particles of gas are in constant motion they exhibit collisions with elasticity perfectly. It explains the relationship among pressure, volume and temperature in gases that depends on the temperature of the kinetic energy in the particles of the moving objects.

Question

Lewis Structure, Hybridization & Molecular Geometry a) Draw the Lewis Structure of the molecules; Label the hybridization of each carbon atom; Predict the approximate molecular geometry around each carbon atom. CH3CHO CH3CN b) Draw the Lewis Structure of Nitromethane; Predict the approximate molecular geometry around the nitrogen atom. CH3NO2 c) Draw the Lewis Structure; Label the hybridization of the boron atom; Predict the approximate molecular geometry. BF3 BF4

Answer 1

Question

Chapter 5, Problem 66P

Interpretation Introduction

(a)

Interpretation:

The cause of pressure of the gas in terms of the kinetic molecular theory should be explained.

Concept Introduction:

When the particles of gas are in constant motion they exhibit collisions with elasticity perfectly. It explains the relationship among pressure, volume and temperature in gases that depends on the temperature of the kinetic energy in the particles of the moving objects.

Interpretation Introduction

(b)

Interpretation:

The cause of temperature of the gas in terms of the kinetic molecular theory should be explained.

Concept Introduction:

When the particles of gas are in constant motion they exhibit collisions with elasticity perfectly. It explains the relationship among pressure, volume and temperature in gases that depends on the temperature of the kinetic energy in the particles of the moving objects.

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Lewis Structure, Hybridization & Molecular Geometry a) Draw the Lewis Structure of the molecules; Label the hybridization of each carbon atom; Predict the approximate molecular geometry around each carbon atom. CH3CHO CH3CN b) Draw the Lewis Structure of Nitromethane; Predict the approximate molecular geometry around the nitrogen atom. CH3NO2 c) Draw the Lewis Structure; Label the hybridization of the boron atom; Predict the approximate molecular geometry. BF3 BF4

a. The structure of the bicarbonate (hydrogen carbonate) ion, HCO3-, HCO3 " is best described as a hybrid of several contributing resonance forms, two of which are shown here. HO :0: HO + :Ö: Bicarbonate is crucial for the control of body pH (for example, blood pH 7.4). A more self-indulgent use is in baking soda, where it serves as a source of CO2 CO2 gas, which gives bread and pastry their fluffy constituency. (i) Draw at least one additional resonance form. = (ii) Using curved "electron-pushing" arrows, show how these Lewis structures may be interconverted by movement of electron pairs. (iii) Determine which form or forms will be the major contributor(s) to the real structure of bicarbonate, explaining your answer on the basis of the criteria in Section 1-5.

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