(a) Interpretation: The alkene that is required for the formation of given alcohol is to be stated. Concept introduction: Hydroboration reaction is a two-step reaction, which involves conversion of alkene into alcohol. This type of reaction follows anti-Markovnikov’s rule. Anti-Markovnikov’s rule states that the positive part of acid attached to that carbon atom in C=C bond which carries lesser number of hydrogen atoms and the negative part of acid will attach to that carbon atom in C=C bond which has higher number of hydrogen atoms.

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Answer 1

Question

Chapter 5, Problem 5.9P

Interpretation Introduction

(a)

Interpretation:

The alkene that is required for the formation of given alcohol is to be stated.

Concept introduction:

Hydroboration reaction is a two-step reaction, which involves conversion of alkene into alcohol. This type of reaction follows anti-Markovnikov’s rule.

Anti-Markovnikov’s rule states that the positive part of acid attached to that carbon atom in C=C bond which carries lesser number of hydrogen atoms and the negative part of acid will attach to that carbon atom in C=C bond which has higher number of hydrogen atoms.

Interpretation Introduction

(b)

Interpretation:

The alkene that is required for the formation of given alcohol is to be stated.

Concept introduction:

Hydroboration reaction is a two-step reaction, which involves conversion of alkene into alcohol. This type of reaction follows anti-Markovnikov’s rule.

Anti-Markovnikov’s rule states that the positive part of acid attached to that carbon atom in C=C bond which carries lesser number of hydrogen atoms and the negative part of acid will attach to that carbon atom in C=C bond which has higher number of hydrogen atoms.

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Instructions: Complete the questions in the space provided. Show all your work 1. You are trying to determine the rate law expression for a reaction that you are completing at 25°C. You measure the initial reaction rate and the starting concentrations of the reactions for 4 trials. BrO³¯ (aq) + 5Br¯ (aq) + 6H* (aq) → 3Br₂ (l) + 3H2O (l) Initial rate Trial [BrO3] [H*] [Br] (mol/L) (mol/L) | (mol/L) (mol/L.s) 1 0.10 0.10 0.10 8.0 2 0.20 0.10 0.10 16 3 0.10 0.20 0.10 16 4 0.10 0.10 0.20 32 a. Based on the above data what is the rate law expression? b. Solve for the value of k (make sure to include proper units) 2. The proposed reaction mechanism is as follows: i. ii. BrО¸¯ (aq) + H+ (aq) → HBrO3 (aq) HBrO³ (aq) + H* (aq) → H₂BrO3* (aq) iii. H₂BrO³* (aq) + Br¯ (aq) → Br₂O₂ (aq) + H2O (l) [Fast] [Medium] [Slow] iv. Br₂O₂ (aq) + 4H*(aq) + 4Br‍(aq) → 3Br₂ (l) + H2O (l) [Fast] Evaluate the validity of this proposed reaction. Justify your answer.

е. Д CH3 D*, D20

C. NaOMe, Br Br

Answer 2

Question

Chapter 5, Problem 5.9P

Interpretation Introduction

(a)

Interpretation:

The alkene that is required for the formation of given alcohol is to be stated.

Concept introduction:

Hydroboration reaction is a two-step reaction, which involves conversion of alkene into alcohol. This type of reaction follows anti-Markovnikov’s rule.

Anti-Markovnikov’s rule states that the positive part of acid attached to that carbon atom in C=C bond which carries lesser number of hydrogen atoms and the negative part of acid will attach to that carbon atom in C=C bond which has higher number of hydrogen atoms.

Interpretation Introduction

(b)

Interpretation:

The alkene that is required for the formation of given alcohol is to be stated.

Concept introduction:

Hydroboration reaction is a two-step reaction, which involves conversion of alkene into alcohol. This type of reaction follows anti-Markovnikov’s rule.

Anti-Markovnikov’s rule states that the positive part of acid attached to that carbon atom in C=C bond which carries lesser number of hydrogen atoms and the negative part of acid will attach to that carbon atom in C=C bond which has higher number of hydrogen atoms.

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Answer 3

Question

Chapter 5, Problem 5.9P

Interpretation Introduction

(a)

Interpretation:

The alkene that is required for the formation of given alcohol is to be stated.

Concept introduction:

Hydroboration reaction is a two-step reaction, which involves conversion of alkene into alcohol. This type of reaction follows anti-Markovnikov’s rule.

Anti-Markovnikov’s rule states that the positive part of acid attached to that carbon atom in C=C bond which carries lesser number of hydrogen atoms and the negative part of acid will attach to that carbon atom in C=C bond which has higher number of hydrogen atoms.

Interpretation Introduction

(b)

Interpretation:

The alkene that is required for the formation of given alcohol is to be stated.

Concept introduction:

Hydroboration reaction is a two-step reaction, which involves conversion of alkene into alcohol. This type of reaction follows anti-Markovnikov’s rule.

Anti-Markovnikov’s rule states that the positive part of acid attached to that carbon atom in C=C bond which carries lesser number of hydrogen atoms and the negative part of acid will attach to that carbon atom in C=C bond which has higher number of hydrogen atoms.

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Answer 4

Question

Chapter 5, Problem 5.9P

Interpretation Introduction

(a)

Interpretation:

The alkene that is required for the formation of given alcohol is to be stated.

Concept introduction:

Hydroboration reaction is a two-step reaction, which involves conversion of alkene into alcohol. This type of reaction follows anti-Markovnikov’s rule.

Anti-Markovnikov’s rule states that the positive part of acid attached to that carbon atom in C=C bond which carries lesser number of hydrogen atoms and the negative part of acid will attach to that carbon atom in C=C bond which has higher number of hydrogen atoms.

Interpretation Introduction

(b)

Interpretation:

The alkene that is required for the formation of given alcohol is to be stated.

Concept introduction:

Hydroboration reaction is a two-step reaction, which involves conversion of alkene into alcohol. This type of reaction follows anti-Markovnikov’s rule.

Anti-Markovnikov’s rule states that the positive part of acid attached to that carbon atom in C=C bond which carries lesser number of hydrogen atoms and the negative part of acid will attach to that carbon atom in C=C bond which has higher number of hydrogen atoms.

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Answer 5

Chapter 5, Problem 5.9P

Interpretation Introduction

(a)

Interpretation:

The alkene that is required for the formation of given alcohol is to be stated.

Concept introduction:

Hydroboration reaction is a two-step reaction, which involves conversion of alkene into alcohol. This type of reaction follows anti-Markovnikov’s rule.

Anti-Markovnikov’s rule states that the positive part of acid attached to that carbon atom in C=C bond which carries lesser number of hydrogen atoms and the negative part of acid will attach to that carbon atom in C=C bond which has higher number of hydrogen atoms.

Interpretation Introduction

(b)

Interpretation:

The alkene that is required for the formation of given alcohol is to be stated.

Concept introduction:

Hydroboration reaction is a two-step reaction, which involves conversion of alkene into alcohol. This type of reaction follows anti-Markovnikov’s rule.

Anti-Markovnikov’s rule states that the positive part of acid attached to that carbon atom in C=C bond which carries lesser number of hydrogen atoms and the negative part of acid will attach to that carbon atom in C=C bond which has higher number of hydrogen atoms.

Answer 6

Chapter 5, Problem 5.9P

Interpretation Introduction

(a)

Interpretation:

The alkene that is required for the formation of given alcohol is to be stated.

Concept introduction:

Hydroboration reaction is a two-step reaction, which involves conversion of alkene into alcohol. This type of reaction follows anti-Markovnikov’s rule.

Anti-Markovnikov’s rule states that the positive part of acid attached to that carbon atom in C=C bond which carries lesser number of hydrogen atoms and the negative part of acid will attach to that carbon atom in C=C bond which has higher number of hydrogen atoms.

Answer 7

Chapter 5, Problem 5.9P

Interpretation Introduction

(a)

Interpretation:

The alkene that is required for the formation of given alcohol is to be stated.

Concept introduction:

Hydroboration reaction is a two-step reaction, which involves conversion of alkene into alcohol. This type of reaction follows anti-Markovnikov’s rule.

Anti-Markovnikov’s rule states that the positive part of acid attached to that carbon atom in C=C bond which carries lesser number of hydrogen atoms and the negative part of acid will attach to that carbon atom in C=C bond which has higher number of hydrogen atoms.

Answer 8

Interpretation Introduction

(b)

Interpretation:

The alkene that is required for the formation of given alcohol is to be stated.

Concept introduction:

Hydroboration reaction is a two-step reaction, which involves conversion of alkene into alcohol. This type of reaction follows anti-Markovnikov’s rule.

Anti-Markovnikov’s rule states that the positive part of acid attached to that carbon atom in C=C bond which carries lesser number of hydrogen atoms and the negative part of acid will attach to that carbon atom in C=C bond which has higher number of hydrogen atoms.

Answer 9

Interpretation Introduction

(b)

Interpretation:

The alkene that is required for the formation of given alcohol is to be stated.

Concept introduction:

Hydroboration reaction is a two-step reaction, which involves conversion of alkene into alcohol. This type of reaction follows anti-Markovnikov’s rule.

Anti-Markovnikov’s rule states that the positive part of acid attached to that carbon atom in C=C bond which carries lesser number of hydrogen atoms and the negative part of acid will attach to that carbon atom in C=C bond which has higher number of hydrogen atoms.

Answer 10

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Answer 11

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Answer 12

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Answer 13

Ch. 5 - Prob. 5.1P Ch. 5 - Prob. 5.2P Ch. 5 - Prob. 5.3P Ch. 5 - Prob. 5.4P Ch. 5 - Prob. 5.5P Ch. 5 - Prob. 5.6P Ch. 5 - Prob. 5.7P Ch. 5 - Prob. 5.8P Ch. 5 - Prob. 5.9P Ch. 5 - Prob. 5.10P

Solution Summary: The author explains that hydroboration reaction is a two-step reaction, which involves conversion of alkene into alcohol.

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Chapter 5 Solutions