ORGANIC CHEMISTRY SAPLING ACCESS + ETEX
6th Edition
ISBN: 9781319306977
Author: LOUDON
Publisher: INTER MAC
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Question
Chapter 5, Problem 5.22P
Interpretation Introduction
(a)
Interpretation:
The structure of the free radical intermediate in the peroxide-initiated reaction of hydrogen bromide with the given
Concept introduction:
The general steps followed by free-radical addition reaction are stated below:
• First step is initiation that involves formation of radical.
• Second step is propagation.
• Third step is the termination that involves the formation of stable bond.
Interpretation Introduction
(b)
Interpretation:
The structure of the free radical intermediate in the peroxide-initiated reaction of hydrogen bromide with the given alkene is to be drawn.
Concept introduction:
The general steps followed by free-radical addition reaction are stated below:
• First step is initiation that involves formation of radical.
• Second step is propagation.
• Third step is the termination that involves the formation of stable bond.
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2. (Part B). Identify a sequence of FGI that prepares the Synthesis Target 2,4-dimethoxy-
pentane. All carbons in the Synthesis Target must start as carbons in either ethyne, propyne
or methanol. Hint: use your analysis of Product carbons' origins (Part A) to identify possible
structure(s) of a precursor that can be converted to the Synthesis Target using one FGI.
All carbons in the Synthesis
Target must start as carbons
in one of the three compounds
below.
H = -H H = -Me
ethyne
propyne
Synthesis Target
2,4-dimethoxypentane
MeOH
methanol
OMe OMe
MeO.
OMe
C₂H₁₂O₂
Product carbons' origins
Draw a box around product
C's that came from A1.
Draw a dashed box around
product C's that came from B1.
Draw the skeletal ("line") structure of the smallest organic molecule that produces potassium 3-hydroxypropanoate when reacted with KOH.
Click and drag to start drawing a
structure.
S
Draw the skeleatal struc
Chapter 5 Solutions
ORGANIC CHEMISTRY SAPLING ACCESS + ETEX
Ch. 5 - Prob. 5.1PCh. 5 - Prob. 5.2PCh. 5 - Prob. 5.3PCh. 5 - Prob. 5.4PCh. 5 - Prob. 5.5PCh. 5 - Prob. 5.6PCh. 5 - Prob. 5.7PCh. 5 - Prob. 5.8PCh. 5 - Prob. 5.9PCh. 5 - Prob. 5.10P
Ch. 5 - Prob. 5.11PCh. 5 - Prob. 5.12PCh. 5 - Prob. 5.13PCh. 5 - Prob. 5.14PCh. 5 - Prob. 5.15PCh. 5 - Prob. 5.16PCh. 5 - Prob. 5.17PCh. 5 - Prob. 5.18PCh. 5 - Prob. 5.19PCh. 5 - Prob. 5.20PCh. 5 - Prob. 5.21PCh. 5 - Prob. 5.22PCh. 5 - Prob. 5.23PCh. 5 - Prob. 5.24PCh. 5 - Prob. 5.25PCh. 5 - Prob. 5.26PCh. 5 - Prob. 5.27APCh. 5 - Prob. 5.28APCh. 5 - Prob. 5.29APCh. 5 - Prob. 5.30APCh. 5 - Prob. 5.31APCh. 5 - Prob. 5.32APCh. 5 - Prob. 5.33APCh. 5 - Prob. 5.34APCh. 5 - Prob. 5.35APCh. 5 - Prob. 5.36APCh. 5 - Prob. 5.37APCh. 5 - Prob. 5.38APCh. 5 - Prob. 5.39APCh. 5 - Prob. 5.40APCh. 5 - Prob. 5.41APCh. 5 - Prob. 5.42APCh. 5 - Prob. 5.43APCh. 5 - Prob. 5.44APCh. 5 - Prob. 5.45APCh. 5 - Prob. 5.46APCh. 5 - Prob. 5.47APCh. 5 - Prob. 5.48APCh. 5 - Prob. 5.49APCh. 5 - Prob. 5.50APCh. 5 - Prob. 5.51APCh. 5 - Prob. 5.52APCh. 5 - Prob. 5.53APCh. 5 - Prob. 5.54AP
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