Introduction to General, Organic and Biochemistry
11th Edition
ISBN: 9781285869759
Author: Frederick A. Bettelheim, William H. Brown, Mary K. Campbell, Shawn O. Farrell, Omar Torres
Publisher: Cengage Learning
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Chapter 5, Problem 5.115P
5-115 Ammonium nitrite decomposes upon heating to form nitrogen gas and water vapor according to the following unbalanced
When a sample is decomposed in a test tube, 511 mL Of wet N2(g) is collected over water at 26°C and 745 torr total pressure. How many grams of dry NH4NO2(s) were initially decomposed? The vapor pressure of water at 26°C is 25.2 torr.
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Chapter 5 Solutions
Introduction to General, Organic and Biochemistry
Ch. 5.3 - Prob. 5.1PCh. 5.3 - Prob. 5.2PCh. 5.3 - Prob. 5.3PCh. 5.4 - Prob. 5.4PCh. 5.4 - Prob. 5.5PCh. 5.4 - Prob. 5.6PCh. 5.5 - Prob. 5.7PCh. 5.7 - Problem 5-8 Will the molecules in each set form a...Ch. 5.10 - Prob. 5.9PCh. 5.10 - Prob. 5.10P
Ch. 5.10 - Prob. 5.11PCh. 5 - Prob. 5.12PCh. 5 - Prob. 5.13PCh. 5 - Prob. 5.14PCh. 5 - Prob. 5.15PCh. 5 - 5-16 Answer true or false. (a) For a sample of gas...Ch. 5 - Prob. 5.17PCh. 5 - Prob. 5.18PCh. 5 - Prob. 5.19PCh. 5 - Prob. 5.20PCh. 5 - Prob. 5.21PCh. 5 - Prob. 5.22PCh. 5 - Prob. 5.23PCh. 5 - Prob. 5.24PCh. 5 - 5-25 A gas in a bulb as in Figure 5-3 registers a...Ch. 5 - Prob. 5.26PCh. 5 - 5-27 A sample of the inhalation anesthetic gas...Ch. 5 - Prob. 5.28PCh. 5 - Prob. 5.29PCh. 5 - Prob. 5.30PCh. 5 - 5-31 A balloon used for atmospheric research has a...Ch. 5 - Prob. 5.32PCh. 5 - 5-33 A certain quantity of helium gas is at a...Ch. 5 - 5-34 A sample of 30.0 mL of krypton gas, Kr, is at...Ch. 5 - 5-35 A 26.4-mL sample of ethylene gas, C2H4, has a...Ch. 5 - Prob. 5.36PCh. 5 - 5-37 A sample of a gas at 77°C and 1.33 atm...Ch. 5 - 5-38 What is the volume in liters occupied by 1.21...Ch. 5 - 5-39 An 8.00-g sample of a gas occupies 22.4 L at...Ch. 5 - Prob. 5.40PCh. 5 - 5-41 Does the density of a gas increase, decrease,...Ch. 5 - Prob. 5.42PCh. 5 - Prob. 5.43PCh. 5 - Prob. 5.44PCh. 5 - Prob. 5.45PCh. 5 - 5-46 Calculate the molar mass of a gas if 3.30 g...Ch. 5 - Prob. 5.47PCh. 5 - Prob. 5.48PCh. 5 - Prob. 5.49PCh. 5 - 5-50 How many molecules of CO are in 100. L of CO...Ch. 5 - Prob. 5.51PCh. 5 - Prob. 5.52PCh. 5 - Prob. 5.53PCh. 5 - 5-54 Automobile air bags are inflated by nitrogen...Ch. 5 - Prob. 5.55PCh. 5 - 5-56 The three main components of dry air and the...Ch. 5 - Prob. 5.57PCh. 5 - Prob. 5.58PCh. 5 - Prob. 5.59PCh. 5 - Prob. 5.60PCh. 5 - Prob. 5.61PCh. 5 - Prob. 5.62PCh. 5 - Prob. 5.63PCh. 5 - Prob. 5.64PCh. 5 - Prob. 5.65PCh. 5 - Prob. 5.66PCh. 5 - Prob. 5.67PCh. 5 - Prob. 5.68PCh. 5 - Prob. 5.69PCh. 5 - Prob. 5.70PCh. 5 - Prob. 5.71PCh. 5 - Prob. 5.72PCh. 5 - Prob. 5.73PCh. 5 - Prob. 5.74PCh. 5 - 5-75 The heat of vaporization of liquid Freon-12,...Ch. 5 - Prob. 5.76PCh. 5 - Prob. 5.77PCh. 5 - Prob. 5.78PCh. 5 - Prob. 5.79PCh. 5 - Prob. 5.80PCh. 5 - 5-81 Compare the number of calories absorbed when...Ch. 5 - Prob. 5.82PCh. 5 - Prob. 5.83PCh. 5 - Prob. 5.84PCh. 5 - Prob. 5.85PCh. 5 - 5-86 Using the phase diagram of water (Figure...Ch. 5 - Prob. 5.87PCh. 5 - Prob. 5.88PCh. 5 - 5-89 (Chemical Connections 5C) In a...Ch. 5 - Prob. 5.90PCh. 5 - Prob. 5.91PCh. 5 - Prob. 5.92PCh. 5 - Prob. 5.93PCh. 5 - Prob. 5.94PCh. 5 - Prob. 5.95PCh. 5 - Prob. 5.96PCh. 5 - Prob. 5.97PCh. 5 - Prob. 5.98PCh. 5 - Prob. 5.99PCh. 5 - Prob. 5.100PCh. 5 - Prob. 5.101PCh. 5 - Prob. 5.102PCh. 5 - Prob. 5.103PCh. 5 - Prob. 5.104PCh. 5 - Prob. 5.105PCh. 5 - 5-106 The normal boiling point of hexane, C6H14,...Ch. 5 - 5-107 If 60.0 g of NH3 occupies 35.1 L under a...Ch. 5 - Prob. 5.108PCh. 5 - Prob. 5.109PCh. 5 - Prob. 5.110PCh. 5 - 5-111 Diving, particularly SCUBA (Self-Contained...Ch. 5 - Prob. 5.112PCh. 5 - 5-113 Ammonia and gaseous hydrogen chloride react...Ch. 5 - 5-114 Carbon dioxide gas, saturated with water...Ch. 5 - 5-115 Ammonium nitrite decomposes upon heating to...Ch. 5 - Prob. 5.116PCh. 5 - Prob. 5.117PCh. 5 - 5-118 Isooctane, which has a chemical formula...Ch. 5 - Prob. 5.119PCh. 5 - Prob. 5.120P
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- 93 The complete combustion of octane can be used as a model for the burning of gasoline: 2C8H18+25O216CO2+18H2O Assuming that this equation provides a reasonable model of the actual combustion process, what volume of air at 1.0 atm and 25°C must be taken into an engine to burn 1 gallon of gasoline? (The partial pressure of oxygen in air is 0.21 atm and the density of liquid octane is 0.70 g/mL.)arrow_forward5-114 Carbon dioxide gas, saturated with water vapor, can be produced by the addition of aqueous acid to calcium carbonate based on the following balanced net ionic equation: (a) How many moles of wet CO (g), collected at 60.°C and 774 torr total pressure, are produced by the complete reaction of 10.0 g of CaCO3 with excess acid? (b) What volume does this wet CO2 occupy? (c) What volume would the CO2 occupy at 774 torr if a desiccant (a chemical drying agent) were added to remove the water? The vapor pressure of water at 60.°C is 149.4 mm Hg.arrow_forward47 HCl(g) reacts with ammonia gas, NH3(g), to form solid ammonium chloride. If a sample of ammonia occupying 250 mL at 21 C and a pressure of 140 torr is allowed to react with excess HCl, what mass of NH4Cl will form?arrow_forward
- 105 The decomposition of mercury(II) thiocyanate produces an odd brown snake-like mass that is so unusual the process was once used in fireworks displays. There are actually several reactions that take place when the solid Hg(SCN)2 is ignited: 2Hg(SCN)2(s)2HgS(s)+CS2(s)+C3N4(s)CS2(s)+3O2(g)CO2(g)+2SO2(g)2C3N4(s)3(CN)2(g)+N2(g)HgS(s)+O2(g)Hg(l)+SO2(g) A 42.4-g sample of Hg(SCN)2 is placed into a 2.4-L vessel at 21°C. The vessel also contains air at a pressure of 758 torr. The container is sealed and the mixture is ignited, causing the reaction sequence above to occur. Once the reaction is complete, the container is cooled back to the original temperature of 21°C. (a) Without doing numerical calculations, predict whether the final pressure in the vessel will be greater than, less than, or equal to the initial pressure. Explain your answer. (b) Calculate the final pressure and compare your result with your prediction. (Assume that the mole fraction of O2 in air is 0.21.)arrow_forwardA 275-mL sample of CO gas is collected over water at 31C and 755 mmHg. If the temperature of the gas collection apparatus rises to 39C, what is the new volume of the sample? Assume that the barometric pressure does not change.arrow_forward61 As one step in its purification, nickel metal reacts with carbon monoxide to form a compound called nickel tetracarbonyl, Ni(CO)4, which is a gas at temperature above about 316 K. A 2.000-L flask is filled with CO gas to a pressure of 748 torr at 350.0 K, and then 5.00 g of Ni is added. If the reaction describe occurs and goes to completion at constant temperature, what will the final pressure in the falsk be?arrow_forward
- 5-25 A gas in a bulb as in Figure 5-3 registers a pressure of 833 mm Hg in the manometer in which the reference arm of the U-shaped tube (A) is sealed and evacuated. What will the difference in the mercury levels be if the reference arm of the U-shaped tube is open to atmospheric pressure (760 mm Hg)?arrow_forward5-107 If 60.0 g of NH3 occupies 35.1 L under a pressure of 77.2 in. Hg, what is the temperature of the gas, in °C?arrow_forwardperform stoichiometric ca1cu1uions for reactions involving gases as reactants or products.arrow_forward
- 5-118 Isooctane, which has a chemical formula C8H18 is the component of gasoline from which the term octane rating derives. (a) Write the balanced chemical equation for the combustion of isooctane. (b) The density of isooctane is 0.792 g/mL. How many kg of C02 are produced each year by the annual U.S. gasoline consumption of L? (c) What is the volume in liters of this CO2 at STP? (d) The chemical formula for isooctane can be represented by (CH3)3CCH2CH(CH3)2. Draw a Lewis structure of isooctane. (e) Another molecule with the same molecular formula is octane, which can be represented by: When comparing isooctane and octane, one structure is observed to have a boiling point of 99°C, while another is known to have a boiling point Of 125°C. Which substance, isooctane or octane, is expected to have the higher boiling point? (f) Determine whether isooctane or octane is expected to have the greater vapor pressure.arrow_forward5-54 Automobile air bags are inflated by nitrogen gas. When a significant collision occurs, an electronic sensor triggers the decomposition of sodium azide to form nitrogen gas and sodium metal. The nitrogen gas then inflates nylon bags, which protect the driver and front-seat passenger from impact with the dashboard and windshield. What volume of nitrogen gas measured at 1 atm and 27°C is formed by the decomposition of 100. g of sodium azide?arrow_forwardHelium gas, He, at 22C and 1.00 atm occupied a vessel whose volume was 2.54 L. What volume would this gas occupy if it were cooled to liquid-nitrogen temperature (197C)?arrow_forward
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