Chemistry: Principles and Practice
3rd Edition
ISBN: 9780534420123
Author: Daniel L. Reger, Scott R. Goode, David W. Ball, Edward Mercer
Publisher: Cengage Learning
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Chapter 5, Problem 5.101QE
In the 1880s, Frederick Trouton noted that the enthalpy of vaporization of 1 mol pure liquid is approximately 88 times the boiling point, Tb, of the liquid on the Kelvin scale. This relationship is called Trouton’s rule and is represented by the thermochemical equation
liquid → gas ΔH = 88 · Tb, joules
Combined with an empirical formula from chemical analysis, Trouton’s rule can be used to find the molecular formula of a compound, as illustrated here. A compound that contains only carbon and hydrogen is 85.6% C and 14.4% H. Its enthalpy of vaporization is 389 J/g, and it boils at a temperature of 322 K.
- (a) What is the empirical formula of this compound?
- (b) Use Trouton’s rule to calculate the approximate enthalpy or vaporization or one mole of the compound. Combine the enthalpy of vaporization per mole with that same quantity per gram to obtain an approximate molar mass of the compound.
- (c) Use the results of parts (a) and (b) to find the molecular formula of this compound. Remember that the molecular mass must be exactly a whole-number multiple of the empirical formula mass, so considerable rounding may be needed.
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Chapter 5 Solutions
Chemistry: Principles and Practice
Ch. 5 - Why must the physical states of all reactants and...Ch. 5 - Why is chemical energy classified as a form of...Ch. 5 - What is the difference between the enthalpy of...Ch. 5 - Classify each process as exothermic or...Ch. 5 - Explain why the specific heat of the contents of...Ch. 5 - Prob. 5.6QECh. 5 - Define heat. What are its units? How does it...Ch. 5 - Prob. 5.8QECh. 5 - Prob. 5.9QECh. 5 - Prob. 5.10QE
Ch. 5 - Prob. 5.11QECh. 5 - Is the Sun exothermic or endothermic? Is it any...Ch. 5 - Under what circumstances is the heat of a process...Ch. 5 - Prob. 5.14QECh. 5 - Prob. 5.15QECh. 5 - Prob. 5.16QECh. 5 - Prob. 5.17QECh. 5 - Prob. 5.18QECh. 5 - Prob. 5.19QECh. 5 - Prob. 5.20QECh. 5 - Prob. 5.21QECh. 5 - Prob. 5.22QECh. 5 - Prob. 5.23QECh. 5 - Prob. 5.24QECh. 5 - Prob. 5.25QECh. 5 - Prob. 5.26QECh. 5 - Prob. 5.27QECh. 5 - Prob. 5.28QECh. 5 - Prob. 5.29QECh. 5 - Prob. 5.30QECh. 5 - Prob. 5.31QECh. 5 - A chemical reaction occurs and absorbs 64.7 cal....Ch. 5 - The enthalpy change for the following reaction is...Ch. 5 - Prob. 5.34QECh. 5 - The thermochemical equation for the burning of...Ch. 5 - When lightning strikes, the energy can force...Ch. 5 - One step in the manufacturing of sulfuric acid is...Ch. 5 - If nitric acid were sufficiently heated, it can be...Ch. 5 - Prob. 5.39QECh. 5 - Prob. 5.40QECh. 5 - Prob. 5.41QECh. 5 - The combustion of 1.00 mol liquid methyl alcohol...Ch. 5 - Another reaction that is used to propel rockets is...Ch. 5 - Prob. 5.44QECh. 5 - Prob. 5.45QECh. 5 - Prob. 5.46QECh. 5 - Prob. 5.47QECh. 5 - Prob. 5.48QECh. 5 - Prob. 5.49QECh. 5 - Prob. 5.50QECh. 5 - The enthalpy change when 1 mol methane (CH4) is...Ch. 5 - Prob. 5.52QECh. 5 - Prob. 5.53QECh. 5 - How much energy is required to raise the...Ch. 5 - How much heat, in kilojoules, must be removed to...Ch. 5 - Prob. 5.56QECh. 5 - Prob. 5.57QECh. 5 - Prob. 5.58QECh. 5 - Prob. 5.59QECh. 5 - Prob. 5.60QECh. 5 - When 7.11 g NH4NO3 is added to 100 mL water, the...Ch. 5 - A 50-mL solution of a dilute AgNO3 solution is...Ch. 5 - A 0.470-g sample of magnesium reacts with 200 g...Ch. 5 - Dissolving 6.00 g CaCl2 in 300 mL of water causes...Ch. 5 - Draw an energy-level diagram (e.g., see Figure...Ch. 5 - Prob. 5.66QECh. 5 - Prob. 5.67QECh. 5 - Prob. 5.68QECh. 5 - Calculate H for the reaction...Ch. 5 - Prob. 5.70QECh. 5 - Given the thermochemical equations...Ch. 5 - In the process of isolating iron from its ores,...Ch. 5 - Prob. 5.73QECh. 5 - Prob. 5.75QECh. 5 - Prob. 5.77QECh. 5 - Prob. 5.78QECh. 5 - Prob. 5.79QECh. 5 - Prob. 5.80QECh. 5 - Prob. 5.81QECh. 5 - Prob. 5.82QECh. 5 - Calculate H when a 38-g sample of glucose,...Ch. 5 - Prob. 5.84QECh. 5 - The octane number of gasoline is based on a...Ch. 5 - One of the components of jet engine fuel is...Ch. 5 - Prob. 5.87QECh. 5 - Prob. 5.88QECh. 5 - When a 2.30-g sample of magnesium dissolves in...Ch. 5 - Prob. 5.90QECh. 5 - Prob. 5.91QECh. 5 - What mass of acetylene, C2H2(g), must be burned to...Ch. 5 - It takes 677 J of heat to increase the temperature...Ch. 5 - Prob. 5.94QECh. 5 - Prob. 5.96QECh. 5 - The enthalpy of combustion of liquid n-hexane,...Ch. 5 - What is Hrxn for reaction of iron(III) oxide and...Ch. 5 - Prob. 5.99QECh. 5 - Prob. 5.100QECh. 5 - In the 1880s, Frederick Trouton noted that the...Ch. 5 - Prob. 5.102QECh. 5 - Prob. 5.103QECh. 5 - Prob. 5.104QECh. 5 - Prob. 5.105QECh. 5 - A compound is 82.7% carbon and 17.3% hydrogen, and...Ch. 5 - Prob. 5.107QECh. 5 - Prob. 5.108QE
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