Chemistry: Principles and Practice
3rd Edition
ISBN: 9780534420123
Author: Daniel L. Reger, Scott R. Goode, David W. Ball, Edward Mercer
Publisher: Cengage Learning
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Chapter 5, Problem 5.56QE
Interpretation Introduction
Interpretation:
Heat that must be removed to decrease the temperature has to be determined using the given data.
Concept Introduction:
The temperature change
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Examine the reaction below. Highlight all bonds that have broken in the reactant.
Br H
H₂C-C-
-H
5
H-C-H
H-C-H
BIE
们
OH
H H
H₂C-C=
H-C-H
H-C-H
Classify each of the following as either a substitution, elimination, or addition reaction.
CH3
CH3
CH2=CH₂
CH2=C-CH2-OH + Br₂
Br-CH2-C
-CH₂-OH
Br
CH,CH3
CH3-C-CH-CH2-CH3
он
° CH₂
HO
C-C-CH3 + NH3
CH₂
он
CH3-CH-O-CH3
O-CH3
CH3-C-CH3 + H₂O
O-CH3
CH3CH₂
H
+ H₂O
CH3-C=C-CH2-CH3
• CHI
Δ
Å CH
CH3
H+
CH3
C-H + HO-CH3
H"
Q-CH₂
CH3-C-CH3 + HO-CH3
OH
O substitution
O elimination
addition
substitution
O elimination
addition
O substitution
elimination
addition
O substitution
O elimination
addition
substitution
O elimination
00
addition
Search 5:45 PM Sun Dec 15
Quiz 9
...
ล 25%0
A
Done
Quiz #9 =
Name:
Draw the major products of the following. Show Stereochemistry when applicable:
1. OsO4
A
2. NaHSO 3, H 20
Cl₂
➤ C
H2, Pd/C
E
HBr
1. Hg(OAc) 2, H₂O
2. NaBH 4
Ꭰ
KI, H3PO4
F
KMnO4, H3O+
KMnO4, H2O
G
H
HBr
Br2
J
CH2N2
➤
K
CH2I2, Zn(Cu)
Cl2, CH3OH
C
1. 03
2. Zn, H3O+
HCI
1. BH 3
N
M
2. NaOH, H 202
KMnO4, NaOH
H₂O
P
Br2, H2O
R
1. BH 3
2. NaOH, H 202
Cl2, CH3CH2OH T
Chapter 5 Solutions
Chemistry: Principles and Practice
Ch. 5 - Why must the physical states of all reactants and...Ch. 5 - Why is chemical energy classified as a form of...Ch. 5 - What is the difference between the enthalpy of...Ch. 5 - Classify each process as exothermic or...Ch. 5 - Explain why the specific heat of the contents of...Ch. 5 - Prob. 5.6QECh. 5 - Define heat. What are its units? How does it...Ch. 5 - Prob. 5.8QECh. 5 - Prob. 5.9QECh. 5 - Prob. 5.10QE
Ch. 5 - Prob. 5.11QECh. 5 - Is the Sun exothermic or endothermic? Is it any...Ch. 5 - Under what circumstances is the heat of a process...Ch. 5 - Prob. 5.14QECh. 5 - Prob. 5.15QECh. 5 - Prob. 5.16QECh. 5 - Prob. 5.17QECh. 5 - Prob. 5.18QECh. 5 - Prob. 5.19QECh. 5 - Prob. 5.20QECh. 5 - Prob. 5.21QECh. 5 - Prob. 5.22QECh. 5 - Prob. 5.23QECh. 5 - Prob. 5.24QECh. 5 - Prob. 5.25QECh. 5 - Prob. 5.26QECh. 5 - Prob. 5.27QECh. 5 - Prob. 5.28QECh. 5 - Prob. 5.29QECh. 5 - Prob. 5.30QECh. 5 - Prob. 5.31QECh. 5 - A chemical reaction occurs and absorbs 64.7 cal....Ch. 5 - The enthalpy change for the following reaction is...Ch. 5 - Prob. 5.34QECh. 5 - The thermochemical equation for the burning of...Ch. 5 - When lightning strikes, the energy can force...Ch. 5 - One step in the manufacturing of sulfuric acid is...Ch. 5 - If nitric acid were sufficiently heated, it can be...Ch. 5 - Prob. 5.39QECh. 5 - Prob. 5.40QECh. 5 - Prob. 5.41QECh. 5 - The combustion of 1.00 mol liquid methyl alcohol...Ch. 5 - Another reaction that is used to propel rockets is...Ch. 5 - Prob. 5.44QECh. 5 - Prob. 5.45QECh. 5 - Prob. 5.46QECh. 5 - Prob. 5.47QECh. 5 - Prob. 5.48QECh. 5 - Prob. 5.49QECh. 5 - Prob. 5.50QECh. 5 - The enthalpy change when 1 mol methane (CH4) is...Ch. 5 - Prob. 5.52QECh. 5 - Prob. 5.53QECh. 5 - How much energy is required to raise the...Ch. 5 - How much heat, in kilojoules, must be removed to...Ch. 5 - Prob. 5.56QECh. 5 - Prob. 5.57QECh. 5 - Prob. 5.58QECh. 5 - Prob. 5.59QECh. 5 - Prob. 5.60QECh. 5 - When 7.11 g NH4NO3 is added to 100 mL water, the...Ch. 5 - A 50-mL solution of a dilute AgNO3 solution is...Ch. 5 - A 0.470-g sample of magnesium reacts with 200 g...Ch. 5 - Dissolving 6.00 g CaCl2 in 300 mL of water causes...Ch. 5 - Draw an energy-level diagram (e.g., see Figure...Ch. 5 - Prob. 5.66QECh. 5 - Prob. 5.67QECh. 5 - Prob. 5.68QECh. 5 - Calculate H for the reaction...Ch. 5 - Prob. 5.70QECh. 5 - Given the thermochemical equations...Ch. 5 - In the process of isolating iron from its ores,...Ch. 5 - Prob. 5.73QECh. 5 - Prob. 5.75QECh. 5 - Prob. 5.77QECh. 5 - Prob. 5.78QECh. 5 - Prob. 5.79QECh. 5 - Prob. 5.80QECh. 5 - Prob. 5.81QECh. 5 - Prob. 5.82QECh. 5 - Calculate H when a 38-g sample of glucose,...Ch. 5 - Prob. 5.84QECh. 5 - The octane number of gasoline is based on a...Ch. 5 - One of the components of jet engine fuel is...Ch. 5 - Prob. 5.87QECh. 5 - Prob. 5.88QECh. 5 - When a 2.30-g sample of magnesium dissolves in...Ch. 5 - Prob. 5.90QECh. 5 - Prob. 5.91QECh. 5 - What mass of acetylene, C2H2(g), must be burned to...Ch. 5 - It takes 677 J of heat to increase the temperature...Ch. 5 - Prob. 5.94QECh. 5 - Prob. 5.96QECh. 5 - The enthalpy of combustion of liquid n-hexane,...Ch. 5 - What is Hrxn for reaction of iron(III) oxide and...Ch. 5 - Prob. 5.99QECh. 5 - Prob. 5.100QECh. 5 - In the 1880s, Frederick Trouton noted that the...Ch. 5 - Prob. 5.102QECh. 5 - Prob. 5.103QECh. 5 - Prob. 5.104QECh. 5 - Prob. 5.105QECh. 5 - A compound is 82.7% carbon and 17.3% hydrogen, and...Ch. 5 - Prob. 5.107QECh. 5 - Prob. 5.108QE
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- Select the stronger base: H-CEN equally basic H H H H-C-N H Select the stronger acid: Select the stronger base: Select the stronger base: H -H equally acidic о equally basic NH equally basic оarrow_forwardClassify each of the following as either a substitution, elimination, or addition reaction. CH3 CH3 CH3-CH-CH2-C-CH3 + Br₂ CH3 CH3 CH3 CH3-C-CH2-C-CH3 + HBr substitution ○ elimination Br CH3 CHI CHO CHA HO CH он Cl CH3-CH2-CH-CH2-CH3 CH₂ DBU H* - CHI CHO CH3 + H2O Ӧ CH3 CH3-CH2-CH=CH-CH3 + HCI OH Pd/C CH3 CH3-CH-CH2-C-CH3 CH3 H C-CH2-CH3 + HO-CH3 addition substitution elimination ○ addition ○ substitution ○ elimination O addition substitution O elimination addition substitution O elimination addition CH3 C-CH3 + H2 CH3 CH3-O-CH-CH2-CH3 Онarrow_forward=> (8 pts) Use retrosynthetic analysis (that is, use retrosynthetic arrows as was done in class) to suggest a synthesis route for the transformation shown below. Sear bonsarrow_forward
- d) 1. Complete the following reactions; all reactions are at room temperature. No heat is involved here. Show Major product only. Indicate the type of mechanism: SN1 or SN2. (1 pt each) a) Br + b) Br e) OH CH3DH + H20 он HCJ Zn Cl₂ OH + HCI 20 C12 + H-Brarrow_forwardWhat is the IUPAC name for the compound shown? LOH IUPAC name: BIU X2 x²arrow_forwardDon't used Ai solutionarrow_forward
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- Use the information in the pk, table below to determine which side of the equilibrium is favored for each of the reactions in the second table. acid pk, acid PK CHA CHÍNH, 36 CH₂SH OH 9 50 45 CH2=CH2 19 15.9 CH₂OH 15.7 10.3 .OH 10.0 4.8 он OH CH₂OH₂ -2.2 -7.2 снон, + i + OH + CH4 Equilibrium Equation CH₂OH + io OH CH3NH + CH2=CH2 CH3NH₂ + он + + H₁₂-C CH2=CH 0 O Left Favored Equal Right Favored о 0 0arrow_forwardClassify each of the following as either a substitution, elimination, or addition reaction. Br K* -OC(CH₁) + Cl₂ + HCI + C½₂ + NH3 + HBr + HOT H₂N + HO H HO substitution O elimination addition substitution ○ elimination addition substitution elimination addition O substitution O elimination O addition 000 substitution O elimination additionarrow_forwardPlease correct answer and don't used hand raitingarrow_forward
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