Chemistry: Principles and Practice
3rd Edition
ISBN: 9780534420123
Author: Daniel L. Reger, Scott R. Goode, David W. Ball, Edward Mercer
Publisher: Cengage Learning
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Chapter 5, Problem 5.21QE
Interpretation Introduction
Interpretation:
The fuel that produces more energy per gram of compound while burning has to be predicted and the differences in energy produced per gram of compound has to be calculated.
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Chapter 5 Solutions
Chemistry: Principles and Practice
Ch. 5 - Why must the physical states of all reactants and...Ch. 5 - Why is chemical energy classified as a form of...Ch. 5 - What is the difference between the enthalpy of...Ch. 5 - Classify each process as exothermic or...Ch. 5 - Explain why the specific heat of the contents of...Ch. 5 - Prob. 5.6QECh. 5 - Define heat. What are its units? How does it...Ch. 5 - Prob. 5.8QECh. 5 - Prob. 5.9QECh. 5 - Prob. 5.10QE
Ch. 5 - Prob. 5.11QECh. 5 - Is the Sun exothermic or endothermic? Is it any...Ch. 5 - Under what circumstances is the heat of a process...Ch. 5 - Prob. 5.14QECh. 5 - Prob. 5.15QECh. 5 - Prob. 5.16QECh. 5 - Prob. 5.17QECh. 5 - Prob. 5.18QECh. 5 - Prob. 5.19QECh. 5 - Prob. 5.20QECh. 5 - Prob. 5.21QECh. 5 - Prob. 5.22QECh. 5 - Prob. 5.23QECh. 5 - Prob. 5.24QECh. 5 - Prob. 5.25QECh. 5 - Prob. 5.26QECh. 5 - Prob. 5.27QECh. 5 - Prob. 5.28QECh. 5 - Prob. 5.29QECh. 5 - Prob. 5.30QECh. 5 - Prob. 5.31QECh. 5 - A chemical reaction occurs and absorbs 64.7 cal....Ch. 5 - The enthalpy change for the following reaction is...Ch. 5 - Prob. 5.34QECh. 5 - The thermochemical equation for the burning of...Ch. 5 - When lightning strikes, the energy can force...Ch. 5 - One step in the manufacturing of sulfuric acid is...Ch. 5 - If nitric acid were sufficiently heated, it can be...Ch. 5 - Prob. 5.39QECh. 5 - Prob. 5.40QECh. 5 - Prob. 5.41QECh. 5 - The combustion of 1.00 mol liquid methyl alcohol...Ch. 5 - Another reaction that is used to propel rockets is...Ch. 5 - Prob. 5.44QECh. 5 - Prob. 5.45QECh. 5 - Prob. 5.46QECh. 5 - Prob. 5.47QECh. 5 - Prob. 5.48QECh. 5 - Prob. 5.49QECh. 5 - Prob. 5.50QECh. 5 - The enthalpy change when 1 mol methane (CH4) is...Ch. 5 - Prob. 5.52QECh. 5 - Prob. 5.53QECh. 5 - How much energy is required to raise the...Ch. 5 - How much heat, in kilojoules, must be removed to...Ch. 5 - Prob. 5.56QECh. 5 - Prob. 5.57QECh. 5 - Prob. 5.58QECh. 5 - Prob. 5.59QECh. 5 - Prob. 5.60QECh. 5 - When 7.11 g NH4NO3 is added to 100 mL water, the...Ch. 5 - A 50-mL solution of a dilute AgNO3 solution is...Ch. 5 - A 0.470-g sample of magnesium reacts with 200 g...Ch. 5 - Dissolving 6.00 g CaCl2 in 300 mL of water causes...Ch. 5 - Draw an energy-level diagram (e.g., see Figure...Ch. 5 - Prob. 5.66QECh. 5 - Prob. 5.67QECh. 5 - Prob. 5.68QECh. 5 - Calculate H for the reaction...Ch. 5 - Prob. 5.70QECh. 5 - Given the thermochemical equations...Ch. 5 - In the process of isolating iron from its ores,...Ch. 5 - Prob. 5.73QECh. 5 - Prob. 5.75QECh. 5 - Prob. 5.77QECh. 5 - Prob. 5.78QECh. 5 - Prob. 5.79QECh. 5 - Prob. 5.80QECh. 5 - Prob. 5.81QECh. 5 - Prob. 5.82QECh. 5 - Calculate H when a 38-g sample of glucose,...Ch. 5 - Prob. 5.84QECh. 5 - The octane number of gasoline is based on a...Ch. 5 - One of the components of jet engine fuel is...Ch. 5 - Prob. 5.87QECh. 5 - Prob. 5.88QECh. 5 - When a 2.30-g sample of magnesium dissolves in...Ch. 5 - Prob. 5.90QECh. 5 - Prob. 5.91QECh. 5 - What mass of acetylene, C2H2(g), must be burned to...Ch. 5 - It takes 677 J of heat to increase the temperature...Ch. 5 - Prob. 5.94QECh. 5 - Prob. 5.96QECh. 5 - The enthalpy of combustion of liquid n-hexane,...Ch. 5 - What is Hrxn for reaction of iron(III) oxide and...Ch. 5 - Prob. 5.99QECh. 5 - Prob. 5.100QECh. 5 - In the 1880s, Frederick Trouton noted that the...Ch. 5 - Prob. 5.102QECh. 5 - Prob. 5.103QECh. 5 - Prob. 5.104QECh. 5 - Prob. 5.105QECh. 5 - A compound is 82.7% carbon and 17.3% hydrogen, and...Ch. 5 - Prob. 5.107QECh. 5 - Prob. 5.108QE
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- What mass of acetylene, C2H2(g), must be burned to produce 3420 kJ of heat, given that its enthalpy of combustion is 1301 kJ/mol? Compare this with the answer to Exercise 5.91 and determine which substance produces more heat per gram.arrow_forwardWater gas, a mixture of carbon monoxide and hydrogen, is produced by treating carbon (in the form of coke or coal) with steam at high temperatures. (See Study Question 83.) C(s) + H2O(g) CO(g) + H2(g) Not all of the carbon available is converted to water gas since some is burned to provide the heat for the endothermic reaction of carbon and water. What mass of carbon must be burned (to CO2 gas) to provide the energy to convert 1.00 kg of carbon to water gas?arrow_forwardA 0.470-g sample of magnesium reacts with 200 g dilute HCl in a coffee-cup calorimeter to form MgCl2(aq) and H2(g). The temperature increases by 10.9 C as the magnesium reacts. Assume that the mixture has the same specific heat as water and a mass of 200 g. (a) Calculate the enthalpy change for the reaction. Is the process exothermic or endothermic? (b) Write the chemical equation and evaluate H.arrow_forward
- The combustion of 1.00 mol liquid methyl alcohol (CH3OH) in excess oxygen is exothermic, giving 727 kJ of heat. (a) Write the thermochemical equation for this reaction. (b) Calculate the enthalpy change that accompanies the burning 10.0 g methanol. (c) Compare this with the amount of heat produced by 10.0 g octane, C8H18, a component of gasoline (see Exercise 5.41).arrow_forwardThe equation for the fermentation of glucose to alcohol and carbon dioxide is: C6H12O6(aq) 2C2H5OH(aq) + 2CO2(g) The enthalpy change for the reaction is 67 kJ. Is this reaction exothermic or endothermic? Is energy, in the form of heat, absorbed or evolved as the reaction occurs?arrow_forwardThe standard enthalpy of formation of solid barium oxide, BaO, is 553.5 kJ/mol, and the standard enthalpy of formation of barium peroxide, BaO2, is 634.3 kJ/mol. (a) Calculate the standard enthalpy change for the following reaction. Is the reaction exothermic or endothermic? 2 BaO2(s) 2 BaO(s) + O2(g) (b) Draw an energy level diagram that shows the relationship between the enthalpy change of the decomposition of BaO2, to BaO and O2, and the enthalpies of formation of BaO2(s) and BaO2(s).arrow_forward
- Compounds with carboncarbon double bonds, such as ethylene, C2H4, add hydrogen in a reaction called hydrogenation. C2H4(g)+H2(g)C2H6(g) Calculate the enthalpy change for this reaction, using the following combustion data: C2H4(g)+3O2(g)2CO2(g)+2H2O(l);H=1411kJC2H6(g)+72O2(g)2CO2(g)+3H2O(l);H=1560kJH2(g)+12O2(g)H2O(l);H=286kJarrow_forwardIf a student performs an endothermic reaction in a calorimeter, how does the calculated value of H differ from the actual value if the heat exchanged with the calorimeter is not taken into account?arrow_forwardSalicylic acid, C7H6O3, is one of the starting materials in the manufacture of aspirin. When 1.00 g of salicylic acid burns in a bomb calorimeter, the temperature of the bomb and water goes from 23.11C to 28.91C. The calorimeter and water absorb 21.9 kJ of heat. How much heat is given off when one mole of salicylic acid burns?arrow_forward
- In a bomb calorimeter, the reaction vessel is surrounded by water that must be added for each experiment. Since the amount of water is not constant from experiment to experiment, the mass of water must be measured in each case. The heat capacity of the calorimeter is broken down into two parts: the water and the calorimeter components. If a calorimeter contains 1.00 kg water and has a total heat capacity of 10.84 kJ/C, what is the heat capacity of the calorimeter components?arrow_forwardWhen 2.50 g of methane burns in oxygen, 125 kJ of heat is produced. What is the enthalpy of combustion per mole of methane under these conditions?arrow_forwardWhen lightning strikes, the energy can force atmospheric nitrogen and oxygen to react to make NO: N2(g)+O2(g)2NO(g)H=+181.8kJ (a) Is this reaction endothermic or exothermic? (b) What quantities of reactants and products are assumed if H = +181.8 kJ? (c) What is the enthalpy change when 3.50 g nitrogen is reacted with excess O2(g)?arrow_forward
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