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Chemistry: The Molecular Nature of Matter
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- Gold can be dissolved from gold-bearing rock by treating the rock with sodium cyanide in the presence of oxygen. 4 Au(s) + 8 NaCN(aq) + O2(g) + 2 H2O() 4 NaAu(CN)2(aq) + 4 NaOH(aq) (a) Name the oxidizing and reducing agents in this reaction. What has been oxidized, and what has been reduced? (b) If you have exactly one metric ton (1 metric ton = 1000 kg) of gold-bearing rock, what volume of 0.075 M NaCN, in liters, do you need to extract the gold if the rock is 0.019% gold?arrow_forwardTriiodide ions are generated in solution by the following (unbalanced) reaction in acidic solution: IO3(aq) + I(aq) I3(aq) Triiodide ion concentration is determined by titration with a sodium thiosulfate (Na2S2O3) solution. The products are iodide ion and tetrathionate ion (S4O6). a. Balance the equation for the reaction of IO3 with I ions. b. A sample of 0.6013 g of potassium iodate was dissolved in water. Hydrochloric acid and solid potassium iodide were then added. What is the minimum mass of solid KI and the minimum volume of 3.00 M HQ required to convert all of the IO3 ions to I ions? c. Write and balance the equation for the reaction of S2O32 with I3 in acidic solution. d. A 25.00-mL sample of a 0.0100 M solution of KIO. is reacted with an excess of KI. It requires 32.04 mL of Na2S2O3 solution to titrate the I3 ions present. What is the molarity of the Na2S2O3 solution? e. How would you prepare 500.0 mL of the KIO3 solution in part d using solid KIO3?arrow_forward1. Sometimes a reaction can fall in more than one category. Into what category (or categories) does the reaction of Ba(OH)2(aq) + H+PO4(aq) fit? acid-base and oxidation-reduction oxidation-reduction acid-base and precipitation precipitationarrow_forward
- Write balanced net ionic equations for the following reactions in acid solution. (a) Liquid hydrazine reacts with an aqueous solution of sodium bromate. Nitrogen gas and bromide ions are formed. (b) Solid phosphorus (P4) reacts with an aqueous solution of nitrate to form nitrogen oxide gas and dihydrogen phosphate (H2PO4-) ions. (c) Aqueous solutions of potassium sulfite and potassium permanganate react. Sulfate and manganese(II) ions are formed.arrow_forwardWrite the net ionic equation for the reaction, if any, that occurs on mixing (a) solutions of sodium hydroxide and magnesium chloride. (b) solutions of sodium nitrate and magnesium bromide. (c) magnesium metal and a solution of hydrochloric acid to produce magnesium chloride and hydrogen. Magnesium metal reacting with HCl.arrow_forwardBromine is obtained from sea water by the following redox reaction: Cl2(g) + 2 NaBr(aq) 2 NaCl(aq) + Br2() (a) What has been oxidized? What has been reduced? (b) Identify the oxidizing and reducing agents.arrow_forward
- The mineral dolomite contains magnesium carbon-ate. This reacts with hydrochloric add. MgCO3(s) + 2 HCl(aq) CO2(g) + MgCl2(aq) + H2O() (a) Write the net ionic equation for this reaction and identify the spectator ions. (b) What type of reaction is this?arrow_forwardXenon trioxide, XeO3, reacts with aqueous base to form the xenate anion, HXeO4. This ion reacts further with OH to form the perxenate anion, XeO64, in the following reaction: 2HXeO4(aq)+2OH(aq)XeO64(aq)+Xe(g)+O2(g)+2H2O(l) Identify the elements that are oxidized and reduced in this reaction. You will note that the equation is balanced with respect to the number of atoms on either side. Verify that the redox part of this equation is also balanced, that is, that the extents of oxidation and reduction are also equal.arrow_forwardThe Toliens test for the presence of reducing sugars (say, in a urine sample) involves treating the sample with silver ions in aqueous ammonia. The result is the formation of a silver mirror within the reaction vessel if a reducing sugar is present. Using glucose, C6H12O6, to illustrate this test, the oxidation-reduction reaction occurring is C6H12O6 (aq) + 2 Ag+(aq) + 2OH(aq) C6H12O7(aq) + 2 Ag(s) + H2O() What has been oxidized, and what has been reduced? What is the oxidizing agent, and what is the reducing agent? Tolien's test. The reaction of silver ions with a sugar such as glucose produces metallic silver. (a) The set-up for the reaction. (b) The silvered test tubearrow_forward
- Chlorine gas was first prepared in 1774 by C. W. Scheele by oxidizing sodium chloride with manganese(IV) oxide. The reaction is NaCl(aq) + H2SO4(aq) + MnO2(s) Na2SO4(aq) + MnCl2(aq) + H2O(l) + Cl2 (g) Balance this equation.arrow_forwardWhich two of the following reactions are oxidation-reduction reactions? Explain your answer briefly. Classify the remaining reaction. (a) CdC12(aq) + Na2S(aq) CdS(s) + 2 NaCl(aq) (b) 2 Ca(s) + O2(g) 2 CaO(s) (c) 4 Fe(OH)2(s) + 2 H2O() + O2(g) 4 Fe(OH)3(s)arrow_forwardBalance each of the following equations, and classify them as precipitation, acid-base, gas-forming, or oxidation-reduction reactions. Show states for reactants and products (s, , g, aq). (a) CuCl2 + H2S CuS + HCl (b) H3PO4 + KOH H2O + K3PO4 (c) Ca +HBr H2 + CaBr2 (d) MgC12 + NaOH Mg(OH)2 + NaClarrow_forward
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