
Chemistry: The Molecular Nature of Matter
7th Edition
ISBN: 9781118516461
Author: Neil D. Jespersen, Alison Hyslop
Publisher: WILEY
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Question
Chapter 5, Problem 14PE
Interpretation Introduction
Interpretation:
The chemical equations for the given reactions are to be written.
Concept Introduction:
A
A reaction that contains the same number of atoms on the product and reactant sides is known as a balanced chemical equation.
If, in any equation, there is an unequal number of atoms on each side of the arrow, the equation is said to be unbalanced.
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2. Predict the NMR spectra for each of these two
compounds by listing, in the NMR tables below, the
chemical shift, the splitting, and the number of
hydrogens associated with each predicted peak. Sort the
peaks from largest chemical shift to lowest.
**Not all slots must be filled**
Peak
Chemical Shift (d)
5.7
1
Multiplicity
multiplate
..........
5.04
double of doublet
2
4.98
double of doublet
3
4.05
doublet of quartet
4
5
LO
3.80
quartet
1.3
doublet
6
Peak
Chemical Shift (d)
Multiplicity
Interpreting NMR spectra is a skill that often requires some
amount of practice, which, in turn, necessitates access to a
collection of NMR spectra. Beyond Labz Organic Synthesis and
Organic Qualitative Analysis have spectral libraries containing
over 700 1H NMR spectra. In this assignment, you will take
advantage of this by first predicting the NMR spectra for two
closely related compounds and then checking your predictions
by looking up the actual spectra in the spectra library. After
completing this assignment, you may wish to select other
compounds for additional practice.
1. Write the IUPAC names for the following two structures:
Question 2
Question 3
2. Predict the NMR spectra for each of these two
compounds by listing, in the NMR tables below, the
chemical shift, the splitting, and the number of
hydrogens associated with each predicted peak. Sort the
peaks from largest chemical shift to lowest.
**Not all slots must be filled**
11:14
...
worksheets.beyondlabz.com
3. To check your predictions, click this link for Interpreting
NMR Spectra 1. You will see a list of all the
-
compounds in the spectra library in alphabetical order by
IUPAC name. Hovering over a name in the list will show
the structure on the chalkboard. The four buttons on the
top of the Spectra tab in the tray are used to select the
different spectroscopic techniques for the selected
compound. Make sure the NMR button has been selected.
4. Scroll through the list of names to find the names for the
two compounds you have been given and click on the
name to display the NMR spectrum for each. In the NMR
tables below, list the chemical shift, the splitting, and
the number of hydrogens associated with each peak for
each compound. Compare your answers to your
predictions.
**Not all slots must be filled**
Peak
Chemical Shift (d)
Multiplicity
1
2
3
4
5
Chapter 5 Solutions
Chemistry: The Molecular Nature of Matter
Ch. 5 - When sodium reacts with molecular oxygen, O2, the...Ch. 5 - Prob. 2PECh. 5 - The chlorite ion, ClO2, is a potent disinfectant,...Ch. 5 - Assign oxidation numbers to each atom in...Ch. 5 - Prob. 5PECh. 5 - Chlorine dioxide, ClO2, is used to kill bacteria...Ch. 5 - The following equation is nor balanced. Explain...Ch. 5 - Practice Exercise 5.8
The element technetium...Ch. 5 - Practice Exercise 5.9
Consider the following...Ch. 5 - Balance the following equation for a basic...
Ch. 5 - Write the balanced half-react ions for the...Ch. 5 - Prob. 12PECh. 5 - Suppose an aqueous mixture is prepared containing...Ch. 5 - Prob. 14PECh. 5 - Prob. 15PECh. 5 - Write a balanced equation for the combustion of...Ch. 5 - Prob. 17PECh. 5 - Prob. 18PECh. 5 - Prob. 1RQCh. 5 - Prob. 2RQCh. 5 - Prob. 3RQCh. 5 - Are the following redox reactions? Explain....Ch. 5 - If the oxidation number of nitrogen in a certain...Ch. 5 - When balancing redox reactions, which side of a...Ch. 5 - Prob. 7RQCh. 5 - What are the net charges on the left and right...Ch. 5 - In Question 5.8, which half-reaction represents...Ch. 5 - The following equation is not balanced....Ch. 5 - 5.11 What is a nonoxidizing acid? Give two...Ch. 5 - What is the strongest oxidizing agent in an...Ch. 5 - Prob. 13RQCh. 5 - Prob. 14RQCh. 5 - What is a single replacement reaction?Ch. 5 - If a metal is able to react with a solution of...Ch. 5 - Prob. 17RQCh. 5 - Prob. 18RQCh. 5 - Where in the activity series do we find the best...Ch. 5 - When manganese reacts with silver ions, is...Ch. 5 - Prob. 21RQCh. 5 - Prob. 22RQCh. 5 - Prob. 23RQCh. 5 - If one of the impurities in diesel fuel has the...Ch. 5 - Prob. 25RQCh. 5 - Prob. 26RQCh. 5 - Prob. 27RQCh. 5 - Potassium permanganate is often used for redox...Ch. 5 - Assign oxidation numbers to the atoms in the...Ch. 5 - 5.30 Assign oxidation numbers to the atoms in the...Ch. 5 - Assign oxidation numbers to each atom in the...Ch. 5 - Assign oxidation numbers to the elements...Ch. 5 - 5.33 Assign oxidation numbers to the elements in...Ch. 5 - 5.34 Assign oxidation numbers to the elements in...Ch. 5 - Titanium burns in pure nitrogen to form TiN. What...Ch. 5 - 5.36 Zirconia, which is , is used to make ceramic...Ch. 5 - 5.37 Ozone, , is an allotrope of oxygen and is one...Ch. 5 - 5.38 The other major air pollutant is . What are...Ch. 5 - For the following reactions, identify the...Ch. 5 - 5.40 For the following reactions, identify the...Ch. 5 - When chlorine is added to drinking water to kill...Ch. 5 - One pollutant in smog is nitrogen dioxide. NO2....Ch. 5 - Balance the following equations for reactions...Ch. 5 - 5.44 Balance the following equations for reactions...Ch. 5 - Prob. 45RQCh. 5 - 5.46 Balance the following equations for reactions...Ch. 5 - 5.47 Balance the equations for the following...Ch. 5 - Balance the equations for the following reactions...Ch. 5 - Prob. 49RQCh. 5 - 5.50 Hydroiodic acid reduces chlorine to...Ch. 5 - Prob. 51RQCh. 5 - Corn is grown for human consumption, feeding...Ch. 5 - Prob. 53RQCh. 5 - Laundry bleach such as Clorox is a dilute solution...Ch. 5 - Prob. 55RQCh. 5 - Chlorine is a good bleaching agent because it is...Ch. 5 - Write balanced molecular, ionic, and net ionic...Ch. 5 - 5.58 Write balanced molecular, ionic, and net...Ch. 5 - Prob. 59RQCh. 5 - Prob. 60RQCh. 5 - Prob. 61RQCh. 5 - Prob. 62RQCh. 5 - Prob. 63RQCh. 5 - Hot, concentrated sulfuric acid is a fairly strong...Ch. 5 - Use Table 5.3 to predict the outcome of the...Ch. 5 - 5.66 Use Table 5.3 to predict the outcome of the...Ch. 5 - The following reactions occur spontaneously....Ch. 5 - The following reactions occur spontaneously....Ch. 5 - Prob. 69RQCh. 5 - When chromium metal is dipped into a solution of...Ch. 5 - Write a balanced equation for the reaction...Ch. 5 - Write a balanced equation for the reaction...Ch. 5 - Write the balanced chemical equation for the...Ch. 5 - Write the balanced chemical equation for the...Ch. 5 - 5.75 Write balanced chemical equations for the...Ch. 5 - Write balanced chemical equations for the complete...Ch. 5 - 5.77 Write balanced equations for the combustion...Ch. 5 - 5.78 Write balanced equations for the combustion...Ch. 5 - 5.79 The metabolism of carbohydrates such as...Ch. 5 - Methanol, CH3OH, has been suggested as an...Ch. 5 - Write the balanced equation for the combustion of...Ch. 5 - 5.82 Thiophene, , is an impurity in crude oil and...Ch. 5 - Write chemical equations for the reaction of...Ch. 5 - Prob. 84RQCh. 5 - Prob. 85RQCh. 5 - Prob. 86RQCh. 5 - In an acidic solution, permanganate ion reacts...Ch. 5 - 5.88 In an acidic solution, bisulfite ion reacts...Ch. 5 - Prob. 89RQCh. 5 - Potable water (drinking water) should not have...Ch. 5 - 5.91 Sulfites are used worldwide in the wine...Ch. 5 - Methylbromide, CH3Br, is used in agriculture to...Ch. 5 - A sample of a copper ore with a mass of 0.4225 g...Ch. 5 - 5.94 A 1.362 g sample of an iron ore that...Ch. 5 - 5.95 Hydrogen peroxide, , solution can be...Ch. 5 - 5.96 Sodium nitrite, , is used as a preservative...Ch. 5 - Prob. 97RQCh. 5 - Prob. 98RQCh. 5 - Both calcium chloride and sodium chloride are used...Ch. 5 - 5.100 One way to analyze a sample for nitrite ion...Ch. 5 - Use oxidation numbers to show that the...Ch. 5 - Prob. 102RQCh. 5 - Prob. 103RQCh. 5 - Prob. 104RQCh. 5 - Balance the following equations using the...Ch. 5 - Prob. 106RQCh. 5 - What is the average oxidation number of carbon in...Ch. 5 - Prob. 108RQCh. 5 - In Problem 5-108, were all of the experiments...Ch. 5 - Prob. 110RQCh. 5 - 5.111 In each of the following pairs, choose the...Ch. 5 - Use Table 5.3 to predict whether the following...Ch. 5 - Sucrose, C12H22O11, is ordinary table sugar. Write...Ch. 5 - Balance the following equations by the...Ch. 5 - 5.115 Lead(IV) oxide reacts with hydrochloric acid...Ch. 5 - Prob. 116RQCh. 5 - A copper bar with a mass of 12.340 g is dipped...Ch. 5 - Prob. 118RQCh. 5 - 5.119 As described in the Chemistry Outside the...Ch. 5 - Titanium(IV) can be reduced to titanium(III) by...Ch. 5 - A researcher planned to use chlorine gas in an...Ch. 5 - 5.122 A sample of a tin ore weighing 0.3000 g was...Ch. 5 - Biodiesel is formed from the reaction of oils with...Ch. 5 - *5.124 In June 2002, the Department of Health and...Ch. 5 - An organic compound contains carbon, hydrogen, and...Ch. 5 - *5.126 A mixture is made by combining with ....Ch. 5 - A solution containing 0.1244 g of K2C2O4 was...Ch. 5 - It was found that a 20.0 mL portion of a solution...Ch. 5 - A 15.00 mL sample of a solution containing oxalic...Ch. 5 - A solution with a volume of 500.0 mL contained a...Ch. 5 - Prob. 131RQCh. 5 - We described the ion-electron method for balancing...Ch. 5 - Assuming that a chemical reaction with DNA could...Ch. 5 - Would you expect atomic oxygen and chlorine to be...Ch. 5 - Prob. 135RQCh. 5 - Prob. 136RQ
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