EBK FOUNDATIONS OF COLLEGE CHEMISTRY
15th Edition
ISBN: 9781118930144
Author: Willard
Publisher: JOHN WILEY+SONS INC.
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Chapter 5, Problem 11PE
Interpretation Introduction
Interpretation:
The special names that are given to the isotopes of hydrogen have to be given.
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Students have asked these similar questions
Q1: Answer the questions for the reaction below:
..!! Br
OH
a) Predict the product(s) of the reaction.
b) Is the substrate optically active? Are the product(s) optically active as a mix?
c) Draw the curved arrow mechanism for the reaction.
d) What happens to the SN1 reaction rate in each of these instances:
1. Change the substrate to
Br
"CI
2. Change the substrate to
3. Change the solvent from 100% CH3CH2OH to 10% CH3CH2OH + 90% DMF
4. Increase the substrate concentration by 3-fold.
Experiment 27 hates & Mechanisms of Reations
Method I visual Clock Reaction
A. Concentration effects on reaction Rates
Iodine
Run [I] mol/L [S₂082] | Time
mo/L
(SCC)
0.04 54.7
Log
1/ Time Temp Log [ ] 13,20] (time)
/ [I] 199
20.06
23.0
30.04 0.04
0.04 80.0
22.8
45
40.02
0.04 79.0
21.6
50.08
0.03 51.0
22.4
60-080-02 95.0
23.4
7 0.08
0-01 1970
23.4
8 0.08 0.04 16.1
22.6
(15 pts) Consider the molecule B2H6. Generate a molecular orbital diagram but this
time using a different approach that draws on your knowledge and ability to put
concepts together. First use VSEPR or some other method to make sure you know
the ground state structure of the molecule. Next, generate an MO diagram for BH2.
Sketch the highest occupied and lowest unoccupied MOs of the BH2 fragment.
These are called frontier orbitals. Now use these frontier orbitals as your basis set
for producing LGO's for B2H6. Since the BH2 frontier orbitals become the LGOS,
you will have to think about what is in the middle of the molecule and treat its basis
as well. Do you arrive at the same qualitative MO diagram as is discussed in the
book? Sketch the new highest occupied and lowest unoccupied MOs for the
molecule (B2H6).
Chapter 5 Solutions
EBK FOUNDATIONS OF COLLEGE CHEMISTRY
Ch. 5.1 - Prob. 5.1PCh. 5.2 - Prob. 5.2PCh. 5.3 - Prob. 5.3PCh. 5.4 - Prob. 5.4PCh. 5.5 - Prob. 5.5PCh. 5.5 - Prob. 5.6PCh. 5.6 - Prob. 5.7PCh. 5 - Prob. 1RQCh. 5 - Prob. 2RQCh. 5 - Prob. 3RQ
Ch. 5 - Prob. 4RQCh. 5 - Prob. 5RQCh. 5 - Prob. 6RQCh. 5 - Prob. 7RQCh. 5 - Prob. 8RQCh. 5 - Prob. 9RQCh. 5 - Prob. 10RQCh. 5 - Prob. 11RQCh. 5 - Prob. 12RQCh. 5 - Prob. 1PECh. 5 - Prob. 2PECh. 5 - Prob. 3PECh. 5 - Prob. 4PECh. 5 - Prob. 5PECh. 5 - Prob. 6PECh. 5 - Prob. 7PECh. 5 - Prob. 8PECh. 5 - Prob. 9PECh. 5 - Prob. 10PECh. 5 - Prob. 11PECh. 5 - Prob. 12PECh. 5 - Prob. 13PECh. 5 - Prob. 14PECh. 5 - Prob. 15PECh. 5 - Prob. 16PECh. 5 - Prob. 17PECh. 5 - Prob. 18PECh. 5 - Prob. 19PECh. 5 - Prob. 20PECh. 5 - Prob. 21PECh. 5 - Prob. 22PECh. 5 - Prob. 23PECh. 5 - Prob. 24PECh. 5 - Prob. 25PECh. 5 - Prob. 26PECh. 5 - Prob. 27PECh. 5 - Prob. 28PECh. 5 - Prob. 29PECh. 5 - Prob. 30PECh. 5 - Prob. 31PECh. 5 - Prob. 32PECh. 5 - Prob. 33PECh. 5 - Prob. 34PECh. 5 - Prob. 35AECh. 5 - Prob. 36AECh. 5 - Prob. 37AECh. 5 - Prob. 38AECh. 5 - Prob. 39AECh. 5 - Prob. 42AECh. 5 - Prob. 43AECh. 5 - Prob. 45AECh. 5 - Prob. 46AECh. 5 - Prob. 47AECh. 5 - Prob. 48AECh. 5 - Prob. 49AECh. 5 - Prob. 50AECh. 5 - Prob. 51AECh. 5 - Prob. 53AECh. 5 - Prob. 54AECh. 5 - Prob. 55AECh. 5 - Prob. 56AECh. 5 - Prob. 60CE
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