Chemistry
10th Edition
ISBN: 9781305957404
Author: Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher: Cengage Learning
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Question
Chapter 5, Problem 111E
Interpretation Introduction
Interpretation: The root mean square velocities of
Concept introduction:
The root mean square velocity
Root mean square velocity can be determined,
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Part II. Given two isomers: 2-methylpentane (A) and 2,2-dimethyl butane (B) answer the following:
(a) match structures of isomers given their mass spectra below (spectra A and spectra B)
(b) Draw the fragments given the following prominent peaks from
each spectrum:
Spectra A m/2 =43 and 1/2-57
spectra B m/2 = 43
(c) why is 1/2=57 peak in spectrum A more intense compared
to the same peak in spectrum B.
Relative abundance
Relative abundance
100
A
50
29
29
0
10
-0
-0
100
B
50
720
30
41
43
57
71
4-0
40
50
60 70
m/z
43
57
8-0
m/z = 86
M
90 100
71
m/z = 86
M
-O
0
10 20 30
40 50
60
70
80
-88
m/z
90
100
Part IV. C6H5 CH2CH2OH is an aromatic compound which was subjected to Electron Ionization - mass
spectrometry (El-MS) analysis. Prominent m/2 values: m/2 = 104 and m/2 = 9) was obtained.
Draw the structures of these fragments.
For each reaction shown below follow the curved arrows to complete each equationby showing the structure of the products. Identify the acid, the base, the conjugated acid andconjugated base. Consutl the pKa table and choose the direciton theequilibrium goes. However show the curved arrows. Please explain if possible.
Chapter 5 Solutions
Chemistry
Ch. 5 - Prob. 1RQCh. 5 - Prob. 2RQCh. 5 - Prob. 3RQCh. 5 - Prob. 4RQCh. 5 - Prob. 5RQCh. 5 - Prob. 6RQCh. 5 - Prob. 7RQCh. 5 - Prob. 8RQCh. 5 - Prob. 9RQCh. 5 - Why do real gases not always behave ideally? Under...
Ch. 5 - Prob. 3ALQCh. 5 - Prob. 4ALQCh. 5 - Prob. 6ALQCh. 5 - Prob. 8ALQCh. 5 - Prob. 11ALQCh. 5 - Prob. 12ALQCh. 5 - Prob. 13ALQCh. 5 - Prob. 14ALQCh. 5 - Prob. 17ALQCh. 5 - Prob. 18ALQCh. 5 - Draw molecular-level views that show the...Ch. 5 - Prob. 22QCh. 5 - Prob. 23QCh. 5 - Prob. 24QCh. 5 - Prob. 25QCh. 5 - As weather balloons rise from the earths surface,...Ch. 5 - Prob. 27QCh. 5 - Consider two different containers, each filled...Ch. 5 - Prob. 29QCh. 5 - Prob. 32QCh. 5 - Prob. 33QCh. 5 - Prob. 34QCh. 5 - Prob. 35QCh. 5 - Prob. 36QCh. 5 - Prob. 37QCh. 5 - Without looking at a table of values, which of the...Ch. 5 - Prob. 39QCh. 5 - Prob. 40QCh. 5 - Prob. 41ECh. 5 - Prob. 42ECh. 5 - A sealed-tube manometer (as shown below) can be...Ch. 5 - Prob. 44ECh. 5 - A diagram for an open-tube manometer is shown...Ch. 5 - Prob. 46ECh. 5 - Prob. 47ECh. 5 - Prob. 48ECh. 5 - An 11.2-L sample of gas is determined to contain...Ch. 5 - Prob. 50ECh. 5 - Prob. 51ECh. 5 - Prob. 52ECh. 5 - Prob. 53ECh. 5 - Prob. 54ECh. 5 - The Steel reaction vessel of a bomb calorimeter,...Ch. 5 - A 5.0-L flask contains 0.60 g O2 at a temperature...Ch. 5 - Prob. 57ECh. 5 - A person accidentally swallows a drop of liquid...Ch. 5 - Prob. 59ECh. 5 - N2O is a gas commonly used to help sedate patients...Ch. 5 - A gas sample containing 1.50 moles at 25C exerts a...Ch. 5 - Prob. 62ECh. 5 - Prob. 63ECh. 5 - What will be the effect on the volume of an ideal...Ch. 5 - Prob. 65ECh. 5 - Prob. 66ECh. 5 - An ideal gas is contained in a cylinder with a...Ch. 5 - Prob. 68ECh. 5 - A sealed balloon is filled with 1.00 L helium at...Ch. 5 - Prob. 70ECh. 5 - Consider the following reaction:...Ch. 5 - A student adds 4.00 g of dry ice (solid CO2) to an...Ch. 5 - Air bags are activated when a severe impact causes...Ch. 5 - Concentrated hydrogen peroxide solutions are...Ch. 5 - In 1897 the Swedish explorer Andre tried to reach...Ch. 5 - Sulfur trioxide, SO3, is produced in enormous...Ch. 5 - A 15.0-L rigid container was charged with 0.500...Ch. 5 - An important process for the production of...Ch. 5 - Consider the reaction between 50.0 mL liquid...Ch. 5 - Urea (H2NCONH2) is used extensively as a nitrogen...Ch. 5 - Prob. 81ECh. 5 - Prob. 82ECh. 5 - Prob. 83ECh. 5 - A compound has the empirical formula CHCl. A...Ch. 5 - Prob. 85ECh. 5 - Silicon tetrachloride (SiCl4) and trichlorosilane...Ch. 5 - Prob. 87ECh. 5 - Prob. 88ECh. 5 - For scuba dives below 150 ft, helium is often used...Ch. 5 - Prob. 90ECh. 5 - Consider the flasks in the following diagram. What...Ch. 5 - Consider the flask apparatus in Exercise 85, which...Ch. 5 - Prob. 93ECh. 5 - At 0C a 1.0-L flask contains 5.0 102 mole of N2,...Ch. 5 - A mixture of cyclopropane and oxygen is sometimes...Ch. 5 - Prob. 96ECh. 5 - Prob. 97ECh. 5 - A tank contains a mixture of 52.5 g oxygen gas and...Ch. 5 - Prob. 99ECh. 5 - Helium is collected over water at 25C and 1.00 atm...Ch. 5 - At elevated temperatures, sodium chlorate...Ch. 5 - Xenon and fluorine will react to form binary...Ch. 5 - Methanol (CH3OH) can be produced by the following...Ch. 5 - In the Mthode Champenoise, grape juice is...Ch. 5 - Hydrogen azide, HN3, decomposes on heating by the...Ch. 5 - Prob. 106ECh. 5 - Prob. 107ECh. 5 - The oxides of Group 2A metals (symbolized by M...Ch. 5 - Prob. 109ECh. 5 - Prob. 110ECh. 5 - Prob. 111ECh. 5 - Prob. 112ECh. 5 - Prob. 113ECh. 5 - Prob. 114ECh. 5 - Prob. 115ECh. 5 - Prob. 116ECh. 5 - Prob. 117ECh. 5 - Prob. 118ECh. 5 - Prob. 119ECh. 5 - Prob. 120ECh. 5 - Prob. 121ECh. 5 - Prob. 122ECh. 5 - Prob. 123ECh. 5 - Prob. 124ECh. 5 - Use the data in Table 84 to calculate the partial...Ch. 5 - Prob. 126ECh. 5 - Prob. 127ECh. 5 - Prob. 128ECh. 5 - Prob. 129ECh. 5 - Prob. 130ECh. 5 - Prob. 131AECh. 5 - At STP, 1.0 L Br2 reacts completely with 3.0 L F2,...Ch. 5 - Prob. 133AECh. 5 - Prob. 134AECh. 5 - Prob. 135AECh. 5 - Cyclopropane, a gas that when mixed with oxygen is...Ch. 5 - The nitrogen content of organic compounds can be...Ch. 5 - Hyperbaric oxygen therapy is used to treat...Ch. 5 - A 15.0L tank is filled with H2 to a pressure of...Ch. 5 - A spherical glass container of unknown volume...Ch. 5 - Prob. 141AECh. 5 - A 20.0L stainless steel container at 25C was...Ch. 5 - Metallic molybdenum can be produced from the...Ch. 5 - Prob. 144AECh. 5 - Prob. 145AECh. 5 - One of the chemical controversies of the...Ch. 5 - An organic compound contains C, H, N, and O....Ch. 5 - Prob. 148AECh. 5 - Prob. 149CWPCh. 5 - Prob. 150CWPCh. 5 - A certain flexible weather balloon contains helium...Ch. 5 - A large flask with a volume of 936 mL is evacuated...Ch. 5 - A 20.0L nickel container was charged with 0.859...Ch. 5 - Consider the unbalanced chemical equation below:...Ch. 5 - Prob. 155CWPCh. 5 - Which of the following statements is(are) true? a....Ch. 5 - A chemist weighed out 5.14 g of a mixture...Ch. 5 - A mixture of chromium and zinc weighing 0.362 g...Ch. 5 - Prob. 159CPCh. 5 - You have an equimolar mixture of the gases SO2 and...Ch. 5 - Methane (CH4) gas flows into a combustion chamber...Ch. 5 - Prob. 162CPCh. 5 - Prob. 163CPCh. 5 - Prob. 164CPCh. 5 - You have a helium balloon at 1.00 atm and 25C. You...Ch. 5 - We state that the ideal gas law tends to hold best...Ch. 5 - You are given an unknown gaseous binary compound...Ch. 5 - Prob. 168CPCh. 5 - Prob. 170IPCh. 5 - In the presence of nitric acid, UO2+ undergoes a...Ch. 5 - Silane, SiH4, is the silicon analogue of methane,...Ch. 5 - Prob. 173IPCh. 5 - Prob. 174IPCh. 5 - Prob. 175MP
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