The highest and lowest energy conformations of giving compound should be drawn. Concept Introduction: Newman projection: The conformational isomers are representing by the Newman projection drawing . Newman projection representing by front carbon atom connected to 3 groups then the 3 groups connected circle is a back carbon atom. The dark wedge is represent the out of the plain then the light wedge is represent the inside the plain. In the Newman projection, the atoms or groups are attached to the center carbon by angle of 60° and this is called as a dihedral angle. The dihedral angle is varying by the rotation of C-C bond, result of this there are two conformations are obtained and this are staggered and eclipsed conformations obtained. The highest energy conformation is eclipsed and lowest energy conformation is staggered. Interaction between the groups present in the front and back carbon atoms are increases the energy of a compound all so increases.

Question

Predict the product formed when the compound shown below undergoes a reaction with MCPBA in CH2Cl2. MCPBA is meta-chloroperoxybenzoic acid.

Answer 1

Question

Chapter 4.8, Problem 19PTS

(a)

Interpretation Introduction

Interpretation:

The highest and lowest energy conformations of giving compound should be drawn.

Concept Introduction:

Newman projection:

The conformational isomers are representing by the Newman projection drawing.

Newman projection representing by front carbon atom connected to 3 groups then the 3 groups connected circle is a back carbon atom.

The dark wedge is represent the out of the plain then the light wedge is represent the inside the plain.

In the Newman projection, the atoms or groups are attached to the center carbon by angle of 60° and this is called as a dihedral angle.

The dihedral angle is varying by the rotation of C-C bond, result of this there are two conformations are obtained and this are staggered and eclipsed conformations obtained.

The highest energy conformation is eclipsed and lowest energy conformation is staggered.

Interaction between the groups present in the front and back carbon atoms are increases the energy of a compound all so increases.

(b)

Interpretation Introduction

Interpretation:

The highest and lowest energy conformations of giving compound should be drawn.

Concept Introduction:

Newman projection:

The conformational isomers are representing by the Newman projection drawing.

Newman projection representing by front carbon atom connected to 3 groups then the 3 groups connected circle is a back carbon atom.

The dark wedge is represent the out of the plain then the light wedge is represent the inside the plain.

In the Newman projection, the atoms or groups are attached to the center carbon by angle of 60° and this is called as a dihedral angle.

The dihedral angle is varying by the rotation of C-C bond, result of this there are two conformations are obtained and this are staggered and eclipsed conformations obtained.

The highest energy conformation is eclipsed and lowest energy conformation is staggered.

Interaction between the groups present in the front and back carbon atoms are increases the energy of a compound all so increases.

(c)

Interpretation Introduction

Interpretation:

The highest and lowest energy conformations of giving compound should be drawn.

Concept Introduction:

Newman projection:

The conformational isomers are representing by the Newman projection drawing.

Newman projection representing by front carbon atom connected to 3 groups then the 3 groups connected circle is a back carbon atom.

The dark wedge is represent the out of the plain then the light wedge is represent the inside the plain.

In the Newman projection, the atoms or groups are attached to the center carbon by angle of 60° and this is called as a dihedral angle.

The dihedral angle is varying by the rotation of C-C bond, result of this there are two conformations are obtained and this are staggered and eclipsed conformations obtained.

The highest energy conformation is eclipsed and lowest energy conformation is staggered.

Interaction between the groups present in the front and back carbon atoms are increases the energy of a compound all so increases.

(d)

Interpretation Introduction

Interpretation:

The highest and lowest energy conformations of giving compound should be drawn.

Concept Introduction:

Newman projection:

The conformational isomers are representing by the Newman projection drawing.

Newman projection representing by front carbon atom connected to 3 groups then the 3 groups connected circle is a back carbon atom.

The dark wedge is represent the out of the plain then the light wedge is represent the inside the plain.

In the Newman projection, the atoms or groups are attached to the center carbon by angle of 60° and this is called as a dihedral angle.

The dihedral angle is varying by the rotation of C-C bond, result of this there are two conformations are obtained and this are staggered and eclipsed conformations obtained.

The highest energy conformation is eclipsed and lowest energy conformation is staggered.

Interaction between the groups present in the front and back carbon atoms are increases the energy of a compound all so increases.

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Predict the product formed when the compound shown below undergoes a reaction with MCPBA in CH2Cl2. MCPBA is meta-chloroperoxybenzoic acid.

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Answer 2

Question

Chapter 4.8, Problem 19PTS

(a)

Interpretation Introduction

Interpretation:

The highest and lowest energy conformations of giving compound should be drawn.

Concept Introduction:

Newman projection:

The conformational isomers are representing by the Newman projection drawing.

Newman projection representing by front carbon atom connected to 3 groups then the 3 groups connected circle is a back carbon atom.

The dark wedge is represent the out of the plain then the light wedge is represent the inside the plain.

In the Newman projection, the atoms or groups are attached to the center carbon by angle of 60° and this is called as a dihedral angle.

The dihedral angle is varying by the rotation of C-C bond, result of this there are two conformations are obtained and this are staggered and eclipsed conformations obtained.

The highest energy conformation is eclipsed and lowest energy conformation is staggered.

Interaction between the groups present in the front and back carbon atoms are increases the energy of a compound all so increases.

(b)

Interpretation Introduction

Interpretation:

The highest and lowest energy conformations of giving compound should be drawn.

Concept Introduction:

Newman projection:

The conformational isomers are representing by the Newman projection drawing.

Newman projection representing by front carbon atom connected to 3 groups then the 3 groups connected circle is a back carbon atom.

The dark wedge is represent the out of the plain then the light wedge is represent the inside the plain.

In the Newman projection, the atoms or groups are attached to the center carbon by angle of 60° and this is called as a dihedral angle.

The dihedral angle is varying by the rotation of C-C bond, result of this there are two conformations are obtained and this are staggered and eclipsed conformations obtained.

The highest energy conformation is eclipsed and lowest energy conformation is staggered.

Interaction between the groups present in the front and back carbon atoms are increases the energy of a compound all so increases.

(c)

Interpretation Introduction

Interpretation:

The highest and lowest energy conformations of giving compound should be drawn.

Concept Introduction:

Newman projection:

The conformational isomers are representing by the Newman projection drawing.

Newman projection representing by front carbon atom connected to 3 groups then the 3 groups connected circle is a back carbon atom.

The dark wedge is represent the out of the plain then the light wedge is represent the inside the plain.

In the Newman projection, the atoms or groups are attached to the center carbon by angle of 60° and this is called as a dihedral angle.

The dihedral angle is varying by the rotation of C-C bond, result of this there are two conformations are obtained and this are staggered and eclipsed conformations obtained.

The highest energy conformation is eclipsed and lowest energy conformation is staggered.

Interaction between the groups present in the front and back carbon atoms are increases the energy of a compound all so increases.

(d)

Interpretation Introduction

Interpretation:

The highest and lowest energy conformations of giving compound should be drawn.

Concept Introduction:

Newman projection:

The conformational isomers are representing by the Newman projection drawing.

Newman projection representing by front carbon atom connected to 3 groups then the 3 groups connected circle is a back carbon atom.

The dark wedge is represent the out of the plain then the light wedge is represent the inside the plain.

In the Newman projection, the atoms or groups are attached to the center carbon by angle of 60° and this is called as a dihedral angle.

The dihedral angle is varying by the rotation of C-C bond, result of this there are two conformations are obtained and this are staggered and eclipsed conformations obtained.

The highest energy conformation is eclipsed and lowest energy conformation is staggered.

Interaction between the groups present in the front and back carbon atoms are increases the energy of a compound all so increases.

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Answer 3

Question

Chapter 4.8, Problem 19PTS

(a)

Interpretation Introduction

Interpretation:

The highest and lowest energy conformations of giving compound should be drawn.

Concept Introduction:

Newman projection:

The conformational isomers are representing by the Newman projection drawing.

Newman projection representing by front carbon atom connected to 3 groups then the 3 groups connected circle is a back carbon atom.

The dark wedge is represent the out of the plain then the light wedge is represent the inside the plain.

In the Newman projection, the atoms or groups are attached to the center carbon by angle of 60° and this is called as a dihedral angle.

The dihedral angle is varying by the rotation of C-C bond, result of this there are two conformations are obtained and this are staggered and eclipsed conformations obtained.

The highest energy conformation is eclipsed and lowest energy conformation is staggered.

Interaction between the groups present in the front and back carbon atoms are increases the energy of a compound all so increases.

(b)

Interpretation Introduction

Interpretation:

The highest and lowest energy conformations of giving compound should be drawn.

Concept Introduction:

Newman projection:

The conformational isomers are representing by the Newman projection drawing.

Newman projection representing by front carbon atom connected to 3 groups then the 3 groups connected circle is a back carbon atom.

The dark wedge is represent the out of the plain then the light wedge is represent the inside the plain.

In the Newman projection, the atoms or groups are attached to the center carbon by angle of 60° and this is called as a dihedral angle.

The dihedral angle is varying by the rotation of C-C bond, result of this there are two conformations are obtained and this are staggered and eclipsed conformations obtained.

The highest energy conformation is eclipsed and lowest energy conformation is staggered.

Interaction between the groups present in the front and back carbon atoms are increases the energy of a compound all so increases.

(c)

Interpretation Introduction

Interpretation:

The highest and lowest energy conformations of giving compound should be drawn.

Concept Introduction:

Newman projection:

The conformational isomers are representing by the Newman projection drawing.

Newman projection representing by front carbon atom connected to 3 groups then the 3 groups connected circle is a back carbon atom.

The dark wedge is represent the out of the plain then the light wedge is represent the inside the plain.

In the Newman projection, the atoms or groups are attached to the center carbon by angle of 60° and this is called as a dihedral angle.

The dihedral angle is varying by the rotation of C-C bond, result of this there are two conformations are obtained and this are staggered and eclipsed conformations obtained.

The highest energy conformation is eclipsed and lowest energy conformation is staggered.

Interaction between the groups present in the front and back carbon atoms are increases the energy of a compound all so increases.

(d)

Interpretation Introduction

Interpretation:

The highest and lowest energy conformations of giving compound should be drawn.

Concept Introduction:

Newman projection:

The conformational isomers are representing by the Newman projection drawing.

Newman projection representing by front carbon atom connected to 3 groups then the 3 groups connected circle is a back carbon atom.

The dark wedge is represent the out of the plain then the light wedge is represent the inside the plain.

In the Newman projection, the atoms or groups are attached to the center carbon by angle of 60° and this is called as a dihedral angle.

The dihedral angle is varying by the rotation of C-C bond, result of this there are two conformations are obtained and this are staggered and eclipsed conformations obtained.

The highest energy conformation is eclipsed and lowest energy conformation is staggered.

Interaction between the groups present in the front and back carbon atoms are increases the energy of a compound all so increases.

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Answer 4

Question

Chapter 4.8, Problem 19PTS

(a)

Interpretation Introduction

Interpretation:

The highest and lowest energy conformations of giving compound should be drawn.

Concept Introduction:

Newman projection:

The conformational isomers are representing by the Newman projection drawing.

Newman projection representing by front carbon atom connected to 3 groups then the 3 groups connected circle is a back carbon atom.

The dark wedge is represent the out of the plain then the light wedge is represent the inside the plain.

In the Newman projection, the atoms or groups are attached to the center carbon by angle of 60° and this is called as a dihedral angle.

The dihedral angle is varying by the rotation of C-C bond, result of this there are two conformations are obtained and this are staggered and eclipsed conformations obtained.

The highest energy conformation is eclipsed and lowest energy conformation is staggered.

Interaction between the groups present in the front and back carbon atoms are increases the energy of a compound all so increases.

(b)

Interpretation Introduction

Interpretation:

The highest and lowest energy conformations of giving compound should be drawn.

Concept Introduction:

Newman projection:

The conformational isomers are representing by the Newman projection drawing.

Newman projection representing by front carbon atom connected to 3 groups then the 3 groups connected circle is a back carbon atom.

The dark wedge is represent the out of the plain then the light wedge is represent the inside the plain.

In the Newman projection, the atoms or groups are attached to the center carbon by angle of 60° and this is called as a dihedral angle.

The dihedral angle is varying by the rotation of C-C bond, result of this there are two conformations are obtained and this are staggered and eclipsed conformations obtained.

The highest energy conformation is eclipsed and lowest energy conformation is staggered.

Interaction between the groups present in the front and back carbon atoms are increases the energy of a compound all so increases.

(c)

Interpretation Introduction

Interpretation:

The highest and lowest energy conformations of giving compound should be drawn.

Concept Introduction:

Newman projection:

The conformational isomers are representing by the Newman projection drawing.

Newman projection representing by front carbon atom connected to 3 groups then the 3 groups connected circle is a back carbon atom.

The dark wedge is represent the out of the plain then the light wedge is represent the inside the plain.

In the Newman projection, the atoms or groups are attached to the center carbon by angle of 60° and this is called as a dihedral angle.

The dihedral angle is varying by the rotation of C-C bond, result of this there are two conformations are obtained and this are staggered and eclipsed conformations obtained.

The highest energy conformation is eclipsed and lowest energy conformation is staggered.

Interaction between the groups present in the front and back carbon atoms are increases the energy of a compound all so increases.

(d)

Interpretation Introduction

Interpretation:

The highest and lowest energy conformations of giving compound should be drawn.

Concept Introduction:

Newman projection:

The conformational isomers are representing by the Newman projection drawing.

Newman projection representing by front carbon atom connected to 3 groups then the 3 groups connected circle is a back carbon atom.

The dark wedge is represent the out of the plain then the light wedge is represent the inside the plain.

In the Newman projection, the atoms or groups are attached to the center carbon by angle of 60° and this is called as a dihedral angle.

The dihedral angle is varying by the rotation of C-C bond, result of this there are two conformations are obtained and this are staggered and eclipsed conformations obtained.

The highest energy conformation is eclipsed and lowest energy conformation is staggered.

Interaction between the groups present in the front and back carbon atoms are increases the energy of a compound all so increases.

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Answer 5

Chapter 4.8, Problem 19PTS

(a)

Interpretation Introduction

Interpretation:

The highest and lowest energy conformations of giving compound should be drawn.

Concept Introduction:

Newman projection:

The conformational isomers are representing by the Newman projection drawing.

Newman projection representing by front carbon atom connected to 3 groups then the 3 groups connected circle is a back carbon atom.

The dark wedge is represent the out of the plain then the light wedge is represent the inside the plain.

In the Newman projection, the atoms or groups are attached to the center carbon by angle of 60° and this is called as a dihedral angle.

The dihedral angle is varying by the rotation of C-C bond, result of this there are two conformations are obtained and this are staggered and eclipsed conformations obtained.

The highest energy conformation is eclipsed and lowest energy conformation is staggered.

Interaction between the groups present in the front and back carbon atoms are increases the energy of a compound all so increases.

(b)

Interpretation Introduction

Interpretation:

The highest and lowest energy conformations of giving compound should be drawn.

Concept Introduction:

Newman projection:

The conformational isomers are representing by the Newman projection drawing.

Newman projection representing by front carbon atom connected to 3 groups then the 3 groups connected circle is a back carbon atom.

The dark wedge is represent the out of the plain then the light wedge is represent the inside the plain.

In the Newman projection, the atoms or groups are attached to the center carbon by angle of 60° and this is called as a dihedral angle.

The dihedral angle is varying by the rotation of C-C bond, result of this there are two conformations are obtained and this are staggered and eclipsed conformations obtained.

The highest energy conformation is eclipsed and lowest energy conformation is staggered.

Interaction between the groups present in the front and back carbon atoms are increases the energy of a compound all so increases.

(c)

Interpretation Introduction

Interpretation:

The highest and lowest energy conformations of giving compound should be drawn.

Concept Introduction:

Newman projection:

The conformational isomers are representing by the Newman projection drawing.

Newman projection representing by front carbon atom connected to 3 groups then the 3 groups connected circle is a back carbon atom.

The dark wedge is represent the out of the plain then the light wedge is represent the inside the plain.

In the Newman projection, the atoms or groups are attached to the center carbon by angle of 60° and this is called as a dihedral angle.

The dihedral angle is varying by the rotation of C-C bond, result of this there are two conformations are obtained and this are staggered and eclipsed conformations obtained.

The highest energy conformation is eclipsed and lowest energy conformation is staggered.

Interaction between the groups present in the front and back carbon atoms are increases the energy of a compound all so increases.

(d)

Interpretation Introduction

Interpretation:

The highest and lowest energy conformations of giving compound should be drawn.

Concept Introduction:

Newman projection:

The conformational isomers are representing by the Newman projection drawing.

Newman projection representing by front carbon atom connected to 3 groups then the 3 groups connected circle is a back carbon atom.

The dark wedge is represent the out of the plain then the light wedge is represent the inside the plain.

In the Newman projection, the atoms or groups are attached to the center carbon by angle of 60° and this is called as a dihedral angle.

The dihedral angle is varying by the rotation of C-C bond, result of this there are two conformations are obtained and this are staggered and eclipsed conformations obtained.

The highest energy conformation is eclipsed and lowest energy conformation is staggered.

Interaction between the groups present in the front and back carbon atoms are increases the energy of a compound all so increases.

Answer 6

Chapter 4.8, Problem 19PTS

(a)

Interpretation Introduction

Interpretation:

The highest and lowest energy conformations of giving compound should be drawn.

Concept Introduction:

Newman projection:

The conformational isomers are representing by the Newman projection drawing.

Newman projection representing by front carbon atom connected to 3 groups then the 3 groups connected circle is a back carbon atom.

The dark wedge is represent the out of the plain then the light wedge is represent the inside the plain.

In the Newman projection, the atoms or groups are attached to the center carbon by angle of 60° and this is called as a dihedral angle.

The dihedral angle is varying by the rotation of C-C bond, result of this there are two conformations are obtained and this are staggered and eclipsed conformations obtained.

The highest energy conformation is eclipsed and lowest energy conformation is staggered.

Interaction between the groups present in the front and back carbon atoms are increases the energy of a compound all so increases.

Answer 7

Chapter 4.8, Problem 19PTS

(a)

Interpretation Introduction

Interpretation:

The highest and lowest energy conformations of giving compound should be drawn.

Concept Introduction:

Newman projection:

The conformational isomers are representing by the Newman projection drawing.

Newman projection representing by front carbon atom connected to 3 groups then the 3 groups connected circle is a back carbon atom.

The dark wedge is represent the out of the plain then the light wedge is represent the inside the plain.

In the Newman projection, the atoms or groups are attached to the center carbon by angle of 60° and this is called as a dihedral angle.

The dihedral angle is varying by the rotation of C-C bond, result of this there are two conformations are obtained and this are staggered and eclipsed conformations obtained.

The highest energy conformation is eclipsed and lowest energy conformation is staggered.

Interaction between the groups present in the front and back carbon atoms are increases the energy of a compound all so increases.

Answer 8

(b)

Interpretation Introduction

Interpretation:

The highest and lowest energy conformations of giving compound should be drawn.

Concept Introduction:

Newman projection:

The conformational isomers are representing by the Newman projection drawing.

Newman projection representing by front carbon atom connected to 3 groups then the 3 groups connected circle is a back carbon atom.

The dark wedge is represent the out of the plain then the light wedge is represent the inside the plain.

In the Newman projection, the atoms or groups are attached to the center carbon by angle of 60° and this is called as a dihedral angle.

The dihedral angle is varying by the rotation of C-C bond, result of this there are two conformations are obtained and this are staggered and eclipsed conformations obtained.

The highest energy conformation is eclipsed and lowest energy conformation is staggered.

Interaction between the groups present in the front and back carbon atoms are increases the energy of a compound all so increases.

Answer 9

(b)

Interpretation Introduction

Interpretation:

The highest and lowest energy conformations of giving compound should be drawn.

Concept Introduction:

Newman projection:

The conformational isomers are representing by the Newman projection drawing.

Newman projection representing by front carbon atom connected to 3 groups then the 3 groups connected circle is a back carbon atom.

The dark wedge is represent the out of the plain then the light wedge is represent the inside the plain.

In the Newman projection, the atoms or groups are attached to the center carbon by angle of 60° and this is called as a dihedral angle.

The dihedral angle is varying by the rotation of C-C bond, result of this there are two conformations are obtained and this are staggered and eclipsed conformations obtained.

The highest energy conformation is eclipsed and lowest energy conformation is staggered.

Interaction between the groups present in the front and back carbon atoms are increases the energy of a compound all so increases.

Answer 10

(c)

Interpretation Introduction

Interpretation:

The highest and lowest energy conformations of giving compound should be drawn.

Concept Introduction:

Newman projection:

The conformational isomers are representing by the Newman projection drawing.

Newman projection representing by front carbon atom connected to 3 groups then the 3 groups connected circle is a back carbon atom.

The dark wedge is represent the out of the plain then the light wedge is represent the inside the plain.

In the Newman projection, the atoms or groups are attached to the center carbon by angle of 60° and this is called as a dihedral angle.

The dihedral angle is varying by the rotation of C-C bond, result of this there are two conformations are obtained and this are staggered and eclipsed conformations obtained.

The highest energy conformation is eclipsed and lowest energy conformation is staggered.

Interaction between the groups present in the front and back carbon atoms are increases the energy of a compound all so increases.

Answer 11

(c)

Interpretation Introduction

Interpretation:

The highest and lowest energy conformations of giving compound should be drawn.

Concept Introduction:

Newman projection:

The conformational isomers are representing by the Newman projection drawing.

Newman projection representing by front carbon atom connected to 3 groups then the 3 groups connected circle is a back carbon atom.

The dark wedge is represent the out of the plain then the light wedge is represent the inside the plain.

In the Newman projection, the atoms or groups are attached to the center carbon by angle of 60° and this is called as a dihedral angle.

The dihedral angle is varying by the rotation of C-C bond, result of this there are two conformations are obtained and this are staggered and eclipsed conformations obtained.

The highest energy conformation is eclipsed and lowest energy conformation is staggered.

Interaction between the groups present in the front and back carbon atoms are increases the energy of a compound all so increases.

Answer 12

(d)

Interpretation Introduction

Interpretation:

The highest and lowest energy conformations of giving compound should be drawn.

Concept Introduction:

Newman projection:

The conformational isomers are representing by the Newman projection drawing.

Newman projection representing by front carbon atom connected to 3 groups then the 3 groups connected circle is a back carbon atom.

The dark wedge is represent the out of the plain then the light wedge is represent the inside the plain.

In the Newman projection, the atoms or groups are attached to the center carbon by angle of 60° and this is called as a dihedral angle.

The dihedral angle is varying by the rotation of C-C bond, result of this there are two conformations are obtained and this are staggered and eclipsed conformations obtained.

The highest energy conformation is eclipsed and lowest energy conformation is staggered.

Interaction between the groups present in the front and back carbon atoms are increases the energy of a compound all so increases.

Answer 13

(d)

Interpretation Introduction

Interpretation:

The highest and lowest energy conformations of giving compound should be drawn.

Concept Introduction:

Newman projection:

The conformational isomers are representing by the Newman projection drawing.

Newman projection representing by front carbon atom connected to 3 groups then the 3 groups connected circle is a back carbon atom.

The dark wedge is represent the out of the plain then the light wedge is represent the inside the plain.

In the Newman projection, the atoms or groups are attached to the center carbon by angle of 60° and this is called as a dihedral angle.

The dihedral angle is varying by the rotation of C-C bond, result of this there are two conformations are obtained and this are staggered and eclipsed conformations obtained.

The highest energy conformation is eclipsed and lowest energy conformation is staggered.

Interaction between the groups present in the front and back carbon atoms are increases the energy of a compound all so increases.

Answer 14

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Ch. 4.2 - Prob. 1LTS Ch. 4.2 - Prob. 1PTS Ch. 4.2 - Prob. 2PTS Ch. 4.2 - Prob. 3ATS Ch. 4.2 - Prob. 2LTS Ch. 4.2 - Prob. 4PTS Ch. 4.2 - Prob. 5ATS Ch. 4.2 - Prob. 3LTS Ch. 4.2 - Prob. 6PTS Ch. 4.2 - Prob. 7ATS

Chapter 4 Solutions