The systematic name of given compounds has to be provided. Concept Introduction: Nomenclature of organic compounds: The naming of the organic compound is given by IUPAC (International Union for pure and applied chemistry). In the IUPAC names consist of certain rules for giving chemical names they are, The longer number of Carbon chain of a compound is identified this is called parent of the compound. In the cyclic compounds the number of carbon involving in ring formation is called parent of the compound. The compound have more than one parent chains means the larger number of substitutions present in the chain is consider as a parent chain. The names of all substituents are arranged by alphabets to starts with lowest numbering. In the complex substituent having compounds the substituent name is assigned by a name each of them based on numbers going away from the parent.

Question

Q4: Rank the relative nucleophilicity of halide ions in water solution and DMF solution, respectively. F CI Br | Q5: Determine which of the substrates will and will not react with NaSCH3 in an SN2 reaction to have a reasonable yield of product. NH2 Br Br Br OH Br

Answer 1

Question

Chapter 4.2, Problem 10ATS

(a)

Interpretation Introduction

Interpretation:

The systematic name of given compounds has to be provided.

Concept Introduction:

Nomenclature of organic compounds:

The naming of the organic compound is given by IUPAC (International Union for pure and applied chemistry). In the IUPAC names consist of certain rules for giving chemical names they are,

The longer number of Carbon chain of a compound is identified this is called parent of the compound.

In the cyclic compounds the number of carbon involving in ring formation is called parent of the compound.

The compound have more than one parent chains means the larger number of substitutions present in the chain is consider as a parent chain.

The names of all substituents are arranged by alphabets to starts with lowest numbering.

In the complex substituent having compounds the substituent name is assigned by a name each of them based on numbers going away from the parent.

(b)

Interpretation Introduction

Interpretation:

The systematic name of given compounds has to be provided.

Concept Introduction:

Nomenclature of organic compounds:

The naming of the organic compound is given by IUPAC (International Union for pure and applied chemistry). In the IUPAC names consist of certain rules for giving chemical names they are,

The longer number of Carbon chain of a compound is identified this is called parent of the compound.

In the cyclic compounds the number of carbon involving in ring formation is called parent of the compound.

The compound have more than one parent chains means the larger number of substitutions present in the chain is consider as a parent chain.

The names of all substituents are arranged by alphabets to starts with lowest numbering.

In the complex substituent having compounds the substituent name is assigned by a name each of them based on numbers going away from the parent.

(c)

Interpretation Introduction

Interpretation:

The systematic name of given compounds has to be provided.

Concept Introduction:

Nomenclature of organic compounds:

The naming of the organic compound is given by IUPAC (International Union for pure and applied chemistry). In the IUPAC names consist of certain rules for giving chemical names they are,

The longer number of Carbon chain of a compound is identified this is called parent of the compound.

In the cyclic compounds the number of carbon involving in ring formation is called parent of the compound.

The compound have more than one parent chains means the larger number of substitutions present in the chain is consider as a parent chain.

The names of all substituents are arranged by alphabets to starts with lowest numbering.

In the complex substituent having compounds the substituent name is assigned by a name each of them based on numbers going away from the parent.

(d)

Interpretation Introduction

Interpretation:

The systematic name of given compounds has to be provided.

Concept Introduction:

Nomenclature of organic compounds:

The naming of the organic compound is given by IUPAC (International Union for pure and applied chemistry). In the IUPAC names consist of certain rules for giving chemical names they are,

The longer number of Carbon chain of a compound is identified this is called parent of the compound.

In the cyclic compounds the number of carbon involving in ring formation is called parent of the compound.

The compound have more than one parent chains means the larger number of substitutions present in the chain is consider as a parent chain.

The names of all substituents are arranged by alphabets to starts with lowest numbering.

In the complex substituent having compounds the substituent name is assigned by a name each of them based on numbers going away from the parent.

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Q4: Rank the relative nucleophilicity of halide ions in water solution and DMF solution, respectively. F CI Br | Q5: Determine which of the substrates will and will not react with NaSCH3 in an SN2 reaction to have a reasonable yield of product. NH2 Br Br Br OH Br

Q7: Rank the following groups in order of basicity, nucleophilicity, and leaving group ability. a) H₂O, OH, CH3COOT b) NH3, H₂O, H₂S

Q8: Rank the following compounds in order of increasing reactivity in a nucleophilic substitution reaction with CN as the nucleophile. Br A B NH2 LL F C D OH CI LLI E Q9: Complete the missing entities for following reactions (e.g., major product(s), reactants, and/or solvents) for the SN2 reactions to occur efficiently. Include curved-arrow mechanism for reactions a) to d). a) H "Cl D + -OCH 3 Page 3 of 5

Answer 2

Question

Chapter 4.2, Problem 10ATS

(a)

Interpretation Introduction

Interpretation:

The systematic name of given compounds has to be provided.

Concept Introduction:

Nomenclature of organic compounds:

The naming of the organic compound is given by IUPAC (International Union for pure and applied chemistry). In the IUPAC names consist of certain rules for giving chemical names they are,

The longer number of Carbon chain of a compound is identified this is called parent of the compound.

In the cyclic compounds the number of carbon involving in ring formation is called parent of the compound.

The compound have more than one parent chains means the larger number of substitutions present in the chain is consider as a parent chain.

The names of all substituents are arranged by alphabets to starts with lowest numbering.

In the complex substituent having compounds the substituent name is assigned by a name each of them based on numbers going away from the parent.

(b)

Interpretation Introduction

Interpretation:

The systematic name of given compounds has to be provided.

Concept Introduction:

Nomenclature of organic compounds:

The naming of the organic compound is given by IUPAC (International Union for pure and applied chemistry). In the IUPAC names consist of certain rules for giving chemical names they are,

The longer number of Carbon chain of a compound is identified this is called parent of the compound.

In the cyclic compounds the number of carbon involving in ring formation is called parent of the compound.

The compound have more than one parent chains means the larger number of substitutions present in the chain is consider as a parent chain.

The names of all substituents are arranged by alphabets to starts with lowest numbering.

In the complex substituent having compounds the substituent name is assigned by a name each of them based on numbers going away from the parent.

(c)

Interpretation Introduction

Interpretation:

The systematic name of given compounds has to be provided.

Concept Introduction:

Nomenclature of organic compounds:

The naming of the organic compound is given by IUPAC (International Union for pure and applied chemistry). In the IUPAC names consist of certain rules for giving chemical names they are,

The longer number of Carbon chain of a compound is identified this is called parent of the compound.

In the cyclic compounds the number of carbon involving in ring formation is called parent of the compound.

The compound have more than one parent chains means the larger number of substitutions present in the chain is consider as a parent chain.

The names of all substituents are arranged by alphabets to starts with lowest numbering.

In the complex substituent having compounds the substituent name is assigned by a name each of them based on numbers going away from the parent.

(d)

Interpretation Introduction

Interpretation:

The systematic name of given compounds has to be provided.

Concept Introduction:

Nomenclature of organic compounds:

The naming of the organic compound is given by IUPAC (International Union for pure and applied chemistry). In the IUPAC names consist of certain rules for giving chemical names they are,

The longer number of Carbon chain of a compound is identified this is called parent of the compound.

In the cyclic compounds the number of carbon involving in ring formation is called parent of the compound.

The compound have more than one parent chains means the larger number of substitutions present in the chain is consider as a parent chain.

The names of all substituents are arranged by alphabets to starts with lowest numbering.

In the complex substituent having compounds the substituent name is assigned by a name each of them based on numbers going away from the parent.

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Answer 3

Question

Chapter 4.2, Problem 10ATS

(a)

Interpretation Introduction

Interpretation:

The systematic name of given compounds has to be provided.

Concept Introduction:

Nomenclature of organic compounds:

The naming of the organic compound is given by IUPAC (International Union for pure and applied chemistry). In the IUPAC names consist of certain rules for giving chemical names they are,

The longer number of Carbon chain of a compound is identified this is called parent of the compound.

In the cyclic compounds the number of carbon involving in ring formation is called parent of the compound.

The compound have more than one parent chains means the larger number of substitutions present in the chain is consider as a parent chain.

The names of all substituents are arranged by alphabets to starts with lowest numbering.

In the complex substituent having compounds the substituent name is assigned by a name each of them based on numbers going away from the parent.

(b)

Interpretation Introduction

Interpretation:

The systematic name of given compounds has to be provided.

Concept Introduction:

Nomenclature of organic compounds:

The naming of the organic compound is given by IUPAC (International Union for pure and applied chemistry). In the IUPAC names consist of certain rules for giving chemical names they are,

The longer number of Carbon chain of a compound is identified this is called parent of the compound.

In the cyclic compounds the number of carbon involving in ring formation is called parent of the compound.

The compound have more than one parent chains means the larger number of substitutions present in the chain is consider as a parent chain.

The names of all substituents are arranged by alphabets to starts with lowest numbering.

In the complex substituent having compounds the substituent name is assigned by a name each of them based on numbers going away from the parent.

(c)

Interpretation Introduction

Interpretation:

The systematic name of given compounds has to be provided.

Concept Introduction:

Nomenclature of organic compounds:

The naming of the organic compound is given by IUPAC (International Union for pure and applied chemistry). In the IUPAC names consist of certain rules for giving chemical names they are,

The longer number of Carbon chain of a compound is identified this is called parent of the compound.

In the cyclic compounds the number of carbon involving in ring formation is called parent of the compound.

The compound have more than one parent chains means the larger number of substitutions present in the chain is consider as a parent chain.

The names of all substituents are arranged by alphabets to starts with lowest numbering.

In the complex substituent having compounds the substituent name is assigned by a name each of them based on numbers going away from the parent.

(d)

Interpretation Introduction

Interpretation:

The systematic name of given compounds has to be provided.

Concept Introduction:

Nomenclature of organic compounds:

The naming of the organic compound is given by IUPAC (International Union for pure and applied chemistry). In the IUPAC names consist of certain rules for giving chemical names they are,

The longer number of Carbon chain of a compound is identified this is called parent of the compound.

In the cyclic compounds the number of carbon involving in ring formation is called parent of the compound.

The compound have more than one parent chains means the larger number of substitutions present in the chain is consider as a parent chain.

The names of all substituents are arranged by alphabets to starts with lowest numbering.

In the complex substituent having compounds the substituent name is assigned by a name each of them based on numbers going away from the parent.

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Answer 4

Question

Chapter 4.2, Problem 10ATS

(a)

Interpretation Introduction

Interpretation:

The systematic name of given compounds has to be provided.

Concept Introduction:

Nomenclature of organic compounds:

The naming of the organic compound is given by IUPAC (International Union for pure and applied chemistry). In the IUPAC names consist of certain rules for giving chemical names they are,

The longer number of Carbon chain of a compound is identified this is called parent of the compound.

In the cyclic compounds the number of carbon involving in ring formation is called parent of the compound.

The compound have more than one parent chains means the larger number of substitutions present in the chain is consider as a parent chain.

The names of all substituents are arranged by alphabets to starts with lowest numbering.

In the complex substituent having compounds the substituent name is assigned by a name each of them based on numbers going away from the parent.

(b)

Interpretation Introduction

Interpretation:

The systematic name of given compounds has to be provided.

Concept Introduction:

Nomenclature of organic compounds:

The naming of the organic compound is given by IUPAC (International Union for pure and applied chemistry). In the IUPAC names consist of certain rules for giving chemical names they are,

The longer number of Carbon chain of a compound is identified this is called parent of the compound.

In the cyclic compounds the number of carbon involving in ring formation is called parent of the compound.

The compound have more than one parent chains means the larger number of substitutions present in the chain is consider as a parent chain.

The names of all substituents are arranged by alphabets to starts with lowest numbering.

In the complex substituent having compounds the substituent name is assigned by a name each of them based on numbers going away from the parent.

(c)

Interpretation Introduction

Interpretation:

The systematic name of given compounds has to be provided.

Concept Introduction:

Nomenclature of organic compounds:

The naming of the organic compound is given by IUPAC (International Union for pure and applied chemistry). In the IUPAC names consist of certain rules for giving chemical names they are,

The longer number of Carbon chain of a compound is identified this is called parent of the compound.

In the cyclic compounds the number of carbon involving in ring formation is called parent of the compound.

The compound have more than one parent chains means the larger number of substitutions present in the chain is consider as a parent chain.

The names of all substituents are arranged by alphabets to starts with lowest numbering.

In the complex substituent having compounds the substituent name is assigned by a name each of them based on numbers going away from the parent.

(d)

Interpretation Introduction

Interpretation:

The systematic name of given compounds has to be provided.

Concept Introduction:

Nomenclature of organic compounds:

The naming of the organic compound is given by IUPAC (International Union for pure and applied chemistry). In the IUPAC names consist of certain rules for giving chemical names they are,

The longer number of Carbon chain of a compound is identified this is called parent of the compound.

In the cyclic compounds the number of carbon involving in ring formation is called parent of the compound.

The compound have more than one parent chains means the larger number of substitutions present in the chain is consider as a parent chain.

The names of all substituents are arranged by alphabets to starts with lowest numbering.

In the complex substituent having compounds the substituent name is assigned by a name each of them based on numbers going away from the parent.

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Answer 5

Chapter 4.2, Problem 10ATS

(a)

Interpretation Introduction

Interpretation:

The systematic name of given compounds has to be provided.

Concept Introduction:

Nomenclature of organic compounds:

The naming of the organic compound is given by IUPAC (International Union for pure and applied chemistry). In the IUPAC names consist of certain rules for giving chemical names they are,

The longer number of Carbon chain of a compound is identified this is called parent of the compound.

In the cyclic compounds the number of carbon involving in ring formation is called parent of the compound.

The compound have more than one parent chains means the larger number of substitutions present in the chain is consider as a parent chain.

The names of all substituents are arranged by alphabets to starts with lowest numbering.

In the complex substituent having compounds the substituent name is assigned by a name each of them based on numbers going away from the parent.

(b)

Interpretation Introduction

Interpretation:

The systematic name of given compounds has to be provided.

Concept Introduction:

Nomenclature of organic compounds:

The naming of the organic compound is given by IUPAC (International Union for pure and applied chemistry). In the IUPAC names consist of certain rules for giving chemical names they are,

The longer number of Carbon chain of a compound is identified this is called parent of the compound.

In the cyclic compounds the number of carbon involving in ring formation is called parent of the compound.

The compound have more than one parent chains means the larger number of substitutions present in the chain is consider as a parent chain.

The names of all substituents are arranged by alphabets to starts with lowest numbering.

In the complex substituent having compounds the substituent name is assigned by a name each of them based on numbers going away from the parent.

(c)

Interpretation Introduction

Interpretation:

The systematic name of given compounds has to be provided.

Concept Introduction:

Nomenclature of organic compounds:

The naming of the organic compound is given by IUPAC (International Union for pure and applied chemistry). In the IUPAC names consist of certain rules for giving chemical names they are,

The longer number of Carbon chain of a compound is identified this is called parent of the compound.

In the cyclic compounds the number of carbon involving in ring formation is called parent of the compound.

The compound have more than one parent chains means the larger number of substitutions present in the chain is consider as a parent chain.

The names of all substituents are arranged by alphabets to starts with lowest numbering.

In the complex substituent having compounds the substituent name is assigned by a name each of them based on numbers going away from the parent.

(d)

Interpretation Introduction

Interpretation:

The systematic name of given compounds has to be provided.

Concept Introduction:

Nomenclature of organic compounds:

The naming of the organic compound is given by IUPAC (International Union for pure and applied chemistry). In the IUPAC names consist of certain rules for giving chemical names they are,

The longer number of Carbon chain of a compound is identified this is called parent of the compound.

In the cyclic compounds the number of carbon involving in ring formation is called parent of the compound.

The compound have more than one parent chains means the larger number of substitutions present in the chain is consider as a parent chain.

The names of all substituents are arranged by alphabets to starts with lowest numbering.

In the complex substituent having compounds the substituent name is assigned by a name each of them based on numbers going away from the parent.

Answer 6

Chapter 4.2, Problem 10ATS

(a)

Interpretation Introduction

Interpretation:

The systematic name of given compounds has to be provided.

Concept Introduction:

Nomenclature of organic compounds:

The naming of the organic compound is given by IUPAC (International Union for pure and applied chemistry). In the IUPAC names consist of certain rules for giving chemical names they are,

The longer number of Carbon chain of a compound is identified this is called parent of the compound.

In the cyclic compounds the number of carbon involving in ring formation is called parent of the compound.

The compound have more than one parent chains means the larger number of substitutions present in the chain is consider as a parent chain.

The names of all substituents are arranged by alphabets to starts with lowest numbering.

In the complex substituent having compounds the substituent name is assigned by a name each of them based on numbers going away from the parent.

Answer 7

Chapter 4.2, Problem 10ATS

(a)

Interpretation Introduction

Interpretation:

The systematic name of given compounds has to be provided.

Concept Introduction:

Nomenclature of organic compounds:

The naming of the organic compound is given by IUPAC (International Union for pure and applied chemistry). In the IUPAC names consist of certain rules for giving chemical names they are,

The longer number of Carbon chain of a compound is identified this is called parent of the compound.

In the cyclic compounds the number of carbon involving in ring formation is called parent of the compound.

The compound have more than one parent chains means the larger number of substitutions present in the chain is consider as a parent chain.

The names of all substituents are arranged by alphabets to starts with lowest numbering.

In the complex substituent having compounds the substituent name is assigned by a name each of them based on numbers going away from the parent.

Answer 8

(b)

Interpretation Introduction

Interpretation:

The systematic name of given compounds has to be provided.

Concept Introduction:

Nomenclature of organic compounds:

The naming of the organic compound is given by IUPAC (International Union for pure and applied chemistry). In the IUPAC names consist of certain rules for giving chemical names they are,

The longer number of Carbon chain of a compound is identified this is called parent of the compound.

In the cyclic compounds the number of carbon involving in ring formation is called parent of the compound.

The compound have more than one parent chains means the larger number of substitutions present in the chain is consider as a parent chain.

The names of all substituents are arranged by alphabets to starts with lowest numbering.

In the complex substituent having compounds the substituent name is assigned by a name each of them based on numbers going away from the parent.

Answer 9

(b)

Interpretation Introduction

Interpretation:

The systematic name of given compounds has to be provided.

Concept Introduction:

Nomenclature of organic compounds:

The naming of the organic compound is given by IUPAC (International Union for pure and applied chemistry). In the IUPAC names consist of certain rules for giving chemical names they are,

The longer number of Carbon chain of a compound is identified this is called parent of the compound.

In the cyclic compounds the number of carbon involving in ring formation is called parent of the compound.

The compound have more than one parent chains means the larger number of substitutions present in the chain is consider as a parent chain.

The names of all substituents are arranged by alphabets to starts with lowest numbering.

In the complex substituent having compounds the substituent name is assigned by a name each of them based on numbers going away from the parent.

Answer 10

(c)

Interpretation Introduction

Interpretation:

The systematic name of given compounds has to be provided.

Concept Introduction:

Nomenclature of organic compounds:

The naming of the organic compound is given by IUPAC (International Union for pure and applied chemistry). In the IUPAC names consist of certain rules for giving chemical names they are,

The longer number of Carbon chain of a compound is identified this is called parent of the compound.

In the cyclic compounds the number of carbon involving in ring formation is called parent of the compound.

The compound have more than one parent chains means the larger number of substitutions present in the chain is consider as a parent chain.

The names of all substituents are arranged by alphabets to starts with lowest numbering.

In the complex substituent having compounds the substituent name is assigned by a name each of them based on numbers going away from the parent.

Answer 11

(c)

Interpretation Introduction

Interpretation:

The systematic name of given compounds has to be provided.

Concept Introduction:

Nomenclature of organic compounds:

The naming of the organic compound is given by IUPAC (International Union for pure and applied chemistry). In the IUPAC names consist of certain rules for giving chemical names they are,

The longer number of Carbon chain of a compound is identified this is called parent of the compound.

In the cyclic compounds the number of carbon involving in ring formation is called parent of the compound.

The compound have more than one parent chains means the larger number of substitutions present in the chain is consider as a parent chain.

The names of all substituents are arranged by alphabets to starts with lowest numbering.

In the complex substituent having compounds the substituent name is assigned by a name each of them based on numbers going away from the parent.

Answer 12

(d)

Interpretation Introduction

Interpretation:

The systematic name of given compounds has to be provided.

Concept Introduction:

Nomenclature of organic compounds:

The naming of the organic compound is given by IUPAC (International Union for pure and applied chemistry). In the IUPAC names consist of certain rules for giving chemical names they are,

The longer number of Carbon chain of a compound is identified this is called parent of the compound.

In the cyclic compounds the number of carbon involving in ring formation is called parent of the compound.

The compound have more than one parent chains means the larger number of substitutions present in the chain is consider as a parent chain.

The names of all substituents are arranged by alphabets to starts with lowest numbering.

In the complex substituent having compounds the substituent name is assigned by a name each of them based on numbers going away from the parent.

Answer 13

(d)

Interpretation Introduction

Interpretation:

The systematic name of given compounds has to be provided.

Concept Introduction:

Nomenclature of organic compounds:

The naming of the organic compound is given by IUPAC (International Union for pure and applied chemistry). In the IUPAC names consist of certain rules for giving chemical names they are,

The longer number of Carbon chain of a compound is identified this is called parent of the compound.

In the cyclic compounds the number of carbon involving in ring formation is called parent of the compound.

The compound have more than one parent chains means the larger number of substitutions present in the chain is consider as a parent chain.

The names of all substituents are arranged by alphabets to starts with lowest numbering.

In the complex substituent having compounds the substituent name is assigned by a name each of them based on numbers going away from the parent.

Answer 14

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Answer 25

Ch. 4.2 - Prob. 1LTS Ch. 4.2 - Prob. 1PTS Ch. 4.2 - Prob. 2PTS Ch. 4.2 - Prob. 3ATS Ch. 4.2 - Prob. 2LTS Ch. 4.2 - Prob. 4PTS Ch. 4.2 - Prob. 5ATS Ch. 4.2 - Prob. 3LTS Ch. 4.2 - Prob. 6PTS Ch. 4.2 - Prob. 7ATS

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