The relative priorities for the given set of substituents have to be assigned. Concept introduction: E-Z designators are used as like cis-trans terminology for non-similar groups attached alkenes. In E-Z designations, the groups attached to vinylic positions are checked by their priority on the basis of higher atomic weight of connected atom, if it is same for the connected atom then consider the next atom of each group and so on. In case of multiple bonds connected with same atoms, then the higher bonds having group has higher priority.

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Answer 1

Question

Chapter 4.2, Problem 7P

(a)

Interpretation Introduction

Interpretation:

The relative priorities for the given set of substituents have to be assigned.

Concept introduction:

E-Z designators are used as like cis-trans terminology for non-similar groups attached alkenes.

In E-Z designations, the groups attached to vinylic positions are checked by their priority on the basis of higher atomic weight of connected atom, if it is same for the connected atom then consider the next atom of each group and so on. In case of multiple bonds connected with same atoms, then the higher bonds having group has higher priority.

(b)

Interpretation Introduction

Interpretation:

The relative priorities for the given set of substituents have to be assigned.

Concept introduction:

E-Z designators are used as like cis-trans terminology for non-similar groups attached alkenes.

In E-Z designations, the groups attached to vinylic positions are checked by their priority on the basis of higher atomic weight of connected atom, if it is same for the connected atom then consider the next atom of each group and so on. In case of multiple bonds connected with same atoms, then the higher bonds having group has higher priority.

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15) Give the IUPAC name for each compound.

Q8 Conformational Analysis of Cycloalkanes In this question you will look at the conformations of the following molecule: CH3 C В F CH3 D -E A H3C F I II Energy Costs for Interactions in Alkane Conformers: Computed Energy Cost (kJ/mol)* 3.8 Interaction H+H eclipsed H+CH3 eclipsed CH3+CH3 eclipsed CH3+CH3 gauche H»CH(CH3)2 gauche H CH(CH:)2 eclipsed CH3+CH(CH3)2 gauche CH3+CH(CH3)2 eclipsed HeC(CH:)3 eclipsed CH3+C(CH3)3 gauche CH3+C(CH:)3 eclipsed H+I eclipsed I+CH3 gauche I+CH3 eclipsed "Values computed with Gaussian09 using B3LYP/6-31G(d) for structure optimization and B3LYP/6-311+G(2df,3p) for the conformation energy. The calculations were performed in the gas phase (no solvent). *This result for t-butyl is a bit peculiar given that the value is less than that for isopropyl, but there is an explanation that I can tell you about in office hours! 4.8 12.6 3.7 (0.0) 3.1 3.6 17.3 2.8 13.6 18.7 6.7 1.2 15.5 Steric Strain in Monosubstituted Cyclohexanes: 1,3-Diaxial strain Y (kJ/mol)…

Give the IUPAC name of the following compounds. Answers must be in small or lower case letters.

Answer 2

Question

Chapter 4.2, Problem 7P

(a)

Interpretation Introduction

Interpretation:

The relative priorities for the given set of substituents have to be assigned.

Concept introduction:

E-Z designators are used as like cis-trans terminology for non-similar groups attached alkenes.

In E-Z designations, the groups attached to vinylic positions are checked by their priority on the basis of higher atomic weight of connected atom, if it is same for the connected atom then consider the next atom of each group and so on. In case of multiple bonds connected with same atoms, then the higher bonds having group has higher priority.

(b)

Interpretation Introduction

Interpretation:

The relative priorities for the given set of substituents have to be assigned.

Concept introduction:

E-Z designators are used as like cis-trans terminology for non-similar groups attached alkenes.

In E-Z designations, the groups attached to vinylic positions are checked by their priority on the basis of higher atomic weight of connected atom, if it is same for the connected atom then consider the next atom of each group and so on. In case of multiple bonds connected with same atoms, then the higher bonds having group has higher priority.

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Answer 3

Question

Chapter 4.2, Problem 7P

(a)

Interpretation Introduction

Interpretation:

The relative priorities for the given set of substituents have to be assigned.

Concept introduction:

E-Z designators are used as like cis-trans terminology for non-similar groups attached alkenes.

In E-Z designations, the groups attached to vinylic positions are checked by their priority on the basis of higher atomic weight of connected atom, if it is same for the connected atom then consider the next atom of each group and so on. In case of multiple bonds connected with same atoms, then the higher bonds having group has higher priority.

(b)

Interpretation Introduction

Interpretation:

The relative priorities for the given set of substituents have to be assigned.

Concept introduction:

E-Z designators are used as like cis-trans terminology for non-similar groups attached alkenes.

In E-Z designations, the groups attached to vinylic positions are checked by their priority on the basis of higher atomic weight of connected atom, if it is same for the connected atom then consider the next atom of each group and so on. In case of multiple bonds connected with same atoms, then the higher bonds having group has higher priority.

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Answer 4

Question

Chapter 4.2, Problem 7P

(a)

Interpretation Introduction

Interpretation:

The relative priorities for the given set of substituents have to be assigned.

Concept introduction:

E-Z designators are used as like cis-trans terminology for non-similar groups attached alkenes.

In E-Z designations, the groups attached to vinylic positions are checked by their priority on the basis of higher atomic weight of connected atom, if it is same for the connected atom then consider the next atom of each group and so on. In case of multiple bonds connected with same atoms, then the higher bonds having group has higher priority.

(b)

Interpretation Introduction

Interpretation:

The relative priorities for the given set of substituents have to be assigned.

Concept introduction:

E-Z designators are used as like cis-trans terminology for non-similar groups attached alkenes.

In E-Z designations, the groups attached to vinylic positions are checked by their priority on the basis of higher atomic weight of connected atom, if it is same for the connected atom then consider the next atom of each group and so on. In case of multiple bonds connected with same atoms, then the higher bonds having group has higher priority.

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Answer 5

Chapter 4.2, Problem 7P

(a)

Interpretation Introduction

Interpretation:

The relative priorities for the given set of substituents have to be assigned.

Concept introduction:

E-Z designators are used as like cis-trans terminology for non-similar groups attached alkenes.

In E-Z designations, the groups attached to vinylic positions are checked by their priority on the basis of higher atomic weight of connected atom, if it is same for the connected atom then consider the next atom of each group and so on. In case of multiple bonds connected with same atoms, then the higher bonds having group has higher priority.

(b)

Interpretation Introduction

Interpretation:

The relative priorities for the given set of substituents have to be assigned.

Concept introduction:

E-Z designators are used as like cis-trans terminology for non-similar groups attached alkenes.

In E-Z designations, the groups attached to vinylic positions are checked by their priority on the basis of higher atomic weight of connected atom, if it is same for the connected atom then consider the next atom of each group and so on. In case of multiple bonds connected with same atoms, then the higher bonds having group has higher priority.

Answer 6

Chapter 4.2, Problem 7P

(a)

Interpretation Introduction

Interpretation:

The relative priorities for the given set of substituents have to be assigned.

Concept introduction:

E-Z designators are used as like cis-trans terminology for non-similar groups attached alkenes.

In E-Z designations, the groups attached to vinylic positions are checked by their priority on the basis of higher atomic weight of connected atom, if it is same for the connected atom then consider the next atom of each group and so on. In case of multiple bonds connected with same atoms, then the higher bonds having group has higher priority.

Answer 7

Chapter 4.2, Problem 7P

(a)

Interpretation Introduction

Interpretation:

The relative priorities for the given set of substituents have to be assigned.

Concept introduction:

E-Z designators are used as like cis-trans terminology for non-similar groups attached alkenes.

In E-Z designations, the groups attached to vinylic positions are checked by their priority on the basis of higher atomic weight of connected atom, if it is same for the connected atom then consider the next atom of each group and so on. In case of multiple bonds connected with same atoms, then the higher bonds having group has higher priority.

Answer 8

(b)

Interpretation Introduction

Interpretation:

The relative priorities for the given set of substituents have to be assigned.

Concept introduction:

E-Z designators are used as like cis-trans terminology for non-similar groups attached alkenes.

In E-Z designations, the groups attached to vinylic positions are checked by their priority on the basis of higher atomic weight of connected atom, if it is same for the connected atom then consider the next atom of each group and so on. In case of multiple bonds connected with same atoms, then the higher bonds having group has higher priority.

Answer 9

(b)

Interpretation Introduction

Interpretation:

The relative priorities for the given set of substituents have to be assigned.

Concept introduction:

E-Z designators are used as like cis-trans terminology for non-similar groups attached alkenes.

In E-Z designations, the groups attached to vinylic positions are checked by their priority on the basis of higher atomic weight of connected atom, if it is same for the connected atom then consider the next atom of each group and so on. In case of multiple bonds connected with same atoms, then the higher bonds having group has higher priority.

Answer 10

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Answer 11

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Answer 12

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Answer 13

Ch. 4.1 - Draw the cis and trans isomers for the following:...Ch. 4.1 - Prob. 4P Ch. 4.1 - Prob. 5P Ch. 4.1 - Prob. 6P Ch. 4.2 - Prob. 7P Ch. 4.2 - Tamoxifen slows the growth of some breast tumors...Ch. 4.2 - Draw and label the E and Z isomers for each of the...Ch. 4.2 - Prob. 10P Ch. 4.2 - Name each of the following:Ch. 4.2 - Draw the structure of (Z)-2,3-dimethyl-3-heptene.

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