Essential Organic Chemistry, Global Edition
3rd Edition
ISBN: 9781292089034
Author: Paula Yurkanis Bruice
Publisher: PEARSON
expand_more
expand_more
format_list_bulleted
Concept explainers
Question
Chapter 4, Problem 51P
(a)
Interpretation Introduction
Interpretation:
The relative priorities for the given set of groups has to be assigned.
Concept introduction:
According to Cahn-Ingold-Prelog system,
The group attached to asymmetric center should be ranked based on the
(b)
Interpretation Introduction
Interpretation:
The relative priorities for the given set of groups has to be assigned.
Concept introduction:
According to Cahn-Ingold-Prelog system,
The group attached to asymmetric center should be ranked based on the atomic number of atom which directly connected to asymmetric center. The higher the atomic number of atom, higher the priority. If there is tie, then consider the next atoms attached to the connected atom and so on.
(c)
Interpretation Introduction
Interpretation:
The relative priorities for the given set of groups has to be assigned.
Concept introduction:
According to Cahn-Ingold-Prelog system,
The group attached to asymmetric center should be ranked based on the atomic number of atom which directly connected to asymmetric center. The higher the atomic number of atom, higher the priority. If there is tie, then consider the next atoms attached to the connected atom and so on.
Expert Solution & Answer
Want to see the full answer?
Check out a sample textbook solution
Students have asked these similar questions
Associate each structure or formula with its degree of unsaturation:
CH3OH
XE
HN
5
H3C
�� Choose...
8
4
10
9
11
12
6
A
CH3
C13H12N2O4
BI
TO
CH3
NH
C21H30OBr2
D
Next page
1. Assign priorities to these set of Substituents
а. -ОН, -СН2CH3 ,
-CH=CH2
-OCH2CH3
b. -NH2
-NO2
-NHCH3 ,
-C=N
с. -СH2CH3
-CH2SH , -CH(CH3)2
-C=CH
d.
CH
COCH3
-coČCH3
e. -CH(CH3)2 , -C(CH3)3 , -CH2CH(CH3)2 ,-CH2C(CH3)3
f. -OCI , -NHCI
-OBr
-NHB.
End of document I
Rank the following substituents in order of increasing priority.
-CH=CH2
-OH
-O-CH3
-CH=O
II
II
IV
II, II, IV, I
I, II, IV, II
I, II, III, IV
I, IV, II, II
Chapter 4 Solutions
Essential Organic Chemistry, Global Edition
Ch. 4.1 - Draw the cis and trans isomers for the following:...Ch. 4.1 - Prob. 4PCh. 4.1 - Prob. 5PCh. 4.1 - Prob. 6PCh. 4.2 - Prob. 7PCh. 4.2 - Tamoxifen slows the growth of some breast tumors...Ch. 4.2 - Draw and label the E and Z isomers for each of the...Ch. 4.2 - Prob. 10PCh. 4.2 - Name each of the following:Ch. 4.2 - Draw the structure of (Z)-2,3-dimethyl-3-heptene.
Ch. 4.3 - Prob. 13PCh. 4.4 - Prob. 14PCh. 4.5 - Prob. 16PCh. 4.6 - Prob. 17PCh. 4.7 - Assign relative priorities to the groups or atoms...Ch. 4.7 - Name the following:Ch. 4.7 - Prob. 22PCh. 4.7 - Draw a perspective formula for each of the...Ch. 4.8 - Prob. 24PCh. 4.8 - Prob. 27PCh. 4.9 - Prob. 28PCh. 4.9 - Prob. 29PCh. 4.9 - Prob. 30PCh. 4.10 - Prob. 31PCh. 4.10 - Prob. 32PCh. 4.10 - Prob. 33PCh. 4.11 - Prob. 34PCh. 4.11 - a. Draw the stereoisomers of...Ch. 4.11 - Prob. 37PCh. 4.11 - Prob. 38PCh. 4.12 - Which of the following compounds has a...Ch. 4.12 - Draw all the stereoisomers for each of the...Ch. 4.12 - Limonene exists as two different stereoisomers....Ch. 4 - a. Draw three constitutional isomers with...Ch. 4 - Which of the following have an asymmetric center?...Ch. 4 - Prob. 45PCh. 4 - Prob. 46PCh. 4 - Of all the possible cyclooctanes that have one...Ch. 4 - Prob. 48PCh. 4 - Prob. 49PCh. 4 - Prob. 50PCh. 4 - Prob. 51PCh. 4 - Prob. 52PCh. 4 - Draw the stereoisomers of 2,4-dichlorohexane....Ch. 4 - Prob. 54PCh. 4 - Prob. 55PCh. 4 - Prob. 56PCh. 4 - Prob. 57PCh. 4 - Prob. 58PCh. 4 - Prob. 59PCh. 4 - Prob. 60PCh. 4 - Prob. 61PCh. 4 - Prob. 62PCh. 4 - Draw structures for each of the following: a....Ch. 4 - Prob. 64PCh. 4 - a. Draw all the isomers with molecular formula...Ch. 4 - Prob. 66PCh. 4 - Prob. 67PCh. 4 - Prob. 68PCh. 4 - Chloramphenicol is a broad-spectrum antibiotic...
Knowledge Booster
Learn more about
Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.Similar questions
- Newman Projections Newman projections draw chemical conformations of a carbon-carbon chemical bond from front to back, with the fi carbon represented by a dot and the back carbon as a circle. H H The following Newman Projection is a representation of which structure? H. CH, CH3 CH3 CH, CH3 CH CH, CH CH H. A В C D В O 0 00arrow_forwardPART 1: For the decalin derivative below please identify the correct Newman projection: Please type your answer as a letter: A, B, C, or D. The answer for PART 1: Н H Н. A B CH3 CH3 Н CH3 CH3 Н အက်သလို လုံး Н. под Н OH CH3 OH H3C Н H3C H₂C H3C H3C Н Н The answer for PART 2: A CH3 OH E C CH3 CH3 OH "CH₂ CH3 H H3C. H3C Н H Н. H.C..... H3C OH OH CH3 PART 2: For the Newman projection below please identify the corresponding decalin derivative with the correct stereochemistry: Please type your answer as a letter: A, B, C, ..., or H. CH3 H B н Н OH F CH3 CH₂ OH он "CH3 OH CH₂ CH3 H3C H H₂C Н H3C Н H C D CH3 SASA SA CH3 H₂C CH3 H₂C" H3C" он CH3 H OH CH3 G CH3 CH3 CH3 ÕH D CH3 CH3 CH3 H H H3C_ Н.С Н CH3 CH₂ H OH H Н CH3arrow_forwardMenthol is a common additive to dental products, topical analgesics, decongestants and many other everyday items. Below is the structure of menthol. Which is the most stable chair conformer of menthol? A a B b C C D d CH3 HO Menthol CH3 -CH3 но но но CH3 CH3 OH A. Barrow_forward
- What is the most stable chair conformation of the 4-methoxy-1,2- dimethylcyclohexane structure given below? A a B b с с D d OCH: "CH3 H3C 4-methoxy-1,2-dimethylcyclohexane OCH: OCH3 H3C H3C- H3C- OCH3 H3C -OCH3 ĆH: CH3 CH3 CH3 A B Darrow_forwardA) (CH3)2CHCH2OH + H2SO4 + ISI CH3CH2CH(CH3)OH+H2SO4 + ISI B) C) CH3CH2CH(CH3)O Na + (CH3)2CHCH2Br O) (CH3)2CHCH₂ONa + CH3CH2CH(CH3) Br 4arrow_forwardLabel each pair of alkenes as constitutional isomers or stereoisomers. Select the single best answer for each part below. Part 1 of 3 H₂C=CHCH₂CH₂CH₂CH₂CH₂CH3 and H₂CH₂CHC=CHCH₂CH₂CH₂CH₂ O stereoisomers O constitutional isomers Part 2 of 3 H₂C H Part 3 of 3 O constitutional isomers O stereoisomers H₂C H CH₂CH3 H₂C H X CH₂CH₂CH₂CH₂ H O constitutional isomers O stereoisomers X CH₂ H X H₂C 5 CH₂CH₂CH₂CH₂ H 00 ← B 00 Ar !arrow_forward
- What is the correct priority numbering of substituents on the following compound? (hydrogen is number 4 and not visible in the Newman projections given) a) 2 b) XoXo to c) OH OH 1 H OH 3 OH 3 2 3 ô 3 OH 2arrow_forwardCan someone help me with these questions. Thank youarrow_forwardWhich C2-C3 Newman projection represents (S)-4-methylpentan-2-ol? H Н_ _н (A) Н. H3C ОН J Н Н CH(CH3)2 (В) H₂C OH CH(CH3)2 (C) H H3C ОН CH(CH3)2 (D) CH3, HH НО SH CH(CH3)2arrow_forward
arrow_back_ios
SEE MORE QUESTIONS
arrow_forward_ios
Recommended textbooks for you
Organic ChemistryChemistryISBN:9781305580350Author:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. FootePublisher:Cengage Learning
Chemistry: An Atoms First ApproachChemistryISBN:9781305079243Author:Steven S. Zumdahl, Susan A. ZumdahlPublisher:Cengage Learning
Organic Chemistry: A Guided InquiryChemistryISBN:9780618974122Author:Andrei StraumanisPublisher:Cengage Learning
Organic Chemistry
Chemistry
ISBN:9781305580350
Author:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. Foote
Publisher:Cengage Learning
Chemistry: An Atoms First Approach
Chemistry
ISBN:9781305079243
Author:Steven S. Zumdahl, Susan A. Zumdahl
Publisher:Cengage Learning
Organic Chemistry: A Guided Inquiry
Chemistry
ISBN:9780618974122
Author:Andrei Straumanis
Publisher:Cengage Learning