Chemistry: Structure and Properties, Books a la Carte PACKAGE W/MasteringChemistry, 2nd Edition
2nd Edition
ISBN: 9780134777559
Author: Tro, Nivaldo J.
Publisher: PEARSON
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Textbook Question
Chapter 4, Problem 74E
Calculate the mass of each sample
- 15.7 mol HNO3
- 1.04 x 10-3 mol H2O2
- 72.1 mmol SO2
- 1.23 mol xenon difluoride
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Complete the following table. The only density needed is already given. Show your
calculations in a neat and easy-to-follow manner in the space below the table. All units
should be included and significant figures should be given close attention. Be sure to notice
that the amount of material should be in millimoles rather than moles, and the theoretical
mass of the product should in milligrams rather than grams.
LOCH 3
+
H2SO4
HNO 3
O=C-OCH 3
NO2
x
H₂O
F.W.
4.0 mL 1.3 M
amount
0.50 mL
in H2SO4
mg Theoretical
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mmoles
density
1.09
Kumada Coupling:
1. m-Diisobutylbenzene below could hypothetically be synthesized by Friedel-Crafts reaction. Write out the reaction with a
mechanism and give two reasons why you would NOT get the desired product.
Draw the reaction (NOT a mechanism) for a Kumada coupling to produce the molecule above from m-dichlorobenzene.
Calculate the theoretical yield for the reaction in question 2 using 1.5 g of p-dichlorobenzene and 3.0 mL isobutyl bromide.
What signals appeared/disappeared/shifted that indicate that you have your intended product and not starting material? What
other impurities are present in your product and how do you know?
Wintergreen from Aspirin:
1. In isolating the salicylic acid, why is it important to press out as much of the water as possible?
2. Write the mechanism of the esterification reaction you did.
3.
What characteristic absorption band changes would you expect in the IR spectrum on going from aspirin to salicyclic acid and
then to methyl salicylate as you did in the experiment today? Give approximate wavenumbers associated with each functional
group change.
What signals appeared/disappeared/shifted that indicate that you have your intended product and not starting material? What
other impurities are present in your product and how do you know?
Chapter 4 Solutions
Chemistry: Structure and Properties, Books a la Carte PACKAGE W/MasteringChemistry, 2nd Edition
Ch. 4 - How do the properties of compounds compare to the...Ch. 4 - What is a chemical bond? Why do chemical bonds...Ch. 4 - Explain the difference between an ionic bond and a...Ch. 4 - List and describe the different ways to represent...Ch. 4 - What is the difference between an empirical...Ch. 4 - Prob. 6ECh. 4 - Prob. 7ECh. 4 - Prob. 8ECh. 4 - How can you use Lewis structures to determine the...Ch. 4 - What is lattice energy?
Ch. 4 - Why is the formation of solid sodium chloride from...Ch. 4 - Prob. 12ECh. 4 - Prob. 13ECh. 4 - Prob. 14ECh. 4 - Prob. 15ECh. 4 - Prob. 16ECh. 4 - Prob. 17ECh. 4 - How does the Lewis model for covalent bonding...Ch. 4 - Explain howto nans molecular inorganic compounds.Ch. 4 - Prob. 20ECh. 4 - What is the formula mass for a compound? Why is it...Ch. 4 - Explain how the information in a chemical formula...Ch. 4 - What is mass percent composition? Why is it...Ch. 4 - Which kinds of conversion factors are inherent in...Ch. 4 - Which kind of chemical formula can be obtained...Ch. 4 - Prob. 26ECh. 4 - Prob. 27ECh. 4 - Prob. 28ECh. 4 - Prob. 29ECh. 4 - Prob. 30ECh. 4 - Prob. 31ECh. 4 - Determine the empirical formula for the compound...Ch. 4 - Determine the number of each type of atom in each...Ch. 4 - Determine the number of each type of atom in each...Ch. 4 - Write a chemical formula for each molecular model....Ch. 4 - Prob. 36ECh. 4 - Prob. 37ECh. 4 - Write an electron configuration for Ne. Then write...Ch. 4 - Prob. 39ECh. 4 - Write a Lewis symbol for each atom or ion. a. S2-...Ch. 4 - Prob. 41ECh. 4 - Write the Lewis symbols that represent the ions in...Ch. 4 - Prob. 43ECh. 4 - Prob. 44ECh. 4 - The lattice energy of CsF is -744 kJ/mol, whereas...Ch. 4 - Rubidium iodide has a lattice energy of-617...Ch. 4 - Prob. 47ECh. 4 - Prob. 48ECh. 4 - Prob. 49ECh. 4 - Prob. 50ECh. 4 - Prob. 51ECh. 4 - Prob. 52ECh. 4 - Prob. 53ECh. 4 - Prob. 54ECh. 4 - Prob. 55ECh. 4 - Prob. 56ECh. 4 - Prob. 57ECh. 4 - Prob. 58ECh. 4 - Prob. 59ECh. 4 - Prob. 60ECh. 4 - Use covalent Lewis structures to explain why each...Ch. 4 - Use covalent Lewis structures to explain why the...Ch. 4 - Prob. 63ECh. 4 - Prob. 64ECh. 4 - Prob. 65ECh. 4 - Prob. 66ECh. 4 - Name each compound. (Refer to the nomenclature...Ch. 4 - Prob. 68ECh. 4 - Prob. 69ECh. 4 - Prob. 70ECh. 4 - Calculate the formula mass for each compound. NO2...Ch. 4 - Prob. 72ECh. 4 - Calculate the number of moles in each sample 72.5...Ch. 4 - Calculate the mass of each sample 15.7 mol HNO3...Ch. 4 - Determine the number of moles (of molecules or...Ch. 4 - Determine the number of moles (of molecules or...Ch. 4 - How many molecules are in each sample? 6.5 g H2O...Ch. 4 - Prob. 78ECh. 4 - Calculate the mass (in g) of each sample. 5.94 x...Ch. 4 - Calculate the mass (in g) of each sample 4.5 x...Ch. 4 - A sugar crystal contains approximately 1.8 x 1017...Ch. 4 - A salt crystal has a mass of 0.12 mg. How many...Ch. 4 - Calculate the mass percent composition of carbon...Ch. 4 - Calculate the mass percent composition of nitrogen...Ch. 4 - Most fertilizers consist of nitrogen-containing...Ch. 4 - Iron in the earth is in the form of iron ore....Ch. 4 - Copper(ll) fluoride contains 37.42% F by mass....Ch. 4 - Silver chloride, often used in silver plating,...Ch. 4 - The iodide ion is a dietary mineral essential to...Ch. 4 - The American Dental Association recommends that an...Ch. 4 - Write a ratio showing the relationship between the...Ch. 4 - Write a ratio showing the relationship between the...Ch. 4 - Determine the number of moles of hydrogen atoms in...Ch. 4 - Determine the number of moles of oxygen atoms in...Ch. 4 - Calculate mass (in grams) of sodium in 8.5 g of...Ch. 4 - Calculate the mass (in kilograms) of chlorine in...Ch. 4 - A chemist decomposes samples of several compounds;...Ch. 4 - A chemist decomposes samples of several compounds;...Ch. 4 - Calculate the empirical formula for each stimulant...Ch. 4 - Calculate the empirical formula for each natural...Ch. 4 - The elemental mass percent composition of...Ch. 4 - The elemental mass percent composition of ascorbic...Ch. 4 - A 0.77-mg sample of nitrogen reacts with chlorine...Ch. 4 - A 45.2-mg sample of phosphorus reacts with...Ch. 4 - The empirical formula and molar mass of several...Ch. 4 - The malar mass and empirical formula of several...Ch. 4 - Combustion analysis of a hydrocarbon produced...Ch. 4 - Combustion analysis of naphthalene, a hydrocarbon...Ch. 4 - The foul odor of rancid butter is due largely to...Ch. 4 - Tartaric acid is the white, powdery substance that...Ch. 4 - Prob. 111ECh. 4 - Prob. 112ECh. 4 - Prob. 113ECh. 4 - Prob. 114ECh. 4 - How many molecules of ethanol (C2H5OH) (the...Ch. 4 - A drop of water has a volume of approximately 0.05...Ch. 4 - Determine the chemical formula of each compound...Ch. 4 - Determine the chemical formula of each compound...Ch. 4 - A Freon™ leak in the air conditioning system of an...Ch. 4 - Prob. 120ECh. 4 - A metal (M) forms a compound with the formula...Ch. 4 - A metal (M) forms an oxide with the formula M2O....Ch. 4 - Estradiol is a female sexual hormone that causes...Ch. 4 - Fructose is a common sugar found in fruit....Ch. 4 - Combustion analysis of a 13.42-g sample of equilin...Ch. 4 - Prob. 126ECh. 4 - Epsom salts is a hydrated ionic compound with the...Ch. 4 - A hydrate of copper(ll) chloride has the following...Ch. 4 - A compound of molar mass 177 g/mol contains only...Ch. 4 - Researchers obtain the following data from...Ch. 4 - Find the total number of atoms in a sample of...Ch. 4 - Vanadium forms four different oxides in which the...Ch. 4 - The chloride of an unknown metal is believed to...Ch. 4 - Prob. 134ECh. 4 - A chromium-containing compound has the formula...Ch. 4 - Prob. 136ECh. 4 - Prob. 137ECh. 4 - Prob. 138ECh. 4 - A mixture of NaCI and NaBr has a mass of 2.00 g...Ch. 4 - Three pure compounds form when 1.00-g samples of...Ch. 4 - A mixture of CaCO3 and (NH4)2CO3is 61.9% CO3 by...Ch. 4 - A mixture of 50.0 g of S and 1.00 x 102 g of CI2...Ch. 4 - Because of increasing evidence of damage to the...Ch. 4 - A particular coal contains 2.55% sulfur by mass....Ch. 4 - Lead is found in Earth’s crust as several...Ch. 4 - A 2.52-g sample of a compound containing only...Ch. 4 - Prob. 147ECh. 4 - The elements X and Y form a compound that is 40% X...Ch. 4 - A compound of X and Y is 13 X by mass. The atomic...Ch. 4 - A mixture of carbon and sulfur has a mass of 9.0...Ch. 4 - When molecules are represented by molecular...Ch. 4 - Prob. 152ECh. 4 - Explain the problem with this statement and...Ch. 4 - Without doing any calculations, arrange the...Ch. 4 - Prob. 155ECh. 4 - Prob. 156ECh. 4 - Prob. 157ECh. 4 - A compound isolated from the rind of lemons is...Ch. 4 - Prob. 159ECh. 4 - What is the empirical formula of the compound with...Ch. 4 - Which substance is an ionic compound? He N2O4 CCl4...Ch. 4 - Prob. 3SAQCh. 4 - Prob. 4SAQCh. 4 - Prob. 5SAQCh. 4 - Prob. 6SAQCh. 4 - Prob. 7SAQCh. 4 - What is the correct Lewis symbol for S?Ch. 4 - How many CH2Cl2 molecules are there in 25.0 g of...Ch. 4 - List the elements in the compound CF2Cl2 in order...Ch. 4 - Determine the mass of potassium in 35.5 g of KBr....Ch. 4 - A compound is 52.14% C, 13.13% H, and 34.73% O by...Ch. 4 - A compound has the empirical formula CH2O and a...Ch. 4 - Combustion of 30.42 g of a compound containing...
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