Chemistry For Today: General, Organic, And Biochemistry, Loose-leaf Version
9th Edition
ISBN: 9781305968707
Author: Spencer L. Seager
Publisher: Brooks Cole
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Question
Chapter 4, Problem 4.90E
Interpretation Introduction
Interpretation:
The formulas for the given compounds are to be stated. The characteristic of the polyatomic ions of the colored compounds that are not found in the white compounds is to be stated. The other polyatomic anions that would form colored compounds of potassium are to be predicted.
Concept introduction:
Ionic compounds are those compounds that have the strong electrostatic force of attraction between the oppositely charged ions. The positively charged ion is known as cation and negatively charged ion is called anion. Conventionally, the formula of the cation is written at left-hand side and formula of the anion is written at right-hand side while writing the formula of an ionic compound.
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Identify and provide an explanation of the operational principles behind a Atomic Absorption Spectrometer (AAS). List the steps involved.
Instructions: Complete the questions in the space provided. Show all your work
1. You are trying to determine the rate law expression for a reaction that you are completing at 25°C. You measure
the initial reaction rate and the starting concentrations of the reactions for 4 trials.
BrO³¯ (aq) + 5Br¯ (aq) + 6H* (aq) → 3Br₂ (l) + 3H2O (l)
Initial rate
Trial
[BrO3]
[H*]
[Br]
(mol/L)
(mol/L) | (mol/L)
(mol/L.s)
1
0.10
0.10
0.10
8.0
2
0.20
0.10
0.10
16
3
0.10
0.20
0.10
16
4
0.10
0.10
0.20
32
a.
Based on the above data what is the rate law expression?
b. Solve for the value of k (make sure to include proper units)
2. The proposed reaction mechanism is as follows:
i.
ii.
BrО¸¯ (aq) + H+ (aq) → HBrO3 (aq)
HBrO³ (aq) + H* (aq) → H₂BrO3* (aq)
iii.
H₂BrO³* (aq) + Br¯ (aq) → Br₂O₂ (aq) + H2O (l)
[Fast]
[Medium]
[Slow]
iv.
Br₂O₂ (aq) + 4H*(aq) + 4Br(aq) → 3Br₂ (l) + H2O (l)
[Fast]
Evaluate the validity of this proposed reaction. Justify your answer.
е.
Д
CH3
D*, D20
Chapter 4 Solutions
Chemistry For Today: General, Organic, And Biochemistry, Loose-leaf Version
Ch. 4 - Refer to the group numbers of the periodic table...Ch. 4 - Prob. 4.2ECh. 4 - Write abbreviated electronic configurations for...Ch. 4 - Write abbreviated electronic configurations for...Ch. 4 - Draw Lewis structure for the elements given in...Ch. 4 - Draw Lewis structures for the elements given in...Ch. 4 - Prob. 4.7ECh. 4 - Prob. 4.8ECh. 4 - Prob. 4.9ECh. 4 - Prob. 4.10E
Ch. 4 - Use the periodic table and predict the number of...Ch. 4 - Prob. 4.12ECh. 4 - Write a symbol for each of the following ions: a.A...Ch. 4 - Write a symbol for each of the following ions: a.A...Ch. 4 - Prob. 4.15ECh. 4 - Identify the element in period 3 that would form...Ch. 4 - Identify the noble gas that is isoelectronic with...Ch. 4 - Identify the noble gas that is isoelectronic with...Ch. 4 - Write equations to represent positive and negative...Ch. 4 - Prob. 4.20ECh. 4 - Write the formula for the ionic compound formed...Ch. 4 - Prob. 4.22ECh. 4 - Classify each of the following as a binary...Ch. 4 - Prob. 4.24ECh. 4 - Prob. 4.25ECh. 4 - Prob. 4.26ECh. 4 - Prob. 4.27ECh. 4 - Prob. 4.28ECh. 4 - Prob. 4.29ECh. 4 - Name the following binary ionic compounds: a. SrS...Ch. 4 - Name the following binary ionic compounds, using a...Ch. 4 - Name the following binary ionic compounds, using a...Ch. 4 - Prob. 4.33ECh. 4 - Prob. 4.34ECh. 4 - Prob. 4.35ECh. 4 - Write formulas for the following binary ionic...Ch. 4 - Prob. 4.37ECh. 4 - Prob. 4.38ECh. 4 - Identify the ions that would occupy lattice sites...Ch. 4 - Identify the ions that would occupy lattice sites...Ch. 4 - Calculate the mass in grams of positive ions and...Ch. 4 - Calculate the mass in grams of positive ions and...Ch. 4 - Prob. 4.43ECh. 4 - Prob. 4.44ECh. 4 - Represent the following reaction using Lewis...Ch. 4 - Prob. 4.46ECh. 4 - Prob. 4.47ECh. 4 - Represent the following molecules by Lewis...Ch. 4 - Draw Lewis structures for the following polyatomic...Ch. 4 - Prob. 4.50ECh. 4 - Prob. 4.51ECh. 4 - Prob. 4.52ECh. 4 - Predict the shape of each of the following...Ch. 4 - Prob. 4.54ECh. 4 - Prob. 4.55ECh. 4 - Prob. 4.56ECh. 4 - Use the periodic table and Table 4.4 to determine...Ch. 4 - Use Table 4.4 and classify the bonds in the...Ch. 4 - Use Table 4.4 and classify the bonds in the...Ch. 4 - Prob. 4.60ECh. 4 - On the basis of the charge distributions you drew...Ch. 4 - Prob. 4.62ECh. 4 - Prob. 4.63ECh. 4 - Prob. 4.64ECh. 4 - Show the charge distribution in the following...Ch. 4 - Prob. 4.66ECh. 4 - Prob. 4.67ECh. 4 - Prob. 4.68ECh. 4 - Prob. 4.69ECh. 4 - Prob. 4.70ECh. 4 - Prob. 4.71ECh. 4 - Prob. 4.72ECh. 4 - Prob. 4.73ECh. 4 - Prob. 4.74ECh. 4 - Prob. 4.75ECh. 4 - The covalent compounds ethyl alcohol and dimethyl...Ch. 4 - Prob. 4.77ECh. 4 - Prob. 4.78ECh. 4 - Prob. 4.79ECh. 4 - Prob. 4.80ECh. 4 - Prob. 4.81ECh. 4 - Prob. 4.82ECh. 4 - Suppose an element from group II(A)(2) and period...Ch. 4 - What would be the mass in grams of 0.200moles of...Ch. 4 - The ampere unit is used to describe the flow of...Ch. 4 - Prob. 4.86ECh. 4 - Prob. 4.87ECh. 4 - Prob. 4.88ECh. 4 - Prob. 4.89ECh. 4 - Prob. 4.90ECh. 4 - Prob. 4.91ECh. 4 - Prob. 4.92ECh. 4 - Prob. 4.93ECh. 4 - Prob. 4.94ECh. 4 - Prob. 4.95ECh. 4 - Noble gases: a.have low boiling points. b.are all...Ch. 4 - Prob. 4.97ECh. 4 - Name the type of bond that is formed when...Ch. 4 - Prob. 4.99ECh. 4 - A atom becomes an ion that possesses a negative...Ch. 4 - When calcium reacts with chlorine to form calcium...Ch. 4 - Prob. 4.102ECh. 4 - Prob. 4.103ECh. 4 - Which molecule below has a nonpolar bond in which...Ch. 4 - What is the correct formula for bismuth (III)...Ch. 4 - Which of the following species will combine with a...Ch. 4 - What type of bond is created when bromine and...Ch. 4 - The parts of an atom directly involved in ionic...Ch. 4 - In forming an ionic bond with an atom of chlorine,...Ch. 4 - In bonding, what would happen between the...Ch. 4 - Which compound contains a bond with no ionic...Ch. 4 - Prob. 4.112ECh. 4 - Which molecule is nonpolar and contains a nonpolar...Ch. 4 - Which of the following is a nonpolar covalent...Ch. 4 - Prob. 4.115ECh. 4 - Prob. 4.116E
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