ELEMENTARY PRINCIPLES OF CHEM. PROCESS.
4th Edition
ISBN: 9781119249214
Author: FELDER
Publisher: INTER WILE
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Textbook Question
Chapter 4, Problem 4.78P
Ethylene oxide is produced by the catalytic oxidation of ethylene:
2C2H4 + O2 —? 2C2H4O
An undesired competing reaction is the combustion of ethylene:
C2H4 + 302
2CO2 + 2H2O
The feed to the reactor (not the fresh feed to the process) contains 3 moles of ethylene per mole of oxygen. The single-pass conversion of ethylene is 20%, and for every 100 moles of ethylene consumed in the reactor, 90 moles of ethylene oxide emerge in the reactor products. A multiple-unit process is used to separate the products: ethylene and oxygen are recycled to the reactor, ethylene oxide is sold as a product, and carbon dioxide and water are discarded.
- Assume a quantity of the reactor feed stream as a basis of calculation, draw and label the flowchart, perform a degree-of-freedom analysis, and write the equations you would use to calculate (i) the molar flow rates of ethylene and oxygen in the fresh feed, (ii) the production rate of ethylene oxide, and (iii) the overall conversion of ethylene. Do no calculations.
- Calculate the quantities specified in Part (a), either manually or with an equation-solving program.
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Chapter 4 Solutions
ELEMENTARY PRINCIPLES OF CHEM. PROCESS.
Ch. 4 - Prob. 4.1PCh. 4 - Rain is falling on a poorly designed 150-m" flat...Ch. 4 - A liquid-phase chemical reaction A -* B takes...Ch. 4 - A stream consisting of 44.6 mole% benzene and...Ch. 4 - Prob. 4.5PCh. 4 - A liquid mixture of acetone and water contains 35...Ch. 4 - Prob. 4.7PCh. 4 - Prob. 4.8PCh. 4 - Inside a distillation column (see Problem 4.8), a...Ch. 4 - Prob. 4.10P
Ch. 4 - In the production of soybean oil, dried and flaked...Ch. 4 - Prob. 4.12PCh. 4 - A process is carried out in which a mixture...Ch. 4 - Strawberries contain about 15wt% solids and 85wt%...Ch. 4 - Two streams flow into a 500-gallon tank. The first...Ch. 4 - A fuel distributor supplies four liquid fuels,...Ch. 4 - Prob. 4.17PCh. 4 - One thousand kilograms per hour of a mixture...Ch. 4 - L-Serine is an amino acid that often is provided...Ch. 4 - A 100 kmol/h stream that is 97 mole% carbon...Ch. 4 - A pharmaceutical product, P, is made in a batch...Ch. 4 - A liquid mixture containing ethanol (55.0 wt%) and...Ch. 4 - A stream of humid air containing 1.50 mole% H2O(v)...Ch. 4 - A liquid mixture contains 60.0 wt% ethanol (E),...Ch. 4 - Certain vegetables and fruits contain plant...Ch. 4 - Two aqueous sulfuric acid solutions containing...Ch. 4 - A paint mixture containing 25.0% of a pigment and...Ch. 4 - In the commercial production of sugar (sucrose),...Ch. 4 - Prob. 4.29PCh. 4 - A garment to protect the wearer from toxic agents...Ch. 4 - A dilute aqueous solution of H2SO4 (Solution A) is...Ch. 4 - Gas streams containing hydrogen and nitrogen in...Ch. 4 - An artificial kidney is a device that removes...Ch. 4 - The indicator-dilution method is a technique used...Ch. 4 - Prob. 4.35PCh. 4 - Gas absorption or gas scrubbing is a commonly used...Ch. 4 - The SO2 scrubbing tower described in Problem 4.36...Ch. 4 - Prob. 4.38PCh. 4 - The hormone estrogen is produced in the ovaries of...Ch. 4 - A liquid mixture containing 30.0mole% benzene (B),...Ch. 4 - Seawater containing 3.50 wt% salt passes through a...Ch. 4 - Inside the column a liquid stream flows downward...Ch. 4 - Prob. 4.43PCh. 4 - Effluents from metal-finishing plants have the...Ch. 4 - In an absorption tower (or absorber), a gas is...Ch. 4 - In the production of a bean oil, beans containing...Ch. 4 - Boilers are used in most chemical plants to...Ch. 4 - Following is a diagram of the shirt-cleaning...Ch. 4 - A drug (D) is produced in a three-stage extraction...Ch. 4 - Prob. 4.52PCh. 4 - Ammonia is oxidized to nitric oxide in the...Ch. 4 - Prob. 4.54PCh. 4 - A stream containing H2S and inert gases and a...Ch. 4 - 436. The reaction between ethylene and hydrogen...Ch. 4 - Prob. 4.57PCh. 4 - Prob. 4.58PCh. 4 - Titanium dioxide (TiCb) is used extensively as a...Ch. 4 - Prob. 4.60PCh. 4 - Prob. 4.61PCh. 4 - Oxygen consumed by a living organism in aerobic...Ch. 4 - A genetically engineered strain of Escherichia...Ch. 4 - The gas-phase reaction between methanol and acetic...Ch. 4 - Prob. 4.65PCh. 4 - Prob. 4.66PCh. 4 - Methane and oxygen react in the presence of a...Ch. 4 - Ethane is chlorinated in a continuous reactor:...Ch. 4 - Ethanol can be produced commercially by the...Ch. 4 - Prob. 4.70PCh. 4 - Solid calcium fluoride (CaF2) reacts with sulfuric...Ch. 4 - Prob. 4.72PCh. 4 - Chlorobenzene (C^HsCl), an important solvent and...Ch. 4 - A catalytic reactor is used to produce...Ch. 4 - 4.7'6. Methanol is produced by reacting carbon...Ch. 4 - Methane reacts with chlorine to produce methyl...Ch. 4 - Ethylene oxide is produced by the catalytic...Ch. 4 - Methanol is synthesized from carbon monoxide and...Ch. 4 - The fresh feed to an ammonia production process...Ch. 4 - A gas contains 75.0 wt% methane. 10.0% ethane....Ch. 4 - Five liters of liquid n-hexane and 4 liters of...Ch. 4 - Gasoline, which we will represent as having the...Ch. 4 - Prob. 4.87PCh. 4 - Natural gas containing a mixture of methane,...Ch. 4 - Propane is burned completely with excess oxygen....Ch. 4 - Prob. 4.91PCh. 4 - Prob. 4.92PCh. 4 - Liquid methanol is fed to a space heater at a rate...Ch. 4 - Prob. 4.94PCh. 4 - Prob. 4.95PCh. 4 - A fuel oil is analyzed and found to contain 85.0...Ch. 4 - Prob. 4.97PCh. 4 - Prob. 4.98PCh. 4 - Prob. 4.99PCh. 4 - 4.1 (Mt. You have been sent by the Environmental...Ch. 4 - Fuel oils contain primarily organic compounds and...
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