(a)
Interpretation:
It should be determined that how many independent material balance may be written for this system.
Concept introduction:
The independent material balance is when the stoichiometric equation of anyone of them can not be obtained by adding or subtracting multiples of the stoichiometric equation of the others.
The material balances are non independent; if two molecular species are in same ratio to each other wherever they appear and if two atomic species are in same ratio to each other wherever they occur.
(b)
Interpretation:
Calculate
Concept introduction:
In order to understand different variables and components of a system, the analysis of degree of freedom can work better. If the degree of freedom is zero then the problem is specified.
The degree of freedom is explained as:
Where, m is total number of independent stream variables, n is number of independent balances, p is total number of specified terms and s is total number of subsidiary relation.
(c)
Interpretation:
Calculate the difference between amount of acetic acid in the feed mixture and that in the 0.5% mixture and show that it equals the amount that leaves in the 9.6% mixture.
Concept introduction:
In any system, for any conserved quantity like total mass, mass of particular species, momentum, energy etc. the balance can be expressed as follows:
Where, input is feed that enters through system boundary, generation is the content produced within system, output is the content which leaves the system and consumption is the feed consumed within the system while accumulation is the actual product build up in the system.
(d)
Interpretation:
Sketch a flow chart of a two-unit process that might be used to recover nearly pure acetic acid from an acetic acid-water mixture.
Concept introduction:
Actually, when a few process information is given and the calculation is to be done on the basis of the information, then in such conditions, flowchart creation is the best way to deal with. It is formed with the help of boxes and arrows to show the process and outline the process units. The arrow lines can show inputs and outputs which help in better understanding of the process.
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Chapter 4 Solutions
ELEMENTARY PRINCIPLES OF CHEM. PROCESS.
- #3 A irreversible isothermal liquid-phase reaction is given as: A → B is conducted in continuous flow systems. The rate of reaction is determined as a function of the conversion of reactant A and the results are given below. The temperature was constant at 500K. The entering molar flow rate of A is 0.4 mol/min. a) If this reaction is conducted in two CSTRS in series. Calculate the required reactor volume of each CSTRS if conversion X₁ = 0.4 and conversion X2 = 0.8. b) If this reaction is conducted in two PFRS in series. Calculate the required reactor volume of each PFRS if conversion X₁ = 0.4 and conversion X2 = 0.8. c) If this reaction is conducted in a PFR followed by a CSTR. Calculate the required reactor volume of PFR if conversion X₁ = 0.4 and of CSTR if conversion X2 = 0.8. X -A (mol/L.min) 0 0.1 0.2 0.4 0.6 0.7 0.8 0.45 0.37 0.3 0.195 0.113 0.079 0.05arrow_forward#2 An exothermic reaction, AB + C, was carried out adiabatically in a PFR or a CSTR and the following data was recorded. The entering molar flow rate of A was 300 mol/min. Calculate the necessary i) PFR volume and ii) CSTR volume to achieve 40% conversion. X 0 0.2 0.4 0.45 0.5 0.6 0.8 0.9 -TA (mol/L-min) 1 1.67 5 5 5 5 1.25 0.91arrow_forwardQuestion: McDaniel Shipyards wants to develop control charts to assess the quality of its steel plate. They... McDaniel Shipyards wants to develop control charts to assess the quality of its steel plate. They take ten sheets of 1" steel plate and compute the number of cosmetic flaws on each roll. Each sheet is 20' by 100'. Compute within 99.73% control limits. Based on the following data: a. Develop limits for the control chart b. Is the process in or out of control? c. Can you detect any outliers, if so which value(s)? Number of Sheet flaws 1 1 2 1 3 2 4 0 5 1 6 5 7 0 8 2 9 0 10 2arrow_forward
- Question: McDaniel Shipyards wants to develop control charts to assess the quality of its steel plate. They take ten sheets of 1" steel plate and compute the number of cosmetic flaws on eac... McDaniel Shipyards wants to develop control charts to assess the quality of its steel plate. They take ten sheets of 1" steel plate and compute the number of cosmetic flaws on each roll. Each sheet is 20' by 100'. Based on the following data, develop limits for the control chart, plot the control chart, and determine whether the process is in control. Answer the following questions below. Number of flaws Sheet 1 1 2 1 = 3 2 4 0 5 1 6 5 7 0 8 2 9 10 0 2 PLEASE WRTIE NEATLY AND EXPLAIN! (: Thanks 1. Calculate the standard deviation of control chart. (a) the standard deviation = 1.0832 (b) the standard deviation = 1.1832 (c) the standard deviation = 1.4 (d) the standard deviation = 1.04 27. 2. Using +- 3 olimits, calculate the LCL and UCL for these data. 3.549; LCL = -3.549 (a) UCL (b) UCL 3.549;…arrow_forwardDerive an expression for incompressible flow in a horizontal pipe of constant diameter andwithout fittings or valves which shows that the pressure is a linear function of pipe length. Whatother assumptions are required for this result? Is this result valid for non-horizontal pipes? Howwill the presence of fittings, valves and other hardware affect this result?arrow_forwardEthylene glycol liquid is used as an antifreeze in many applications. If it is stored in a vessel at a pressure of at 150 psig flows through a ¾ inch-diameter hole to atmospheric pressure. Estimate the discharge rate if the ambient pressure is 1 atm. For ethylene glycol at 77°F, the specific gravity is 1.15 and the viscosity is 25 cP. The molecular weight is 62.07.arrow_forward
- Please help me with parts A through Darrow_forwardA semi-truck tire is inflated to 110 psig with nitrogen. What will be the initial gas discharge ratein lbm/s due to a 1/16-inch diameter hole? Assume at temperature of 80℉ and an ambientpressure of 1 atm.arrow_forward# 4 The reaction, AB, is to be carried out isothermally in a continuous flow reactor. The entering volumetric flow rate, vo is 10 L/h and is constant (v=vo). Calculate both the CSTR and PFR volumes necessary to reduce the entering concentration of species A from CAD to CA = 0.01 CAO when the entering molar flow rate of species A is 5 mol/h. (a) This reaction is a second order reaction. The reaction rate constant, k is given as 300 L/mol.h. (b) This reaction is a zeroth order reaction. The reaction rate constant, k is given as 0.05 mol/h.L.arrow_forward
- #3 Using the initial rates method and the given experimental data below to determine the rate law and the value of the rate constant for the reaction, as shown below. All trials are performed at the same temperature. 2NO + Cl2 → 2NCOCI Trial [NO] (mol/L) [Cl₂] (mol/L) Initial rates (mol/L.s) 1 0.10 0.10 0.00300 2 0.10 0.15 0.00450 3 0.15 0.10 0.00675arrow_forward#2 The reaction rate constant at temperature, T₁, is 15 mol/L-s while at the reaction rate constant changed to 7 mol/L-s when temperature changed to T2 at 398 K. What is T₁? Given the activation energy is 600 kJ/mol. Assume at this temperature interval, pre-exponential factor and activation energy are constant.arrow_forward#1 Chloral is consumed at a rate of 10 mol/L-s when reacting with chlorobenzene to form DDT and water in the reaction given below. Determine: i) the rate of disappearance of chlorobenzene. ii) the rate of formation of DDT. CCI CHO (Chloral) + 2C6H5Cl (Chlorobenzene) → (C6H4Cl)2CHCCI 3 (DDT) + H2Oarrow_forward
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