
ELEM.PRIN.OF CHEMICAL PROC.-W/ACCESS
4th Edition
ISBN: 9781119330745
Author: FELDER
Publisher: WILEY
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Chapter 4, Problem 4.70P
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Acreage of farmland required for the production of
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In the production of ethyl acetate via reactive distillation, the column operates at 5 bar with an equimolar feed (ethanol + acetic acid) at 80°C. The reaction follows: \[CH_3COOH + C_2H_5OH \rightleftharpoons CH_3COOC_2H_5 + H_2O \quad (K_{eq} = 4.2 \text{ at } 80°C)\] Given: - NRTL parameters for all binary pairs - Tray efficiency = 65% - Vapor-liquid equilibrium exhibits positive azeotrope formation Calculate the exact minimum reflux ratio required to achieve 98% ethyl acetate purity in the distillate, assuming: 1) The reaction reaches equilibrium on each tray 2) The heavy key component is water
In a multi-stage distillation column designed to separate a binary mixture of ethanol and water, the mass flow rate of the feed entering the column is \( F \), and the distillate product flow rate is \( D \). The reflux ratio \( R \) is defined as the ratio of the liquid returned to the column to the distillate flow rate. For the ideal case, where the column operates at maximum efficiency, determine the **minimum reflux ratio** \( R_{\text{min}} \) when the relative volatility \( \alpha = 1.5 \).
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Chapter 4 Solutions
ELEM.PRIN.OF CHEMICAL PROC.-W/ACCESS
Ch. 4 - Prob. 4.1PCh. 4 - Rain is falling on a poorly designed 150-m" flat...Ch. 4 - A liquid-phase chemical reaction A -* B takes...Ch. 4 - A stream consisting of 44.6 mole% benzene and...Ch. 4 - Prob. 4.5PCh. 4 - A liquid mixture of acetone and water contains 35...Ch. 4 - Prob. 4.7PCh. 4 - Prob. 4.8PCh. 4 - Inside a distillation column (see Problem 4.8), a...Ch. 4 - Prob. 4.10P
Ch. 4 - In the production of soybean oil, dried and flaked...Ch. 4 - Prob. 4.12PCh. 4 - A process is carried out in which a mixture...Ch. 4 - Strawberries contain about 15wt% solids and 85wt%...Ch. 4 - Two streams flow into a 500-gallon tank. The first...Ch. 4 - A fuel distributor supplies four liquid fuels,...Ch. 4 - Prob. 4.17PCh. 4 - One thousand kilograms per hour of a mixture...Ch. 4 - L-Serine is an amino acid that often is provided...Ch. 4 - A 100 kmol/h stream that is 97 mole% carbon...Ch. 4 - A pharmaceutical product, P, is made in a batch...Ch. 4 - A liquid mixture containing ethanol (55.0 wt%) and...Ch. 4 - A stream of humid air containing 1.50 mole% H2O(v)...Ch. 4 - A liquid mixture contains 60.0 wt% ethanol (E),...Ch. 4 - Certain vegetables and fruits contain plant...Ch. 4 - Two aqueous sulfuric acid solutions containing...Ch. 4 - A paint mixture containing 25.0% of a pigment and...Ch. 4 - In the commercial production of sugar (sucrose),...Ch. 4 - Prob. 4.29PCh. 4 - A garment to protect the wearer from toxic agents...Ch. 4 - A dilute aqueous solution of H2SO4 (Solution A) is...Ch. 4 - Gas streams containing hydrogen and nitrogen in...Ch. 4 - An artificial kidney is a device that removes...Ch. 4 - The indicator-dilution method is a technique used...Ch. 4 - Prob. 4.35PCh. 4 - Gas absorption or gas scrubbing is a commonly used...Ch. 4 - The SO2 scrubbing tower described in Problem 4.36...Ch. 4 - Prob. 4.38PCh. 4 - The hormone estrogen is produced in the ovaries of...Ch. 4 - A liquid mixture containing 30.0mole% benzene (B),...Ch. 4 - Seawater containing 3.50 wt% salt passes through a...Ch. 4 - Inside the column a liquid stream flows downward...Ch. 4 - Prob. 4.43PCh. 4 - Effluents from metal-finishing plants have the...Ch. 4 - In an absorption tower (or absorber), a gas is...Ch. 4 - In the production of a bean oil, beans containing...Ch. 4 - Boilers are used in most chemical plants to...Ch. 4 - Following is a diagram of the shirt-cleaning...Ch. 4 - A drug (D) is produced in a three-stage extraction...Ch. 4 - Prob. 4.52PCh. 4 - Ammonia is oxidized to nitric oxide in the...Ch. 4 - Prob. 4.54PCh. 4 - A stream containing H2S and inert gases and a...Ch. 4 - 436. The reaction between ethylene and hydrogen...Ch. 4 - Prob. 4.57PCh. 4 - Prob. 4.58PCh. 4 - Titanium dioxide (TiCb) is used extensively as a...Ch. 4 - Prob. 4.60PCh. 4 - Prob. 4.61PCh. 4 - Oxygen consumed by a living organism in aerobic...Ch. 4 - A genetically engineered strain of Escherichia...Ch. 4 - The gas-phase reaction between methanol and acetic...Ch. 4 - Prob. 4.65PCh. 4 - Prob. 4.66PCh. 4 - Methane and oxygen react in the presence of a...Ch. 4 - Ethane is chlorinated in a continuous reactor:...Ch. 4 - Ethanol can be produced commercially by the...Ch. 4 - Prob. 4.70PCh. 4 - Solid calcium fluoride (CaF2) reacts with sulfuric...Ch. 4 - Prob. 4.72PCh. 4 - Chlorobenzene (C^HsCl), an important solvent and...Ch. 4 - A catalytic reactor is used to produce...Ch. 4 - 4.7'6. Methanol is produced by reacting carbon...Ch. 4 - Methane reacts with chlorine to produce methyl...Ch. 4 - Ethylene oxide is produced by the catalytic...Ch. 4 - Methanol is synthesized from carbon monoxide and...Ch. 4 - The fresh feed to an ammonia production process...Ch. 4 - A gas contains 75.0 wt% methane. 10.0% ethane....Ch. 4 - Five liters of liquid n-hexane and 4 liters of...Ch. 4 - Gasoline, which we will represent as having the...Ch. 4 - Prob. 4.87PCh. 4 - Natural gas containing a mixture of methane,...Ch. 4 - Propane is burned completely with excess oxygen....Ch. 4 - Prob. 4.91PCh. 4 - Prob. 4.92PCh. 4 - Liquid methanol is fed to a space heater at a rate...Ch. 4 - Prob. 4.94PCh. 4 - Prob. 4.95PCh. 4 - A fuel oil is analyzed and found to contain 85.0...Ch. 4 - Prob. 4.97PCh. 4 - Prob. 4.98PCh. 4 - Prob. 4.99PCh. 4 - 4.1 (Mt. You have been sent by the Environmental...Ch. 4 - Fuel oils contain primarily organic compounds and...
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- A distillation column with 100 kmol/h feed of 50% A and 50% B produces a distillate product with xD = 0.95 and a bottom stream with xbot = 0.04 of the more volatile species A. CMO is valid and the equilibrium data is given by y = 2.4x/1 + 1.4x a) If the feed is saturated liquid, determine the minimum reflux ratio b) If the feed is saturated vapor, determine the minimum reflux ratioarrow_forwardA distillation column with 100 kmol/h feed of 60% A and 40% B produces a distillate product with xD = 0.98 and a bottom stream with xbot = 0.02 of the more volatile species A. CMO is valid and the equilibrium data is given by y = 2.2x/1+1.2x a) If the reflux ratio R is 2, determine (numerically) the composition (y) of the vapor stream entering the top equilibrium plate.__________b) If R = 2 and q = 0.6, determine the liquid flow rate in the stripping section of the column__________c) If q = 0, the minimum reflux ratio isarrow_forwardNatural gas having a specific gravity relative to air of 0.60 and a viscosity of 0.011 cP is flowing through a 6-in. Schedule 40 pipe in which is installed a standard sharp-edged orifice equipped with flange taps. The gas is at 100°F and 20lb/in? abs at the upstream tap. The manometer reading is 46.3 in. of water at 60°F. The ratio of specific heats for natural gas is 1.30. The diameter of the orifice is 2.00 in. Calculate the rate of flow of gas through the line in cubic feet.arrow_forward
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