Bundle: Chemistry for Today: General, Organic, and Biochemistry, Loose-Leaf Version, 9th + LMS Integrated OWLv2, 4 terms (24 months) Printed Access Card
9th Edition
ISBN: 9781337598255
Author: Spencer L. Seager
Publisher: Cengage Learning
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Textbook Question
Chapter 4, Problem 4.61E
On the basis of the charge distributions you drew for the molecules of Exercise 4.57, classify each of the molecules as polar or nonpolar.
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Students have asked these similar questions
Wintergreen from Aspirin:
1. In isolating the salicylic acid, why is it important to press out as much of the water as possible?
2. Write the mechanism of the esterification reaction you did.
3.
What characteristic absorption band changes would you expect in the IR spectrum on going from aspirin to salicyclic acid and
then to methyl salicylate as you did in the experiment today? Give approximate wavenumbers associated with each functional
group change.
What signals appeared/disappeared/shifted that indicate that you have your intended product and not starting material? What
other impurities are present in your product and how do you know?
Synthesis of ZybanⓇ:
1. Write a mechanism for the bromination of m-chloropropiophenone.
Br₂
CH2Cl2
Cl
Br
2. Give the expected m/z (to a round number) for the molecular ion from the product above (including isotopic peaks).
3. What signals appeared/disappeared/shifted that indicate that you have your intended product and not starting material? What
other impurities are present in your product and how do you know?
Synthesis of Ibuprofen-Part 2:
1. Some pain relievers including ibuprofen (MotrinⓇ) and naproxen (Aleve®) are "α-arylpropanoic acids." Look up the structure
of naproxen (AleveⓇ), another a-arylpropionic acid. Using the same reactions that we used for making ibuprofen, show how
to make naproxen from the compound below. Show all intermediates and reagents in your synthesis.
Show how you would prepare ibuprofen starting from p-isobutylbenzene rather than p-isobutylacetophenenone. What reaction
steps would need to change/add?
3. What signals appeared/disappeared/shifted that indicate that you have your intended product and not starting material? What
other impurities are present in your product and how do you know?
Chapter 4 Solutions
Bundle: Chemistry for Today: General, Organic, and Biochemistry, Loose-Leaf Version, 9th + LMS Integrated OWLv2, 4 terms (24 months) Printed Access Card
Ch. 4 - Refer to the group numbers of the periodic table...Ch. 4 - Prob. 4.2ECh. 4 - Write abbreviated electronic configurations for...Ch. 4 - Write abbreviated electronic configurations for...Ch. 4 - Draw Lewis structure for the elements given in...Ch. 4 - Draw Lewis structures for the elements given in...Ch. 4 - Prob. 4.7ECh. 4 - Prob. 4.8ECh. 4 - Prob. 4.9ECh. 4 - Prob. 4.10E
Ch. 4 - Use the periodic table and predict the number of...Ch. 4 - Prob. 4.12ECh. 4 - Write a symbol for each of the following ions: a.A...Ch. 4 - Write a symbol for each of the following ions: a.A...Ch. 4 - Prob. 4.15ECh. 4 - Identify the element in period 3 that would form...Ch. 4 - Identify the noble gas that is isoelectronic with...Ch. 4 - Identify the noble gas that is isoelectronic with...Ch. 4 - Write equations to represent positive and negative...Ch. 4 - Prob. 4.20ECh. 4 - Write the formula for the ionic compound formed...Ch. 4 - Prob. 4.22ECh. 4 - Classify each of the following as a binary...Ch. 4 - Prob. 4.24ECh. 4 - Prob. 4.25ECh. 4 - Prob. 4.26ECh. 4 - Prob. 4.27ECh. 4 - Prob. 4.28ECh. 4 - Prob. 4.29ECh. 4 - Name the following binary ionic compounds: a. SrS...Ch. 4 - Name the following binary ionic compounds, using a...Ch. 4 - Name the following binary ionic compounds, using a...Ch. 4 - Prob. 4.33ECh. 4 - Prob. 4.34ECh. 4 - Prob. 4.35ECh. 4 - Write formulas for the following binary ionic...Ch. 4 - Prob. 4.37ECh. 4 - Prob. 4.38ECh. 4 - Identify the ions that would occupy lattice sites...Ch. 4 - Identify the ions that would occupy lattice sites...Ch. 4 - Calculate the mass in grams of positive ions and...Ch. 4 - Calculate the mass in grams of positive ions and...Ch. 4 - Prob. 4.43ECh. 4 - Prob. 4.44ECh. 4 - Represent the following reaction using Lewis...Ch. 4 - Prob. 4.46ECh. 4 - Prob. 4.47ECh. 4 - Represent the following molecules by Lewis...Ch. 4 - Draw Lewis structures for the following polyatomic...Ch. 4 - Prob. 4.50ECh. 4 - Prob. 4.51ECh. 4 - Prob. 4.52ECh. 4 - Predict the shape of each of the following...Ch. 4 - Prob. 4.54ECh. 4 - Prob. 4.55ECh. 4 - Prob. 4.56ECh. 4 - Use the periodic table and Table 4.4 to determine...Ch. 4 - Use Table 4.4 and classify the bonds in the...Ch. 4 - Use Table 4.4 and classify the bonds in the...Ch. 4 - Prob. 4.60ECh. 4 - On the basis of the charge distributions you drew...Ch. 4 - Prob. 4.62ECh. 4 - Prob. 4.63ECh. 4 - Prob. 4.64ECh. 4 - Show the charge distribution in the following...Ch. 4 - Prob. 4.66ECh. 4 - Prob. 4.67ECh. 4 - Prob. 4.68ECh. 4 - Prob. 4.69ECh. 4 - Prob. 4.70ECh. 4 - Prob. 4.71ECh. 4 - Prob. 4.72ECh. 4 - Prob. 4.73ECh. 4 - Prob. 4.74ECh. 4 - Prob. 4.75ECh. 4 - The covalent compounds ethyl alcohol and dimethyl...Ch. 4 - Prob. 4.77ECh. 4 - Prob. 4.78ECh. 4 - Prob. 4.79ECh. 4 - Prob. 4.80ECh. 4 - Prob. 4.81ECh. 4 - Prob. 4.82ECh. 4 - Suppose an element from group II(A)(2) and period...Ch. 4 - What would be the mass in grams of 0.200moles of...Ch. 4 - The ampere unit is used to describe the flow of...Ch. 4 - Prob. 4.86ECh. 4 - Prob. 4.87ECh. 4 - Prob. 4.88ECh. 4 - Prob. 4.89ECh. 4 - Prob. 4.90ECh. 4 - Prob. 4.91ECh. 4 - Prob. 4.92ECh. 4 - Prob. 4.93ECh. 4 - Prob. 4.94ECh. 4 - Prob. 4.95ECh. 4 - Noble gases: a.have low boiling points. b.are all...Ch. 4 - Prob. 4.97ECh. 4 - Name the type of bond that is formed when...Ch. 4 - Prob. 4.99ECh. 4 - A atom becomes an ion that possesses a negative...Ch. 4 - When calcium reacts with chlorine to form calcium...Ch. 4 - Prob. 4.102ECh. 4 - Prob. 4.103ECh. 4 - Which molecule below has a nonpolar bond in which...Ch. 4 - What is the correct formula for bismuth (III)...Ch. 4 - Which of the following species will combine with a...Ch. 4 - What type of bond is created when bromine and...Ch. 4 - The parts of an atom directly involved in ionic...Ch. 4 - In forming an ionic bond with an atom of chlorine,...Ch. 4 - In bonding, what would happen between the...Ch. 4 - Which compound contains a bond with no ionic...Ch. 4 - Prob. 4.112ECh. 4 - Which molecule is nonpolar and contains a nonpolar...Ch. 4 - Which of the following is a nonpolar covalent...Ch. 4 - Prob. 4.115ECh. 4 - Prob. 4.116E
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