(a) Interpretation: The name of the given compound is to be stated. Concept introduction: The systematic naming of organic compound is given by IUPAC nomenclature . The naming of organic compound is done such that the organic compound structure is correctly interpreted from the name. Rules for writing IUPAC name from structural formula are: 1. First identify the longest carbon chain. 2. Then identify the functional groups attached to the longest chain. 3. Identify the position, location, and number of the substituent bonded to the carbon chain. 4. Use prefix di, tri, tetra if similar type of substituent is present.

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Answer 1

Question

Chapter 4, Problem 4.5P

Interpretation Introduction

(a)

Interpretation:

The name of the given compound is to be stated.

Concept introduction:

The systematic naming of organic compound is given by IUPAC nomenclature. The naming of organic compound is done such that the organic compound structure is correctly interpreted from the name.

Rules for writing IUPAC name from structural formula are:

1. First identify the longest carbon chain.

2. Then identify the functional groups attached to the longest chain.

3. Identify the position, location, and number of the substituent bonded to the carbon chain.

4. Use prefix di, tri, tetra if similar type of substituent is present.

Interpretation Introduction

(b)

Interpretation:

The name of the given compound is to be stated.

Concept introduction:

The systematic naming of organic compound is given by IUPAC nomenclature. The naming of organic compound is done such that the organic compound structure is correctly interpreted from the name.

Rules for writing IUPAC name from structural formula are:

1. First identify the longest carbon chain.

2. Then identify the functional groups attached to the longest chain.

3. Identify the position, location, and number of the substituent bonded to the carbon chain.

4. Use prefix di, tri, tetra if similar type of substituent is present.

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(a) Write the structures of the following compounds and mark them as chiral or achiral. 4 (i) 2-Bromopentane (ii) 3-Bromopentane (iii) 1-Bromo-2-methylbutane (iv) 2-Chloro-3-methylbutane (b) Identify the asymmetric carbon in the chiral compounds. (c) Write the structure of the other enantiomer of the chiral compounds.

5.76 2,3-Dibromoprop-1-ene (C3H4Br₂) has four H atoms. Suppose that any of these H atoms can be replaced by a Cl atom to yield a molecule with the formula C3H3Br₂Cl. (a) Identify two H atoms where this substitution would yield constitutional isomers of C3H3Br₂Cl; (b) enantiomers of C3H3Br₂Cl; (c) diastereomers of C3H3Br₂Cl. co 11 HHH Juods H Brugtrio 2 bas A 2,3-Dil so ontemme A chon Br 2,3-Dibromoprop-1-ene

If either of the following molecules has a stereogenic carbon (chirality center), give structures for both of the enantiomers. (a) 2-bromopropane (b) 2-bromobutane

Answer 2

Question

Chapter 4, Problem 4.5P

Interpretation Introduction

(a)

Interpretation:

The name of the given compound is to be stated.

Concept introduction:

The systematic naming of organic compound is given by IUPAC nomenclature. The naming of organic compound is done such that the organic compound structure is correctly interpreted from the name.

Rules for writing IUPAC name from structural formula are:

1. First identify the longest carbon chain.

2. Then identify the functional groups attached to the longest chain.

3. Identify the position, location, and number of the substituent bonded to the carbon chain.

4. Use prefix di, tri, tetra if similar type of substituent is present.

Interpretation Introduction

(b)

Interpretation:

The name of the given compound is to be stated.

Concept introduction:

The systematic naming of organic compound is given by IUPAC nomenclature. The naming of organic compound is done such that the organic compound structure is correctly interpreted from the name.

Rules for writing IUPAC name from structural formula are:

1. First identify the longest carbon chain.

2. Then identify the functional groups attached to the longest chain.

3. Identify the position, location, and number of the substituent bonded to the carbon chain.

4. Use prefix di, tri, tetra if similar type of substituent is present.

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Answer 3

Question

Chapter 4, Problem 4.5P

Interpretation Introduction

(a)

Interpretation:

The name of the given compound is to be stated.

Concept introduction:

The systematic naming of organic compound is given by IUPAC nomenclature. The naming of organic compound is done such that the organic compound structure is correctly interpreted from the name.

Rules for writing IUPAC name from structural formula are:

1. First identify the longest carbon chain.

2. Then identify the functional groups attached to the longest chain.

3. Identify the position, location, and number of the substituent bonded to the carbon chain.

4. Use prefix di, tri, tetra if similar type of substituent is present.

Interpretation Introduction

(b)

Interpretation:

The name of the given compound is to be stated.

Concept introduction:

The systematic naming of organic compound is given by IUPAC nomenclature. The naming of organic compound is done such that the organic compound structure is correctly interpreted from the name.

Rules for writing IUPAC name from structural formula are:

1. First identify the longest carbon chain.

2. Then identify the functional groups attached to the longest chain.

3. Identify the position, location, and number of the substituent bonded to the carbon chain.

4. Use prefix di, tri, tetra if similar type of substituent is present.

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Answer 4

Question

Chapter 4, Problem 4.5P

Interpretation Introduction

(a)

Interpretation:

The name of the given compound is to be stated.

Concept introduction:

The systematic naming of organic compound is given by IUPAC nomenclature. The naming of organic compound is done such that the organic compound structure is correctly interpreted from the name.

Rules for writing IUPAC name from structural formula are:

1. First identify the longest carbon chain.

2. Then identify the functional groups attached to the longest chain.

3. Identify the position, location, and number of the substituent bonded to the carbon chain.

4. Use prefix di, tri, tetra if similar type of substituent is present.

Interpretation Introduction

(b)

Interpretation:

The name of the given compound is to be stated.

Concept introduction:

The systematic naming of organic compound is given by IUPAC nomenclature. The naming of organic compound is done such that the organic compound structure is correctly interpreted from the name.

Rules for writing IUPAC name from structural formula are:

1. First identify the longest carbon chain.

2. Then identify the functional groups attached to the longest chain.

3. Identify the position, location, and number of the substituent bonded to the carbon chain.

4. Use prefix di, tri, tetra if similar type of substituent is present.

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Answer 5

Chapter 4, Problem 4.5P

Interpretation Introduction

(a)

Interpretation:

The name of the given compound is to be stated.

Concept introduction:

The systematic naming of organic compound is given by IUPAC nomenclature. The naming of organic compound is done such that the organic compound structure is correctly interpreted from the name.

Rules for writing IUPAC name from structural formula are:

1. First identify the longest carbon chain.

2. Then identify the functional groups attached to the longest chain.

3. Identify the position, location, and number of the substituent bonded to the carbon chain.

4. Use prefix di, tri, tetra if similar type of substituent is present.

Interpretation Introduction

(b)

Interpretation:

The name of the given compound is to be stated.

Concept introduction:

The systematic naming of organic compound is given by IUPAC nomenclature. The naming of organic compound is done such that the organic compound structure is correctly interpreted from the name.

Rules for writing IUPAC name from structural formula are:

1. First identify the longest carbon chain.

2. Then identify the functional groups attached to the longest chain.

3. Identify the position, location, and number of the substituent bonded to the carbon chain.

4. Use prefix di, tri, tetra if similar type of substituent is present.

Answer 6

Chapter 4, Problem 4.5P

Interpretation Introduction

(a)

Interpretation:

The name of the given compound is to be stated.

Concept introduction:

The systematic naming of organic compound is given by IUPAC nomenclature. The naming of organic compound is done such that the organic compound structure is correctly interpreted from the name.

Rules for writing IUPAC name from structural formula are:

1. First identify the longest carbon chain.

2. Then identify the functional groups attached to the longest chain.

3. Identify the position, location, and number of the substituent bonded to the carbon chain.

4. Use prefix di, tri, tetra if similar type of substituent is present.

Answer 7

Chapter 4, Problem 4.5P

Interpretation Introduction

(a)

Interpretation:

The name of the given compound is to be stated.

Concept introduction:

The systematic naming of organic compound is given by IUPAC nomenclature. The naming of organic compound is done such that the organic compound structure is correctly interpreted from the name.

Rules for writing IUPAC name from structural formula are:

1. First identify the longest carbon chain.

2. Then identify the functional groups attached to the longest chain.

3. Identify the position, location, and number of the substituent bonded to the carbon chain.

4. Use prefix di, tri, tetra if similar type of substituent is present.

Answer 8

Interpretation Introduction

(b)

Interpretation:

The name of the given compound is to be stated.

Concept introduction:

The systematic naming of organic compound is given by IUPAC nomenclature. The naming of organic compound is done such that the organic compound structure is correctly interpreted from the name.

Rules for writing IUPAC name from structural formula are:

1. First identify the longest carbon chain.

2. Then identify the functional groups attached to the longest chain.

3. Identify the position, location, and number of the substituent bonded to the carbon chain.

4. Use prefix di, tri, tetra if similar type of substituent is present.

Answer 9

Interpretation Introduction

(b)

Interpretation:

The name of the given compound is to be stated.

Concept introduction:

The systematic naming of organic compound is given by IUPAC nomenclature. The naming of organic compound is done such that the organic compound structure is correctly interpreted from the name.

Rules for writing IUPAC name from structural formula are:

1. First identify the longest carbon chain.

2. Then identify the functional groups attached to the longest chain.

3. Identify the position, location, and number of the substituent bonded to the carbon chain.

4. Use prefix di, tri, tetra if similar type of substituent is present.

Answer 10

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Answer 11

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Answer 12

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Answer 13

Ch. 4 - Prob. 4.1P Ch. 4 - Prob. 4.2P Ch. 4 - Prob. 4.3P Ch. 4 - Prob. 4.4P Ch. 4 - Prob. 4.5P Ch. 4 - Prob. 4.6P Ch. 4 - Prob. 4.7P Ch. 4 - Prob. 4.8P Ch. 4 - Prob. 4.9P Ch. 4 - Prob. 4.10P

Solution Summary: The author explains the IUPAC nomenclature and the structure of the compound.

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Chapter 4 Solutions