Organic Chemistry Study Guide and Solutions
Organic Chemistry Study Guide and Solutions
6th Edition
ISBN: 9781936221868
Author: Marc Loudon, Jim Parise
Publisher: W. H. Freeman
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Chapter 4, Problem 4.54AP
Interpretation Introduction

Interpretation:

The structures of two isomeric alkenes with molecular formula C6H12 which reacts with HI to give the same product and undergoes catalytic hydrogenation to give hexane are to be stated.

Concept introduction:

When an unsymmetrical alkene is reacted with hydrogen halide, an alkyl halide is formed. The substitution of hydrogen halide in an alkene takes place by Markovnikov’s rule. Catalytic hydrogenation is a reduction process of addition of hydrogen atoms in an alkene or an alkyne by using a metal catalyst. The number of bonds is reduced between carbon atoms.

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6. Consider the following exothermic reaction below. 2Cu2+(aq) +41 (aq)2Cul(s) + 12(aq) a. If Cul is added, there will be a shift left/shift right/no shift (circle one). b. If Cu2+ is added, there will be a shift left/shift right/no shift (circle one). c. If a solution of AgNO3 is added, there will be a shift left/shift right/no shift (circle one). d. If the solvent hexane (C6H14) is added, there will be a shift left/shift right/no shift (circle one). Hint: one of the reaction species is more soluble in hexane than in water. e. If the reaction is cooled, there will be a shift left/shift right/no shift (circle one). f. Which of the changes above will change the equilibrium constant, K?
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