Organic Chemistry Study Guide and Solutions
Organic Chemistry Study Guide and Solutions
6th Edition
ISBN: 9781936221868
Author: Marc Loudon, Jim Parise
Publisher: W. H. Freeman
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Chapter 4, Problem 4.16P
Interpretation Introduction

(a)

Interpretation:

The given compounds are to be arranged in the increasing order of stability.

Concept introduction:

The alkene stability is affected by the alkyl substituents on the C-C double bond. Higher the alkyl substitution, higher is the stability. The stability of alkenes can be compared using heats of formation. Higher the negative value of heat of formation, higher is the stability of alkenes.

Interpretation Introduction

(b)

Interpretation:

The given compounds are to be arranged in the increasing order of stability.

Concept introduction:

The alkene stability is affected by the alkyl substituents on the C-C double bond. Higher the alkyl substitution, higher is the stability. The stability of alkenes can be compared using heats of formation. Higher the negative value of heat of formation, higher is the stability of alkenes.

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6. Consider the following exothermic reaction below. 2Cu2+(aq) +41 (aq)2Cul(s) + 12(aq) a. If Cul is added, there will be a shift left/shift right/no shift (circle one). b. If Cu2+ is added, there will be a shift left/shift right/no shift (circle one). c. If a solution of AgNO3 is added, there will be a shift left/shift right/no shift (circle one). d. If the solvent hexane (C6H14) is added, there will be a shift left/shift right/no shift (circle one). Hint: one of the reaction species is more soluble in hexane than in water. e. If the reaction is cooled, there will be a shift left/shift right/no shift (circle one). f. Which of the changes above will change the equilibrium constant, K?
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