Introduction to General, Organic and Biochemistry
11th Edition
ISBN: 9781285869759
Author: Frederick A. Bettelheim, William H. Brown, Mary K. Campbell, Shawn O. Farrell, Omar Torres
Publisher: Cengage Learning
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Chapter 4, Problem 4.49P
4-49 Calculate the number of:
(a) nitrogen atoms in 25.0 g of TNT, C7H5N3O6
(b) carbon atoms in 40.0 g of ethanol, C2H6O
(c) oxygen atoms in 500. mg of aspirin, C9H8O4
(d) sodium atoms in 2.40 g of sodium dihydrogen phosphate, NaH2PO4
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(a) Calculate the molar mass of ammonium nitrate, NH4NO3. (b) What is the mass percent of nitrogen in ammonium nitrate? (c) How many kilograms of nitrogen are present in a 10.0-lb bag of ammonium nitrate? (d) How many kilograms of ammonium nitrate contain 1.00 lb of nitrogen? (1 lb = 453.6 g)
a) What is the mass, in grams, of 2.50 x 10-3 mol ofammonium phosphate?(b) How many moles of chloride ions are in 0.2550 g ofaluminum chloride?(c) What is the mass, in grams, of 7.70 x 1020 molecules ofcaffeine, C8H10N4O2?(d) What is the molar mass of cholesterol if 0.00105 mol hasa mass of 0.406 g?
Answer true or false.
(b) Avogadro’s number, to three significant figures, is 6.02 x 1023 formula units per mole.
(d) 1 mol of H2O contains 3 x 6.02 x 1023 formula units.
(i) 1 mol of ibuprofen, C13H18O2, contains 33 mol of atoms.
Chapter 4 Solutions
Introduction to General, Organic and Biochemistry
Ch. 4.2 - Problem 4-1 Following is an unbalanced equation...Ch. 4.2 - Problem 4-2 Balance this equation:Ch. 4.2 - Prob. 4.3PCh. 4.3 - Problem 4-4 When a solution of copper(II)...Ch. 4.4 - Problem 4-5 In each equation, identify the...Ch. 4.5 - Problem 4-6 What is (a) the molecular weight of...Ch. 4.6 - Prob. 4.7PCh. 4.6 - Problem 4-8 We wish to weigh 2.84 mol of sodium...Ch. 4.6 - Problem 4-9 How many moles of C atoms, H atoms,...Ch. 4.6 - Problem 4-10 How many moles of copper(I) ions,...
Ch. 4.6 - Prob. 4.11PCh. 4.7 - Prob. 4.12PCh. 4.7 - Prob. 4.13PCh. 4.7 - Problem 4-14 Ethanol is produced industrially by...Ch. 4.7 - Prob. 4.15PCh. 4.7 - Prob. 4.16PCh. 4 - 4-17 Balance each equation.Ch. 4 - 4-18 Balance each equation.Ch. 4 - Prob. 4.19PCh. 4 - 4-20 Calcium oxide is prepared by heating...Ch. 4 - 4-21 The brilliant white light in some firework...Ch. 4 - Prob. 4.22PCh. 4 - 4-23 When solid carbon burns in a limited supply...Ch. 4 - Prob. 4.24PCh. 4 - 4-25 In the chemical test for arsenic, the gas...Ch. 4 - Prob. 4.26PCh. 4 - Prob. 4.27PCh. 4 - 4-28 Answer true or false. (a) A net ionic...Ch. 4 - 4-29 Balance these net ionic equations. (a)...Ch. 4 - 4-30 In the equation (a) Identify the spectator...Ch. 4 - 4-31 Predict whether a precipitate will form when...Ch. 4 - 4-32 When a solution of ammonium chloride is added...Ch. 4 - 4-33 When a solution of hydrochloric acid, HCl, is...Ch. 4 - Prob. 4.34PCh. 4 - Prob. 4.35PCh. 4 - 4-36 Using the solubility generalizations given in...Ch. 4 - 4-37 Answer true or false. (a) When a substance is...Ch. 4 - Prob. 4.38PCh. 4 - Prob. 4.39PCh. 4 - Prob. 4.40PCh. 4 - Prob. 4.41PCh. 4 - 4-42 Calculate the formula weight of: (a) KCl (b)...Ch. 4 - 4-43 Calculate the molecular weight of: (a)...Ch. 4 - 4-44 Answer true or false. (a) The mole is a...Ch. 4 - 4-45 Calculate the number of moles in: (a) 32 g of...Ch. 4 - 4-46 Calculate the number of grams in: (a) 1.77...Ch. 4 - 4-47 Calculate the number of moles of: (a) O atoms...Ch. 4 - 4-48 Calculate the number of moles of: (a) S2-...Ch. 4 - 4-49 Calculate the number of: (a) nitrogen atoms...Ch. 4 - 4-50 How many molecules are in each of the...Ch. 4 - 4-51 What is the mass in grams of each number of...Ch. 4 - 4-52 The molecular weight of hemoglobin is about...Ch. 4 - 4-53 A typical deposit of cholesterol, C27H46O, in...Ch. 4 - 4-54 Answer true or false. (a) Stoichiometry is...Ch. 4 - 4-55 For the reaction: (a) How many moles of N2...Ch. 4 - 4-56 Magnesium reacts with sulfuric acid according...Ch. 4 - 4-57 Chloroform, CHCl3, is prepared industrially...Ch. 4 - 4-58 At one time, acetaldehyde was prepared...Ch. 4 - 4-59 Chlorine dioxide, ClO2, is used for bleaching...Ch. 4 - 4-60 Ethanol, C2H6O, is added to gasoline to...Ch. 4 - 4-61 In photosynthesis, green plants convert CO2...Ch. 4 - 4-62 Iron ore is converted to iron by heating it...Ch. 4 - Prob. 4.63PCh. 4 - 4-64 Aspirin is made by the reaction of salicylic...Ch. 4 - 4-65 Suppose the preparation of aspirin from...Ch. 4 - 4-66 Benzene reacts with bromine to produce...Ch. 4 - 4-67 Ethyl chloride is prepared by the reaction of...Ch. 4 - 4-68 Diethyl ether is made from ethanol according...Ch. 4 - Prob. 4.69PCh. 4 - Prob. 4.70PCh. 4 - 4-71 Which of these reactions are exothermic, and...Ch. 4 - Prob. 4.72PCh. 4 - Prob. 4.73PCh. 4 - Prob. 4.74PCh. 4 - Prob. 4.75PCh. 4 - Prob. 4.76PCh. 4 - 4-77 To convert 1 mol of iron(III) oxide to its...Ch. 4 - 4-78 (Chemical Connections 4A) How does fluoride...Ch. 4 - Prob. 4.79PCh. 4 - Prob. 4.80PCh. 4 - 4-81 (Chemical Connections 4C) Balance the lithium...Ch. 4 - 4-82 When gaseous dinitrogen pentoxide, N2O5, is...Ch. 4 - Prob. 4.83PCh. 4 - Prob. 4.84PCh. 4 - Prob. 4.85PCh. 4 - 4-86 When an aqueous solution of Na3PO4 is added...Ch. 4 - Prob. 4.87PCh. 4 - 4-88 Chlorophyll, the compound responsible for the...Ch. 4 - 4-89 If 7.0 kg of is added to 11.0 kg of to form...Ch. 4 - 4-90 Lead(lI) nitrate and aluminum chloride react...Ch. 4 - 4-91 Assume that the average red blood cell has a...Ch. 4 - 4-92 Reaction of pentane, C5H12, with oxygen, O2,...Ch. 4 - 4-93 Ammonia is prepared industrially by the...Ch. 4 - 4-94 2,3,7,8-Tetrachlorodibenzo-p-dioxin (TCDD) is...Ch. 4 - Prob. 4.95PCh. 4 - Prob. 4.96PCh. 4 - Prob. 4.97PCh. 4 - Prob. 4.98PCh. 4 - Prob. 4.99PCh. 4 - Prob. 4.100PCh. 4 - Prob. 4.101PCh. 4 - 4-102 Aspartame, an artificial sweetener used as a...Ch. 4 - 4-103 Caffeine, a central nervous system...
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- 4-53 A typical deposit of cholesterol, C27H46O, in an artery might have a mass of 3.9 mg. How many mol ecules of cholesterol are in this mass?arrow_forwardWrite an equation from the following description: reactants are gaseous NH3 and O2, products are gaseous NO2 and liquid H2O, and the stoichiometric coefficients are 4, 7, 4, and 6, respectively.arrow_forward4-91 Assume that the average red blood cell has a mass of 2 × 10-8 g and that 20% of its mass is hemoglobin (a protein whose molar mass is 68,000). How many molecules of hemoglobin are present in one red blood cell?arrow_forward
- 4-61 In photosynthesis, green plants convert CO2 and H2O to glucose, C6H12O6. How many grams of CO2are required to produce 5.1 g of glucose?arrow_forwardFig. 5-5 illustrates a schematic diagram of a combustion device used to analyze organic compounds. Given that a certain amount of a compound containing carbon, hydrogen, and oxygen is combusted in this device, explain how the data relating to the mass of CO2 produced and the mass of H2O produced can be manipulated to determine the empirical formula.arrow_forward4-93 Ammonia is prepared industrially by the reaction of nitrogen and hydrogen according to the following equation: If 29.7 kg of N2 is added to 3.31 kg of H2, (a) Which reactant is the limiting reagent? (b) How many grams of the other reactant are left over? (c) How many grams of NH3 are formed if the reaction goes to completion?arrow_forward
- 4-103 Caffeine, a central nervous system stimulant, has the molecular formula C8H10N402. (a) How many moles of caffeine are present in 6.19 1025 molecules of caffeine? (b) Imagine you dissolve caffeine in water to a volume of 100.0 mL, which is known to have a density of 1.23 g/mL. How many molecules of caffeine are present in this volume? (c) How many nitrogen atoms are present in 3.5 mg of caffeine? (d) Complete the skeletal structure of caffeine, where all the bonded atoms are shown but double bonds, triple bonds, and/or lone pairs are missing. (e) Identify the various types of geometries present in each central atom of caffeine using VSEPR theory. (f) Determine the various relative bond angles associated with each central atom of caffeine using VSEPR theory (g) What is the most polar bond in caffeine? (h) Would you predict caffeine to be polar or nonpolar? (j) Consider the combustion of caffeine, which results in formation of NO2(g) as well as other expected products. Write a balanced chemical equation for this reaction. (j) The heat of combustion for caffeine is 2211 kcall/mol. How much heat will be given off if 0.81 g of caffeine is burned completely? (k) Calculate the weight of H2O(g) that can be prepared from 8.00 g of caffeine mixed with 20.3 g of oxygen gas.arrow_forwardWhat is the molarity of each ion present in aqueous solutions of the following compounds prepared by dissolving 28.0 g of each compound in water to make 785 mL of solution? (a) potassium oxide (b) sodium hydrogen carbonate (c) scandium(III) iodite (d) magnesium phosphatearrow_forwardThe principal component of mothballs is naphthalene, a compound with a molecular mass of about 130 amu, containing only carbon and hydrogen. A 3.000-mg sample of naphthalene burns to give 10.3 mg of CO2. Determine its empirical and molecular formulas.arrow_forward
- The active ingredient in some antiperspirants is aluminum chlorohydrate, Al2(OH)5Cl. Analysis of a 2.000-g sample of antiperspirant yields 0.334 g of aluminum. What percent (by mass) of aluminum chlorohydrate is present in the antiperspirant? (Assume that there are no other compounds containing aluminum in the antiperspirant.)arrow_forward4-56 Magnesium reacts with sulfuric acid according to the following equation. How many moles of lI2 are produced by the complete reaction of 230. mg of Mg with sulfuric acid?arrow_forward4-88 Chlorophyll, the compound responsible for the green color of leaves and grasses, contains one atom of magnesium in each molecule. If the percentage by weight of magnesium in chlorophyll is 2.72%, what is the molecular weight of chlorophyll?arrow_forward
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