Introduction to General, Organic and Biochemistry
11th Edition
ISBN: 9781285869759
Author: Frederick A. Bettelheim, William H. Brown, Mary K. Campbell, Shawn O. Farrell, Omar Torres
Publisher: Cengage Learning
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Textbook Question
Chapter 4, Problem 4.46P
4-46 Calculate the number of grams in:
(a) 1.77 mol of nitrogen dioxide, NO2
(b) 0.84 mol of 2-propanol, C3H8O (rubbing alcohol)
(c) 3.69 mol of uranium hexafluoride, UF6
(d) 0.348 mol of galactose, C6H12O6
(e) 4.9 X 10-2 mol of vitamin C, C6H8O6
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Chapter 4 Solutions
Introduction to General, Organic and Biochemistry
Ch. 4.2 - Problem 4-1 Following is an unbalanced equation...Ch. 4.2 - Problem 4-2 Balance this equation:Ch. 4.2 - Prob. 4.3PCh. 4.3 - Problem 4-4 When a solution of copper(II)...Ch. 4.4 - Problem 4-5 In each equation, identify the...Ch. 4.5 - Problem 4-6 What is (a) the molecular weight of...Ch. 4.6 - Prob. 4.7PCh. 4.6 - Problem 4-8 We wish to weigh 2.84 mol of sodium...Ch. 4.6 - Problem 4-9 How many moles of C atoms, H atoms,...Ch. 4.6 - Problem 4-10 How many moles of copper(I) ions,...
Ch. 4.6 - Prob. 4.11PCh. 4.7 - Prob. 4.12PCh. 4.7 - Prob. 4.13PCh. 4.7 - Problem 4-14 Ethanol is produced industrially by...Ch. 4.7 - Prob. 4.15PCh. 4.7 - Prob. 4.16PCh. 4 - 4-17 Balance each equation.Ch. 4 - 4-18 Balance each equation.Ch. 4 - Prob. 4.19PCh. 4 - 4-20 Calcium oxide is prepared by heating...Ch. 4 - 4-21 The brilliant white light in some firework...Ch. 4 - Prob. 4.22PCh. 4 - 4-23 When solid carbon burns in a limited supply...Ch. 4 - Prob. 4.24PCh. 4 - 4-25 In the chemical test for arsenic, the gas...Ch. 4 - Prob. 4.26PCh. 4 - Prob. 4.27PCh. 4 - 4-28 Answer true or false. (a) A net ionic...Ch. 4 - 4-29 Balance these net ionic equations. (a)...Ch. 4 - 4-30 In the equation (a) Identify the spectator...Ch. 4 - 4-31 Predict whether a precipitate will form when...Ch. 4 - 4-32 When a solution of ammonium chloride is added...Ch. 4 - 4-33 When a solution of hydrochloric acid, HCl, is...Ch. 4 - Prob. 4.34PCh. 4 - Prob. 4.35PCh. 4 - 4-36 Using the solubility generalizations given in...Ch. 4 - 4-37 Answer true or false. (a) When a substance is...Ch. 4 - Prob. 4.38PCh. 4 - Prob. 4.39PCh. 4 - Prob. 4.40PCh. 4 - Prob. 4.41PCh. 4 - 4-42 Calculate the formula weight of: (a) KCl (b)...Ch. 4 - 4-43 Calculate the molecular weight of: (a)...Ch. 4 - 4-44 Answer true or false. (a) The mole is a...Ch. 4 - 4-45 Calculate the number of moles in: (a) 32 g of...Ch. 4 - 4-46 Calculate the number of grams in: (a) 1.77...Ch. 4 - 4-47 Calculate the number of moles of: (a) O atoms...Ch. 4 - 4-48 Calculate the number of moles of: (a) S2-...Ch. 4 - 4-49 Calculate the number of: (a) nitrogen atoms...Ch. 4 - 4-50 How many molecules are in each of the...Ch. 4 - 4-51 What is the mass in grams of each number of...Ch. 4 - 4-52 The molecular weight of hemoglobin is about...Ch. 4 - 4-53 A typical deposit of cholesterol, C27H46O, in...Ch. 4 - 4-54 Answer true or false. (a) Stoichiometry is...Ch. 4 - 4-55 For the reaction: (a) How many moles of N2...Ch. 4 - 4-56 Magnesium reacts with sulfuric acid according...Ch. 4 - 4-57 Chloroform, CHCl3, is prepared industrially...Ch. 4 - 4-58 At one time, acetaldehyde was prepared...Ch. 4 - 4-59 Chlorine dioxide, ClO2, is used for bleaching...Ch. 4 - 4-60 Ethanol, C2H6O, is added to gasoline to...Ch. 4 - 4-61 In photosynthesis, green plants convert CO2...Ch. 4 - 4-62 Iron ore is converted to iron by heating it...Ch. 4 - Prob. 4.63PCh. 4 - 4-64 Aspirin is made by the reaction of salicylic...Ch. 4 - 4-65 Suppose the preparation of aspirin from...Ch. 4 - 4-66 Benzene reacts with bromine to produce...Ch. 4 - 4-67 Ethyl chloride is prepared by the reaction of...Ch. 4 - 4-68 Diethyl ether is made from ethanol according...Ch. 4 - Prob. 4.69PCh. 4 - Prob. 4.70PCh. 4 - 4-71 Which of these reactions are exothermic, and...Ch. 4 - Prob. 4.72PCh. 4 - Prob. 4.73PCh. 4 - Prob. 4.74PCh. 4 - Prob. 4.75PCh. 4 - Prob. 4.76PCh. 4 - 4-77 To convert 1 mol of iron(III) oxide to its...Ch. 4 - 4-78 (Chemical Connections 4A) How does fluoride...Ch. 4 - Prob. 4.79PCh. 4 - Prob. 4.80PCh. 4 - 4-81 (Chemical Connections 4C) Balance the lithium...Ch. 4 - 4-82 When gaseous dinitrogen pentoxide, N2O5, is...Ch. 4 - Prob. 4.83PCh. 4 - Prob. 4.84PCh. 4 - Prob. 4.85PCh. 4 - 4-86 When an aqueous solution of Na3PO4 is added...Ch. 4 - Prob. 4.87PCh. 4 - 4-88 Chlorophyll, the compound responsible for the...Ch. 4 - 4-89 If 7.0 kg of is added to 11.0 kg of to form...Ch. 4 - 4-90 Lead(lI) nitrate and aluminum chloride react...Ch. 4 - 4-91 Assume that the average red blood cell has a...Ch. 4 - 4-92 Reaction of pentane, C5H12, with oxygen, O2,...Ch. 4 - 4-93 Ammonia is prepared industrially by the...Ch. 4 - 4-94 2,3,7,8-Tetrachlorodibenzo-p-dioxin (TCDD) is...Ch. 4 - Prob. 4.95PCh. 4 - Prob. 4.96PCh. 4 - Prob. 4.97PCh. 4 - Prob. 4.98PCh. 4 - Prob. 4.99PCh. 4 - Prob. 4.100PCh. 4 - Prob. 4.101PCh. 4 - 4-102 Aspartame, an artificial sweetener used as a...Ch. 4 - 4-103 Caffeine, a central nervous system...
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- 4-91 Assume that the average red blood cell has a mass of 2 × 10-8 g and that 20% of its mass is hemoglobin (a protein whose molar mass is 68,000). How many molecules of hemoglobin are present in one red blood cell?arrow_forward4-52 The molecular weight of hemoglobin is about 68,000 amu. What is the mass in grams of a single molecule of hemoglobin?arrow_forwardFig. 5-5 illustrates a schematic diagram of a combustion device used to analyze organic compounds. Given that a certain amount of a compound containing carbon, hydrogen, and oxygen is combusted in this device, explain how the data relating to the mass of CO2 produced and the mass of H2O produced can be manipulated to determine the empirical formula.arrow_forward
- 4-49 Calculate the number of: (a) nitrogen atoms in 25.0 g of TNT, C7H5N3O6 (b) carbon atoms in 40.0 g of ethanol, C2H6O (c) oxygen atoms in 500. mg of aspirin, C9H8O4 (d) sodium atoms in 2.40 g of sodium dihydrogen phosphate, NaH2PO4arrow_forward4-47 Calculate the number of moles of: (a) O atoms in 18.1 mol of forma1dehyde, CH2O (b) Br atoms in 0.41 mol of bromoform, CHBr3 (c) O atoms in 3.5 X 103 mol of A12(SO4)3 (d)Hg atoms in 87 g of HgOarrow_forward4-61 In photosynthesis, green plants convert CO2 and H2O to glucose, C6H12O6. How many grams of CO2are required to produce 5.1 g of glucose?arrow_forward
- 4-103 Caffeine, a central nervous system stimulant, has the molecular formula C8H10N402. (a) How many moles of caffeine are present in 6.19 1025 molecules of caffeine? (b) Imagine you dissolve caffeine in water to a volume of 100.0 mL, which is known to have a density of 1.23 g/mL. How many molecules of caffeine are present in this volume? (c) How many nitrogen atoms are present in 3.5 mg of caffeine? (d) Complete the skeletal structure of caffeine, where all the bonded atoms are shown but double bonds, triple bonds, and/or lone pairs are missing. (e) Identify the various types of geometries present in each central atom of caffeine using VSEPR theory. (f) Determine the various relative bond angles associated with each central atom of caffeine using VSEPR theory (g) What is the most polar bond in caffeine? (h) Would you predict caffeine to be polar or nonpolar? (j) Consider the combustion of caffeine, which results in formation of NO2(g) as well as other expected products. Write a balanced chemical equation for this reaction. (j) The heat of combustion for caffeine is 2211 kcall/mol. How much heat will be given off if 0.81 g of caffeine is burned completely? (k) Calculate the weight of H2O(g) that can be prepared from 8.00 g of caffeine mixed with 20.3 g of oxygen gas.arrow_forward4-54 Answer true or false. (a) Stoichiometry is the study of mass relationships in chemical reactions. (b) To determine mass relationships in a chemical reaction, you first need to know the balanced chemical equation for the reaction. (c) To convert from grams to moles and vice versa, use Avogadro’s number as a conversion factor. (d) To convert from grams to moles and vice versa, use molar mass as a conversion factor. (e) A limiting reagent is the reagent that is used up first. (f) Suppose a chemical reaction between A and B requires 1 mol of A and 2 mol of B. If 1 mol of each is present, then B is the limiting reagent. (g) Theoretical yield is the yield of product that should be obtained according to the balanced chemical equation. (h) Theoretical yield is the yield of product that should be obtained if all limiting reagent is con verted to product. (j) Percent yield is the number of grams of product divided by the number of grams of the limiting reagent times 100. (j) To calculate percent yield, divide the mass of product formed by the theoretical yield and multiply by 100.arrow_forward4-93 Ammonia is prepared industrially by the reaction of nitrogen and hydrogen according to the following equation: If 29.7 kg of N2 is added to 3.31 kg of H2, (a) Which reactant is the limiting reagent? (b) How many grams of the other reactant are left over? (c) How many grams of NH3 are formed if the reaction goes to completion?arrow_forward
- 4-45 Calculate the number of moles in: (a) 32 g of methane, CH4 (b) 345.6 g of nitric oxide, NO (c) 184.4 g of chlorine dioxide, ClO2 (d) 720. g of glycerin, C3H8O3arrow_forward4-57 Chloroform, CHCl3, is prepared industrially by the reaction of methane with chlorine. How many grams of Cl2 are needed to produce 1.50 moles of chloroform?arrow_forwardWrite an equation from the following description: reactants are gaseous NH3 and O2, products are gaseous NO2 and liquid H2O, and the stoichiometric coefficients are 4, 7, 4, and 6, respectively.arrow_forward
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