Chemistry: Principles and Practice
3rd Edition
ISBN: 9780534420123
Author: Daniel L. Reger, Scott R. Goode, David W. Ball, Edward Mercer
Publisher: Cengage Learning
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Chapter 4, Problem 4.120QE
Interpretation Introduction
Interpretation:
The theoretical yield of hydrazine has to be calculated.
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Q4: Rank the relative nucleophilicity of halide ions in water solution and DMF solution,
respectively.
F CI
Br |
Q5: Determine which of the substrates will and will not react with NaSCH3 in an SN2 reaction to
have a reasonable yield of product.
NH2
Br
Br
Br
OH
Br
Q7: Rank the following groups in order of basicity, nucleophilicity, and leaving group ability.
a) H₂O, OH, CH3COOT
b) NH3, H₂O, H₂S
Q8: Rank the following compounds in order of increasing reactivity in a nucleophilic substitution
reaction with CN as the nucleophile.
Br
A
B
NH2
LL
F
C
D
OH
CI
LLI
E
Q9: Complete the missing entities for following reactions (e.g., major product(s), reactants,
and/or solvents) for the SN2 reactions to occur efficiently. Include curved-arrow mechanism for
reactions a) to d).
a)
H
"Cl
D
+
-OCH 3
Page 3 of 5
Chapter 4 Solutions
Chemistry: Principles and Practice
Ch. 4 - Prob. 4.1QECh. 4 - A solution is formed by mixing 1 gal ethanol with...Ch. 4 - An aqueous sample is known to contain either Sr2+...Ch. 4 - Ammonium chloride is a strong electrolyte. Draw a...Ch. 4 - Experiments show that propionic acid (CH3CH2COOH)...Ch. 4 - Describe the procedure used to make 1.250 L of...Ch. 4 - If enough Li2SO4 dissolves in water to make a 0.33...Ch. 4 - Describe how 500 mL of a 1.5 M solution of HCl...Ch. 4 - Addition of water to concentrated sulfuric acid is...Ch. 4 - Draw the flow diagram for a calculation that...
Ch. 4 - Prob. 4.11QECh. 4 - Describe in words the titration of an acid with a...Ch. 4 - Describe the use of gravimetric analysis to...Ch. 4 - Draw the contents of a beaker of water that...Ch. 4 - Prob. 4.15QECh. 4 - Prob. 4.16QECh. 4 - Prob. 4.17QECh. 4 - Prob. 4.18QECh. 4 - Write the net ionic equation for the reaction, if...Ch. 4 - Write the net ionic equation for the reaction, if...Ch. 4 - Prob. 4.21QECh. 4 - Prob. 4.22QECh. 4 - Write the overall equation (including the physical...Ch. 4 - Write the overall equation (including the physical...Ch. 4 - Write the overall equation (including the physical...Ch. 4 - Write the overall equation (including the physical...Ch. 4 - An aqueous sample is known to contain either Pb2+...Ch. 4 - An aqueous sample is known to contain either Ag+...Ch. 4 - An aqueous sample is known to contain either Mg2+...Ch. 4 - An aqueous sample is known to contain either Pb2+...Ch. 4 - In the beakers shown below, the colored spheres...Ch. 4 - In the beakers shown below, the colored spheres...Ch. 4 - Calculate the molarity of KOH in a solution...Ch. 4 - Calculate the molarity of NaCl in a solution...Ch. 4 - Calculate the molarity of AgNO3 in a solution...Ch. 4 - Calculate the molarity of NaOH in a solution...Ch. 4 - What volume of a 2.3 M HCl solution is needed to...Ch. 4 - What volume of a 5.22 M NaOH solution is needed to...Ch. 4 - What volume of a 2.11 M Li2CO3 solution is needed...Ch. 4 - What volume of a 5.00 M H2SO4 solution is needed...Ch. 4 - What is the molarity of a glucose (C6H12O6)...Ch. 4 - If you dilute 25.0 mL of 1.50 M hydrochloric acid...Ch. 4 - Prob. 4.43QECh. 4 - Prob. 4.44QECh. 4 - Prob. 4.45QECh. 4 - Prob. 4.46QECh. 4 - How many grams of AgNO3 are needed to prepare 300...Ch. 4 - What mass of oxalic acid, H2C2O4, is required to...Ch. 4 - Prob. 4.49QECh. 4 - What mass of sodium sulfate, in grams, is needed...Ch. 4 - What is the molarity of a solution of strontium...Ch. 4 - What is the molarity of a solution of sodium...Ch. 4 - What is the molarity of a solution of magnesium...Ch. 4 - If 6.73 g of Na2CO3 is dissolved in enough water...Ch. 4 - The substance KSCN is frequently used to test for...Ch. 4 - Potassium permanganate (KMnO4) solutions are used...Ch. 4 - Two liters of a 1.5 M solution of sodium hydroxide...Ch. 4 - Prob. 4.58QECh. 4 - Prob. 4.59QECh. 4 - Prob. 4.60QECh. 4 - Prob. 4.61QECh. 4 - Prob. 4.62QECh. 4 - Prob. 4.63QECh. 4 - Prob. 4.64QECh. 4 - What volume of 2.4 M HCl is needed to obtain 1.3...Ch. 4 - Prob. 4.66QECh. 4 - Prob. 4.67QECh. 4 - Prob. 4.68QECh. 4 - Prob. 4.69QECh. 4 - Prob. 4.70QECh. 4 - What volume of 0.66 M HNO3 is needed to react...Ch. 4 - What volume of 0.22 M hydrochloric acid is needed...Ch. 4 - Prob. 4.73QECh. 4 - Prob. 4.74QECh. 4 - Prob. 4.75QECh. 4 - Prob. 4.76QECh. 4 - Prob. 4.77QECh. 4 - What mass of iron (III) hydroxide precipitates on...Ch. 4 - Prob. 4.79QECh. 4 - What is the solid that precipitates, and how much...Ch. 4 - What volume of 1.212 M silver nitrate is needed to...Ch. 4 - Prob. 4.82QECh. 4 - A solid forms when excess barium chloride is added...Ch. 4 - Prob. 4.84QECh. 4 - Write the overall equation (including the physical...Ch. 4 - Write the overall equation (including the physical...Ch. 4 - What is the molar concentration of a solution of...Ch. 4 - Prob. 4.88QECh. 4 - What is the molar concentration of an HCl solution...Ch. 4 - What is the molar concentration of an H2SO4...Ch. 4 - Prob. 4.91QECh. 4 - Prob. 4.92QECh. 4 - The pungent odor of vinegar is a result of the...Ch. 4 - Prob. 4.94QECh. 4 - Oranges and grapefruits are known as citrus fruits...Ch. 4 - Prob. 4.96QECh. 4 - Prob. 4.97QECh. 4 - Prob. 4.98QECh. 4 - Prob. 4.99QECh. 4 - Prob. 4.100QECh. 4 - Prob. 4.101QECh. 4 - Prob. 4.102QECh. 4 - Prob. 4.103QECh. 4 - Prob. 4.104QECh. 4 - Prob. 4.105QECh. 4 - Prob. 4.106QECh. 4 - Prob. 4.107QECh. 4 - Prob. 4.108QECh. 4 - Prob. 4.109QECh. 4 - Prob. 4.110QECh. 4 - Prob. 4.115QECh. 4 - Prob. 4.117QECh. 4 - Prob. 4.118QECh. 4 - Prob. 4.119QECh. 4 - Prob. 4.120QECh. 4 - Prob. 4.121QECh. 4 - Prob. 4.122QECh. 4 - Prob. 4.123QE
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- Q10: (a) Propose a synthesis of C from A. (b) Propose a synthesis of C from B. Br Br ...\SCH 3 A B Carrow_forward9: Complete the missing entities for following reactions (e.g., major product(s), reactants, and/or solvents) for the SN2 reactions to occur efficiently. Include curved-arrow mechanism for reactions a) to d).arrow_forwardComplete the missing entities for following reactions (e.g., major product(s), reactants, and/or solvents) for the SN2 reactions to occur efficiently. Include curved-arrow mechanism for reactions a) to d).arrow_forward
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- Q2: Group these solvents into either protic solvents or aprotic solvents. Acetonitrile (CH3CN), H₂O, Acetic acid (CH3COOH), Acetone (CH3COCH3), CH3CH2OH, DMSO (CH3SOCH3), DMF (HCON(CH3)2), CH3OHarrow_forwardSuppose the rate of evaporation in a hot, dry region is 1.76 meters per year, and the seawater there has a salinity of 35 ‰. Assuming a 93% yield, how much salt (NaCl) can be harvested each year from 1 km2 of solar evaporation ponds that use this seawater as a source?arrow_forwardhelparrow_forward
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