Chemistry: Principles and Reactions
8th Edition
ISBN: 9781305079373
Author: William L. Masterton, Cecile N. Hurley
Publisher: Cengage Learning
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Chapter 4, Problem 32QAP
A student tries to determine experimentally the molar mass of aspirin (HAsp). She takes 1.00 g of aspirin, dissolves it in water, and neutralizes it with 17.6 mL of 0.315 M KOH. The equation for the reaction is
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Chapter 4 Solutions
Chemistry: Principles and Reactions
Ch. 4 - Write the formulas of the following compounds and...Ch. 4 - Prob. 2QAPCh. 4 - Describe how you would precipitate (a) zinc...Ch. 4 - Name the reagent, if any, that you would add to a...Ch. 4 - Write net ionic equations for the formation of (a)...Ch. 4 - Write net ionic equations to explain the formation...Ch. 4 - Decide whether a precipitate will form when the...Ch. 4 - Follow the directions of Question 7 for solutions...Ch. 4 - Write a net ionic equation for any precipitation...Ch. 4 - Follow the directions for Question 9 for the...
Ch. 4 - What volume of 0.2500 M cobalt(III) sulfate is...Ch. 4 - Prob. 12QAPCh. 4 - A 50.00-mL sample of 0.0250 M silver nitrate is...Ch. 4 - Aluminum ions react with carbonate ions to form an...Ch. 4 - When Na3PO4 and Ca(NO3)2 are combined, the...Ch. 4 - When solutions of aluminum sulfate and sodium...Ch. 4 - Prob. 17QAPCh. 4 - Prob. 18QAPCh. 4 - Prob. 19QAPCh. 4 - Follow the directions of Question 19 for the...Ch. 4 - For an acid-base reaction, what is the reacting...Ch. 4 - Follow the directions of Question 21 for the...Ch. 4 - Prob. 23QAPCh. 4 - Prob. 24QAPCh. 4 - Consider the following generic equation: H+(aq)+...Ch. 4 - Consider the following generic equation...Ch. 4 - Prob. 27QAPCh. 4 - Prob. 28QAPCh. 4 - Prob. 29QAPCh. 4 - Consider several 25.00-mL solutions of perchloric...Ch. 4 - Prob. 31QAPCh. 4 - A student tries to determine experimentally the...Ch. 4 - Prob. 33QAPCh. 4 - For a product to be called vinegar, it must...Ch. 4 - The percentage of sodium hydrogen carbonate,...Ch. 4 - Prob. 36QAPCh. 4 - An artificial fruit beverage contains 12.0 g of...Ch. 4 - Lactic acid, C3H6O3 is the acid present in sour...Ch. 4 - Prob. 39QAPCh. 4 - Prob. 40QAPCh. 4 - Assign oxidation numbers to each element in (a)...Ch. 4 - Assign oxidation numbers to each element in (a)...Ch. 4 - Classify each of the following half-reactions as...Ch. 4 - Classify each of the following half-reactions as...Ch. 4 - Classify each of the following half-reactions as...Ch. 4 - Prob. 46QAPCh. 4 - For each unbalanced equation given below • write...Ch. 4 - Prob. 48QAPCh. 4 - A solution of potassium permanganate reacts with...Ch. 4 - Prob. 50QAPCh. 4 - Hydrogen gas is bubbled into a solution of barium...Ch. 4 - Consider the reaction tween silver and nitric acid...Ch. 4 - The molarity of iodine in solution can be...Ch. 4 - A wire weighing 0.250 g and containing 92.50% Fe...Ch. 4 - Glycerol (C3H8O3) is commonly used as an additive...Ch. 4 - Laws passed in some states define a drunk driver...Ch. 4 - A sample of limestone weighing 1.005 g is...Ch. 4 - The iron content of hemoglobin is determined by...Ch. 4 - In order to determine the purity of ammonium...Ch. 4 - Gold metal will dissolve only in aqua regia, a...Ch. 4 - Prob. 61QAPCh. 4 - Ten mL of concentrated H3PO4 (91.7% by mass,...Ch. 4 - Consider the following balanced redox reaction in...Ch. 4 - Prob. 64QAPCh. 4 - Using circles to represent cations and squares to...Ch. 4 - Assuming that circles represent cations and...Ch. 4 - Consider four beakers. Beaker A has an aqueous...Ch. 4 - The following figures represent species before and...Ch. 4 - A student is asked to identify the metal nitrate...Ch. 4 - Three students titrate different samples of the...Ch. 4 - Calcium in blood or urine can be determined by...Ch. 4 - Copper metal can reduce silver ions to metallic...Ch. 4 - Copper metal can reduce silver ions to metallic...Ch. 4 - A solution contains both iron(II) and iron(III)...Ch. 4 - A student is given 0.930 g of an unknown acid,...Ch. 4 - Solid iron(III) hydroxide is added to 625 mL of...Ch. 4 - A 300.0-g sample of a solid is made up of a...Ch. 4 - When 85.0 mL of 0.250 M Ba(OH)2 solution is added...
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- A soluble iodide was dissolved in water. Then an excess of silver nitrate, AgNO3, was added to precipitate all of the iodide ion as silver iodide, AgI. If 1.545 g of the soluble iodide gave 2.185 g of silver iodide, how many grams of iodine are in the sample of soluble iodide? What is the mass percentage of iodine, I, in the compound?arrow_forwardWrite a balanced equation for the reaction of hydroiodic acid, HI, with calcium hydroxide, Ca(OH)2. Then, write the balanced complete ionic equation and the net ionic equation for this neutralization reaction.arrow_forwardArsenic acid, H3AsO4, is a poisonous acid that has been used in the treatment of wood to prevent insect damage. Arsenic acid has three acidic protons. Say you take a 25.00-mL sample of arsenic acid and prepare it for titration with NaOH by adding 25.00 mL of water. The complete neutralization of this solution requires the addition of 53.07 mL of 0.6441 M NaOH solution. Write the balanced chemical reaction for the titration, and calculate the molarity of the arsenic acid sample.arrow_forward
- 1. Sometimes a reaction can fall in more than one category. Into what category (or categories) does the reaction of Ba(OH)2(aq) + H+PO4(aq) fit? acid-base and oxidation-reduction oxidation-reduction acid-base and precipitation precipitationarrow_forwardSodium chloride is used in intravenous solutions for medical applications. The NaCl concentration in such solutions must be accurately known and can be assessed by reacting the solution with an experimentally determined volume of AgNO3 solution of known concentration. The net ionic equation is Ag+(aq)+Cl(aq)AgCl(s) Suppose that a chemical technician uses 19.3 mL of 0.200-M AgNO3 to convert all the NaCl in a 25.0-mL sample of an intravenous solution to AgCl. Calculate the molarity of NaCl in the solution.arrow_forward2. Equal amounts (moles) of acetic acid(aq) and sodium sulfite, Na2SO3(aq), are mixed. The resulting solution is acidic basic neutralarrow_forward
- Potassium hydrogen phthalate, KHC8H4O4, is used to standardize solutions of bases. The acidic anion reacts with bases according to this net ionic equation: A 0.902-g sample of potassium hydrogen phthalate requires 26.45 mL NaOH to react; determine the molarity of the NaOH.arrow_forwardTwenty-five mL of a 0.388 M solution of Na2SO4 is mixed with 35.3 mL of 0.229 M Na2SO4. What is the molarity of the resulting solution? Assume that the volumes are additive.arrow_forwardAn antacid tablet contains sodium hydrogen carbonate, NaHCO3, and inert ingredients. A 0.465-g sample of powdered tablet was mixed with 53.3 mL of 0.190 M HCl (hydrochloric acid). The mixture was allowed to stand until it reacted. NaHCO3(s)+HCl(aq)NaCl(aq)+H2O(l)+CO2(g) The excess hydrochloric acid was titrated with 54.6 mL of 0.128 M NaOH (sodium hydroxide). HCl(aq)+NaOH(aq)NaCl(aq)+H2O(l) What is the percentage of sodium hydrogen carbonate in the antacid?arrow_forward
- Vitamin C is ascorbic acid, HC6H7O6, which can be titrated with a strong base. HC6H7O6(aq) + NaOH(aq) NaC6H7O6(aq) + H2O() A student dissolved a 500.0-mg vitamin C tablet in 200.0 mL water and then titrated it with 0.1250-M NaOH. It required 21.30 mL of the base to reach the equivalence point. Calculate the mass percentage of the tablet that is impurity.arrow_forwardAn antacid tablet has calcium carbonate as the active ingredient; other ingredients include a starch binder. You dissolve the tablet in hydrochloric acid and filter off insoluble material. You add potassium oxalate to the filtrate (containing calcium ion) to precipitate calcium oxalate. If a tablet weighing 0.750 g gave 0.629 g of calcium oxalate, what is the mass percentage of active ingredient in the tablet?arrow_forwardA 25.0-mL sample of vinegar (which contains the weak acid acetic acid, CH3CO2H) requires 28.33 mL of a 0.953 M solution of NaOH for titration to the equivalence point. What is the mass of acetic acid (molar mass = 60.05 g/mol), in grams, in the vinegar sample, and what is the concentration of acetic acid in the vinegar? CH3CO2H(aq) + NaOH(aq) NaCH3CO2(aq) + H2O(l)arrow_forward
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